General Plumbopyrochlore Information
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Chemical Formula: |
(Pb,Y,U,Ca)2-xNb2O6(OH) |
Composition: |
Molecular Weight = 484.00 gm |
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Calcium 0.83 % Ca 1.16 % CaO |
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Yttrium 3.67 % Y 4.67 % Y2O3 |
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Uranium 4.92 % U 5.91 % UO3 |
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Tantalum 3.74 % Ta 4.56 % Ta2O5 |
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Niobium 26.87 % Nb 38.44 % Nb2O5 |
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Iron 2.31 % Fe 2.97 % FeO |
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Silicon 1.16 % Si 2.48 % SiO2 |
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Hydrogen 0.10 % H 0.93 % H2O |
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Lead 34.25 % Pb 36.89 % PbO |
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Oxygen 22.15 % O |
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______ ______ |
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100.00 % 98.02 % = TOTAL OXIDE |
Empirical Formula: |
Pb0.8Y0.2U0.1Ca0.1Nb1.4Si0.2Fe2+0.2Ta0.1O6.2(OH)0.5 |
Environment: |
Metasomatically altered granitic rocks. |
IMA Status: |
Approved IMA 1966 |
Locality: |
Undisclosed locality in the Northern Ural Mountains, Russia. Link to MinDat.org Location Data. |
Name Origin: |
For lead, PLUMBum, in its composition and its relationship to pyrochlore. |
Synonym: |
ICSD 45816 |
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PDF 25-453 |
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Plumbopyrochlore Image |
Images:
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Images:
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Plumbopyrochlore Crystallography
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Cell Dimensions: |
a = 10.534, Z = 8; V = 1,168.91 Den(Calc)= 5.50 |
Crystal System: |
Isometric - HexoctahedralH-M Symbol (4/m 3 2/m) Space Group: F d3m |
X Ray Diffraction: |
By Intensity(I/Io): 3.02(1), 1.581(0.9), 1.861(0.9), |
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Physical Properties of Plumbopyrochlore
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Cleavage: |
None |
Color: |
Brown, Greenish yellow, Dark brown, Red. |
Density: |
5.04 |
Diaphaniety: |
Translucent to Opaque |
Fracture: |
Brittle - Uneven - Very brittle fracture producing uneven fragments. |
Habit: |
Octahedral Crystals - Occurs as octahedral shaped crystals. |
Hardness: |
4.5-5.5 - Near Apatite |
Luster: |
Vitreous - Resinous |
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Optical Properties of Plumbopyrochlore
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Gladstone-Dale: |
CI meas= -0.126 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= -0.032 (Excellent) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1964,KPDmeas= 0.2143,KC= 0.1902 |
Optical Data: |
Isotropic, n=2.08. |
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Calculated Properties of Plumbopyrochlore
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Electron Density: |
relectron=4.80 gm/cc note: rPlumbopyrochlore =5.50 gm/cc. |
Fermion Index |
Fermion Index = 0.07719 Boson Index = 0.92281 |
Photoelectric: |
PEPlumbopyrochlore = 823.00 barns/electron U=PEPlumbopyrochlore x relectron=3,954.14 barns/cc. |
Radioactivity: |
GRapi = 366,187.63 (Gamma Ray American Petroleum Institute Units)
Plumbopyrochlore is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
83.06 ± 20.77 grams of pure Plumbopyrochlore .
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 100 cm box)
8306.3 ±2076.6 grams of pure Plumbopyrochlore .
