General Pyrochlore Information
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Chemical Formula: |
(Na,Ca)2Nb2O6(OH,F) |
Composition: |
Molecular Weight = 353.84 gm |
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Sodium 9.75 % Na 13.14 % Na2O |
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Calcium 5.66 % Ca 7.92 % CaO |
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Niobium 52.51 % Nb 75.12 % Nb2O5 |
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Hydrogen 0.21 % H 1.91 % H2O |
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Oxygen 30.52 % O |
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Fluorine 1.34 % F 1.34 % F |
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- % F -0.57 % -O=F2 |
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______ ______ |
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100.00 % 98.87 % = TOTAL OXIDE |
Empirical Formula: |
Na1.5Ca0.5Nb2O6(OH)0.75F0.25 |
Environment: |
Nepheline-syenite rocks. |
IMA Status: |
Valid Species (Pre-IMA) 1826 |
Locality: |
Fredriksvarn and Larvik, Norway. Link to MinDat.org Location Data. |
Name Origin: |
From the Greek pyr - "fire" and chloros - "green." |
Synonym: |
ICSD 27815 |
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PDF 17-746 |
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Pyrochlore Image |
Images:
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Pyrochlore
Comments: Deep brownish black crystals of pyrochlore to 0.9 cm across.
Location: Lauzon Farm, Oka, Quebec, Canada.
Scale: 3.9 x 2.9 cm.
© John Veevaert |
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Images:
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Pyrochlore Crystallography
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Cell Dimensions: |
a = 10.37, Z = 10; V = 1,115.16 Den(Calc)= 5.27 |
Crystal System: |
Isometric - HexoctahedralH-M Symbol (4/m 3 2/m) Space Group: F d3m |
X Ray Diffraction: |
By Intensity(I/Io): 3(1), 1.838(0.6), 1.568(0.5), |
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Crystal Structure:
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Bonazzi P , Bindi L , Zoppi M , Capitani G C , Olmi F , American Mineralogist , 91 (2006) p.794-801, Single-crystal diffraction and transmission electron microscopy studies, of silicified pyrochlore from Narssarssk, Julianehaab district, Greenland, Locality: Narssarssk, Julianehaab district, Greenland, Sample: 396a
View Additional jPOWD Structure files for Pyrochlore
[1]
[2]
[3]
[4]
[5]
[6]
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Physical Properties of Pyrochlore
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Cleavage: |
[111] Indistinct, [111] Indistinct, [111] Indistinct |
Color: |
Brown, Yellowish brown, Yellow, Greenish brown, Reddish brown. |
Density: |
4.2 - 6.4, Average = 5.3 |
Diaphaniety: |
Subtranslucent to opaque |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Disseminated - Occurs in small, distinct particles dispersed in matrix. |
Habit: |
Granular - Generally occurs as anhedral to subhedral crystals in matrix. |
Hardness: |
5-5.5 - Apatite-Knife Blade |
Luminescence: |
None. |
Luster: |
Resinous - Greasy |
Streak: |
yellowish brown |
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Optical Properties of Pyrochlore
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Gladstone-Dale: |
CI meas= 0.208 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= 0.203 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1992,KPDmeas= 0.1981,KC= 0.2501 |
Optical Data: |
Isotropic, n=1.9-2.2. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Pyrochlore in Air
| λ |
R |
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∑ R(λ) |
| 400 nm |
11.30 |
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| 420 nm |
11.20 |
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| 440 nm |
11.10 |
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| 460 nm |
11.00 |
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| 480 nm |
11.00 |
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| 500 nm |
10.90 |
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| 520 nm |
10.80 |
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| 540 nm |
10.70 |
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| 560 nm |
10.60 |
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| 580 nm |
10.50 |
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| 600 nm |
10.50 |
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| 620 nm |
10.40 |
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| 640 nm |
10.40 |
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| 660 nm |
10.40 |
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| 680 nm |
