General Grunerite Information
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Chemical Formula: |
[ ]Fe++7Si8O22(OH)2 |
Composition: |
Molecular Weight = 1,001.61 gm |
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Iron 39.03 % Fe 50.21 % FeO |
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Silicon 22.43 % Si 47.99 % SiO2 |
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Hydrogen 0.20 % H 1.80 % H2O |
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Oxygen 38.34 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Fe2+7(Si8O22)(OH)2 |
IMA Status: |
Valid Species (Pre-IMA) 1853 |
Locality: |
Link to MinDat.org Location Data. |
Name Origin: |
Named for Louis Emmanuel Gruner (1809-1883), Swiss-French chemist who analyzed the mineral. |
Synonym: |
Amosite |
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ICSD 24590 |
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PDF 44-1401 |
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Grunerite Image |
Images:
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Grunerite Crystallography
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Axial Ratios: |
a:b:c =0.5252:1:0.2925 |
Cell Dimensions: |
a = 9.57, b = 18.22, c = 5.33, Z = 2; beta = 102.1° V = 908.72 Den(Calc)= 3.66 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 2/m |
X Ray Diffraction: |
By Intensity(I/Io): 8.33(1), 2.77(0.9), 3.07(0.8), |
Crystal Structure:
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Finger L W , Mineralogical Society of America Special Paper , 2 (1969) p.95-100, The crystal structure and cation distribution of a grunerite, Locality: Wabush iron formation, Labrador, Canada
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Physical Properties of Grunerite
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Cleavage: |
[110] Perfect, [???] Distinct |
Color: |
Ashen, Brown, Brownish green, Dark gray. |
Density: |
3.4 - 3.5, Average = 3.45 |
Diaphaniety: |
Translucent to opaque |
Fracture: |
Sub Conchoidal - Fractures developed in brittle materials characterized by semi-curving surfaces. |
Habit: |
Columnar - Forms columns |
Habit: |
Fibrous - Crystals made up of fibers. |
Habit: |
Massive - Uniformly indistinguishable crystals forming large masses. |
Hardness: |
5-6 - Between Apatite and Orthoclase |
Luminescence: |
Non-fluorescent. |
Luster: |
Vitreous - Pearly |
Streak: |
colorless |
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Optical Properties of Grunerite
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Gladstone-Dale: |
CI meas= -0.004 (Superior) - where the CI = (1-KPDmeas/KC) CI calc= 0.054 (Good) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1896,KPDmeas= 0.2011,KC= 0.2003 |
Optical Data: |
Biaxial (-), a=1.663-1.686, b=1.68-1.709, g=1.696-1.729, bire=0.0330-0.0430, 2V(Calc)=84-86, 2V(Meas)=90-70. Dispersion r > v. |
Pleochroism (x): |
colorless, colorless, or pale yellow. |
Pleochroism (y): |
colorless, pale yellow, or yellowish gray. |
Pleochroism (z): |
colorless, pale green, pale yellow, or pale greenish yellow. |
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Calculated Properties of Grunerite
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Electron Density: |
relectron=3.36 gm/cc note: rGrunerite =3.45 gm/cc. |
Fermion Index |
Fermion Index = 0.01893 Boson Index = 0.98107 |
Photoelectric: |
PEGrunerite = 12.52 barns/electron U=PEGrunerite x relectron= 42.08 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Grunerite is Not Radioactive |
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Grunerite Classification
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Dana Class: |
66.1.1.3 (66)Inosilicate Double-Width Unbranched Chains, W=2 |
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(66.1)Dana Type |
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(66.1.1)Group 1, the Mg-Fe-Mn-Li amphiboles (Monoclinic) |
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66.1.1.1 Magnesiocummingtonite (Mg,Fe)7Si8O22(OH)2 C 2/m 2/m |