Estimated Radioactivity from Plumbopyrochlore - strong
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.03 cm |
8,803,095 |
2.38E-04 |
366,187.63 |
120.39 |
| 100 gm / 3.26 cm |
880,310 |
2.38E-05 |
36,618.76 |
12.04 |
| 10 gm / 1.51 cm |
88,031 |
2.38E-06 |
3,661.88 |
1.20 |
| 1 gm / 7.03 mm |
8,803 |
2.38E-07 |
366.19 |
0.12 |
| 0.1 gm / 3.26 mm |
880 |
2.38E-08 |
36.62 |
0.01 |
| 0.01 gm / 1.51 mm |
88 |
2.38E-09 |
3.66 |
0.00 |
| 0.001 gm / 0.70 mm |
9 |
2.38E-10 |
0.37 |
0.00 |
Weight of pure Plumbopyrochlore in grams (gm) and Calculated Diameter of a Sphere with a Density of 5.50 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
**
Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
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Plumbopyrochlore Classification
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Dana Class: |
8.2.1.6 (8)Multiple Oxides with Nb, Ta, and Ti |
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(8.2)where (A)2 (B2O6) (O,OH,F) |
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(8.2.1)Pyrochlore Group (Pyrochlore Subgroup; Nb>Ta;(Nb+Ta)>2(Ti) |
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8.2.1.1 Pyrochlore (Na,Ca)2Nb2O6(OH,F) F d3m 4/m 3 2/m |
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8.2.1.2 Kalipyrochlore (H2O,Sr)(Nb,Ti)(O,OH)6·(H2O,K) F d3m 4/m 3 2/m |
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8.2.1.3 Bariopyrochlore (Ba,Sr)(Nb,Ti)2(O,OH)7 F d3m 4/m 3 2/m |
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8.2.1.4 Yttropyrochlore-(Y) (Y,Na,Ca,U)1-2(Nb,Ta,Ti)2(O,OH)7 F d3m 2/m 3 |
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8.2.1.5 Ceriopyrochlore-(Ce) (Ce,Ca,Y)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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8.2.1.6 Plumbopyrochlore (Pb,Y,U,Ca)2-xNb2O6(OH) F d3m 4/m 3 2/m |
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8.2.1.7 Uranpyrochlore (U,Ca,Ce)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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8.2.1.8 Strontiopyrochlore* Sr2Nb2(O,OH)7 F d3m 4/m 3 2/m |
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8.2.1.9 Bismutopyrochlore! (Bi,U,Ca,Pb)1x(Nb,Ta)2O6(OH)·n(H2O) F d3m 4/m 3 2/m |
Strunz Class: |
IV/C.17-80 IV - Oxides |
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IV/C - Oxides with metal : oxygen = 2:3 (M2O3 and related compounds) |
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IV/C.17 - Pyrochlore group, Pyrochlore series with Nb > Ti |
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IV/C.17-10 Pyrochlore (Na,Ca)2Nb2O6(OH,F) F d3m 4/m 3 2/m |
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IV/C.17-20 Calciobetafite Ca2(Ti,Nb)2(O,OH)7 F d3m 4/m 3 2/m |
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IV/C.17-30 Kalipyrochlore (H2O,Sr)(Nb,Ti)(O,OH)6·(H2O,K) F d3m 4/m 3 2/m |
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IV/C.17-40 Strontiopyrochlore* Sr2Nb2(O,OH)7 F d3m 4/m 3 2/m |
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IV/C.17-50 Bariopyrochlore (Ba,Sr)(Nb,Ti)2(O,OH)7 F d3m 4/m 3 2/m |
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IV/C.17-60 Yttropyrochlore-(Y) (Y,Na,Ca,U)1-2(Nb,Ta,Ti)2(O,OH)7 F d3m 2/m 3 |
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IV/C.17-70 Ceriopyrochlore-(Ce) (Ce,Ca,Y)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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IV/C.17-80 Plumbopyrochlore (Pb,Y,U,Ca)2-xNb2O6(OH) F d3m 4/m 3 2/m |
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IV/C.17-85 Bismutopyrochlore! (Bi,U,Ca,Pb)1x(Nb,Ta)2O6(OH)·n(H2O) F d3m 4/m 3 2/m |
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IV/C.17-90 Uranpyrochlore (U,Ca,Ce)2(Nb,Ta)2O6(OH,F) F d3m 4/m 3 2/m |
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Other Plumbopyrochlore Information
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References: |
NAME( AntBidBlaNic3) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Plumbopyrochlore :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - Uranium Minerals
13 -École des Mines de Paris
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Plumbopyrochlore
(Pb,Y,U,Ca)2-xNb2O6(OH)
Dana No: 8.2.1.6 Strunz No: IV/C.17-80
Locality:
Notes:
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