10.40 |
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| 700 nm |
10.40 |
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Calculated Relative Intensity Colors of Pyrochlore in Air
Relative Intensity |
0% |
90% |
100% |
180% |
270% |
360% |
450% |
540% |
630% |
720% |
810% |
830% |
| R |
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Calculated Properties of Pyrochlore
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Electron Density: |
relectron=4.93 gm/cc note: rPyrochlore =5.27 gm/cc. |
Fermion Index |
Fermion Index = 0.00022 Boson Index = 0.99978 |
Photoelectric: |
PEPyrochlore = 80.27 barns/electron U=PEPyrochlore x relectron= 395.72 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Pyrochlore is Not Radioactive |
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Pyrochlore Classification
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Dana Class: |
8.2.1.1 (8)Multiple Oxides with Nb, Ta, and Ti |
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(8.2)where (A)2 (B2O6) (O,OH,F) |
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(8.2.1)Pyrochlore Group (Pyrochlore Subgroup; Nb>Ta;(Nb+Ta)>2(Ti) |
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8.2.1.1 Pyrochlore (Na,Ca)2Nb2O6(OH,F) F d3m 4/m 3 2/m |
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8.2.1.2 Kalipyrochlore (H2O,Sr)(Nb,Ti)(O,OH)6·(H2O,K) F d3m 4/m 3 2/m |
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8.2.1.3 Bariopyrochlore (Ba,Sr)(Nb,Ti)2(O,OH)7 F d3m 4/m 3 2/m |
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8.2.1.4 Yttropyrochlore-(Y) (Y,Na,Ca,U)1-2(Nb,Ta,Ti)2(O,OH)7 F d3m 2/m 3 |
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8.2.1.5 Ceriopyrochlore-(Ce) (Ce,Ca,Y)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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8.2.1.6 Plumbopyrochlore (Pb,Y,U,Ca)2-xNb2O6(OH) F d3m 4/m 3 2/m |
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8.2.1.7 Uranpyrochlore (U,Ca,Ce)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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8.2.1.8 Strontiopyrochlore* Sr2Nb2(O,OH)7 F d3m 4/m 3 2/m |
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8.2.1.9 Bismutopyrochlore! (Bi,U,Ca,Pb)1x(Nb,Ta)2O6(OH)·n(H2O) F d3m 4/m 3 2/m |
Strunz Class: |
IV/C.17-10 IV - Oxides |
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IV/C - Oxides with metal : oxygen = 2:3 (M2O3 and related compounds) |
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IV/C.17 - Pyrochlore group, Pyrochlore series with Nb > Ti |
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IV/C.17-10 Pyrochlore (Na,Ca)2Nb2O6(OH,F) F d3m 4/m 3 2/m |
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IV/C.17-20 Calciobetafite Ca2(Ti,Nb)2(O,OH)7 F d3m 4/m 3 2/m |
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IV/C.17-30 Kalipyrochlore (H2O,Sr)(Nb,Ti)(O,OH)6·(H2O,K) F d3m 4/m 3 2/m |
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IV/C.17-40 Strontiopyrochlore* Sr2Nb2(O,OH)7 F d3m 4/m 3 2/m |
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IV/C.17-50 Bariopyrochlore (Ba,Sr)(Nb,Ti)2(O,OH)7 F d3m 4/m 3 2/m |
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IV/C.17-60 Yttropyrochlore-(Y) (Y,Na,Ca,U)1-2(Nb,Ta,Ti)2(O,OH)7 F d3m 2/m 3 |
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IV/C.17-70 Ceriopyrochlore-(Ce) (Ce,Ca,Y)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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IV/C.17-80 Plumbopyrochlore (Pb,Y,U,Ca)2-xNb2O6(OH) F d3m 4/m 3 2/m |
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IV/C.17-85 Bismutopyrochlore! (Bi,U,Ca,Pb)1x(Nb,Ta)2O6(OH)·n(H2O) F d3m 4/m 3 2/m |
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IV/C.17-90 Uranpyrochlore (U,Ca,Ce)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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Other Pyrochlore Information
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References: |
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Pyrochlore :
1 - Alkali-Nuts(English)
2 - Alkali-Nuts(Francais)
3 -Am. Min. Crystal Structure Database
4 - Amethyst Galleries' Mineral Gallery
5 -Athena
6 - Crocoite.com Mineral Locations
7 - EUROmin Project
8 -Google Images
9 -Google Scholar
10 -Handbook of Mineralogy (UofA)
11 -MinDAT
12 -MinMax(Deutsch)
13 -MinMax(English)
14 -Mineralienatlas (Deutsch)
15 - Minerals of Wisconsin
16 -QUT Mineral Atlas
17 - WWW-MINCRYST
18 -École des Mines de Paris
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Pyrochlore
(Na,Ca)2Nb2O6(OH,F)
Dana No: 8.2.1.1 Strunz No: IV/C.17-10
Locality:
Notes:
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