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66.1.1.2 Cummingtonite []Mg7Si8O22(OH)2 C 2/m 2/m |
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66.1.1.3 Grunerite []Fe7Si8O22(OH)2 C 2/m 2/m |
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66.1.1.3b Permanganogrunerite! []Mn4(Fe)3(Si8O22)(OH)2 C 2/m 2/m |
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66.1.1.4 Manganocummingtonite Na(Na,Mn)2(Mg4,Fe)5Si8O22(OH)2 C 2/m 2/m |
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66.1.1.5 Manganogrunerite []Mn2Fe5Si8O22(OH) C 2/m 2/m |
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66.1.1.6 Magnesioclinoholmquistite? Li2(Mg,Fe)3Al2Si8O22(OH)2 C 2/m 2/m |
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66.1.1.7 Clinoholmquistite? [](Li2Mg3Al2)Si8O22(OH)2 C 2/m 2/m |
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66.1.1.8 Clinoferroholmquistite [](Li2Fe3Al2)Si8O22(OH)2 C 2/m 2/m |
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66.1.1.8a Ferri-clinoholmquistite! []Li2Mg3(Fe3)2(Si8O22)(OH)2 C 2/m 2/m |
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66.1.1.8b Ferri-clinoferroholmquistite! []Li2(Fe2Fe3)Si8O22(OH)2 C 2/m 2/m |
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66.1.1.9 Sodic-ferripedrizite! Na(LiNa)(Fe2Mg2Li)Si8O22(OH,F)2 C 2/m 2/m |
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66.1.1.9a Ferripedrizite! NaLi2(Fe2Mg2Li)Si8O22(OH)2 C 2/m 2/m |
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66.1.1.9b Sodic-ferri-ferropedrizite! NaLi2(Fe2Fe3)Si8O22(OH)2 C 2/m 2/m |
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66.1.1.9c Fluoro-sodic-pedrizite! NaLi2(Mg2Al2Li)S5Si8O22F2 C 2/m 2/m |
Strunz Class: |
VIII/F.07-30 VIII - Silicates |
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VIII/F - Inosilicates (chain and band) double chains [Si4O11]6- , Mg-Fe-Mn-Amphiboles |
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VIII/F.07 - Amphibole group, Magnesiocummingtonite - Ferroclinoholmquistite series |
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VIII/F.07-10 Magnesiocummingtonite (Mg,Fe)7Si8O22(OH)2 C 2/m 2/m |
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VIII/F.07-20 Cummingtonite []Mg7Si8O22(OH)2 C 2/m 2/m |
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VIII/F.07-30 Grunerite []Fe7Si8O22(OH)2 C 2/m 2/m |
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VIII/F.07-40 Manganocummingtonite Na(Na,Mn)2(Mg4,Fe)5Si8O22(OH)2 C 2/m 2/m |
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VIII/F.07-50 Manganogrunerite []Mn2Fe5Si8O22(OH) C 2/m 2/m |
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VIII/F.07-55 Permanganogrunerite! []Mn4(Fe)3(Si8O22)(OH)2 C 2/m 2/m |
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VIII/F.07-60 Magnesioclinoholmquistite? Li2(Mg,Fe)3Al2Si8O22(OH)2 C 2/m 2/m |
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VIII/F.07-70 Clinoholmquistite? [](Li2Mg3Al2)Si8O22(OH)2 C 2/m 2/m |
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VIII/F.07-80 Clinoferroholmquistite [](Li2Fe3Al2)Si8O22(OH)2 C 2/m 2/m |
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VIII/F.07-90 Ferri-clinoferroholmquistite! []Li2(Fe2Fe3)Si8O22(OH)2 C 2/m 2/m |
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Other Grunerite Information
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References: |
NAME( Dana8) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Heinrich65) |
See Also: |
Links to other databases for Grunerite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - CalTech Mineral Spectroscopy
4 - EUROmin Project
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (MinSocAm)
8 -Handbook of Mineralogy (UofA)
9 - HyperPhysics
10 -MinDAT
11 -MinMax(Deutsch)
12 -MinMax(English)
13 -Mineralienatlas (Deutsch)
14 - Minerals of Wisconsin
15 -QUT Mineral Atlas
16 - WWW-MINCRYST
17 -École des Mines de Paris
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Grunerite
[ ]Fe++7Si8O22(OH)2
Dana No: 66.1.1.3 Strunz No: VIII/F.07-30
Locality:
Notes:
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