General Pseudobrookite Information
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Chemical Formula: |
(Fe+++,Fe++)2(Ti,Fe++)O5 |
Composition: |
Molecular Weight = 238.41 gm |
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Magnesium 1.02 % Mg 1.69 % MgO |
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Titanium 15.06 % Ti 25.13 % TiO2 |
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Iron 50.36 % Fe 19.59 % FeO / 50.24 % Fe2O3 |
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Oxygen 33.55 % O |
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______ ______ |
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100.00 % 96.64 % = TOTAL OXIDE |
Empirical Formula: |
Fe3+1.5Fe2+0.4Mg0.1Ti0.75Fe2+0.25O5 |
Environment: |
Magmatic, post-volcanic or young volcanic rocks. |
IMA Status: |
Valid Species (Pre-IMA) 1878 |
Locality: |
Vesuvius and Etna, Italy. Link to MinDat.org Location Data. |
Name Origin: |
From the Greek pseudo - "I mislead" and the mineral brookite. |
Synonym: |
ICSD 69038 |
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PDF 41-1432 |
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Pseudobrookite Image |
Images:
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Pseudobrookite Crystallography
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Axial Ratios: |
a:b:c =0.9859:1:0.3751 |
Cell Dimensions: |
a = 9.79, b = 9.93, c = 3.725, Z = 4; V = 362.12 Den(Calc)= 4.37 |
Crystal System: |
Orthorhombic - DipyramidalH-M Symbol (2/m 2/m 2/m) Space Group: Bbmm |
X Ray Diffraction: |
By Intensity(I/Io): 3.483(1), 2.748(0.8), 4.902(0.45), |
Forms:
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Forms:
[ 1 2 1]
[ 0 1 0]
[ 1 1 1]
[ 2 1 0]
[ 1 0 1]
[ 1 1 0]
[ 1 0 0]
[ 1 2 0]
[ 1 3 1]
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Crystal Structure:
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Yang H , Hazen R M , American Mineralogist , 84 (1999) p.130-137, Comparative high-pressure crystal chemistry of karrooite, MgTi2O5, with, different ordering states, Sample P600, x(Ti) in M1 = .070, P = 0 GPa
View Additional jPOWD Structure files for Pseudobrookite
[1]
[10]
[11]
[12]
[13]
[2]
[3]
[4]
[5]
[6]
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[8]
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Physical Properties of Pseudobrookite
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Cleavage: |
[010] Poor |
Color: |
Brownish black, Reddish brown, Black. |
Density: |
4.4 |
Diaphaniety: |
Opaque |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Crystalline - Fine - Occurs as well-formed fine sized crystals. |
Hardness: |
6 - Orthoclase |
Luminescence: |
Non-fluorescent. |
Luster: |
Adamantine - Metallic |
Streak: |
brown |
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Optical Properties of Pseudobrookite
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Optical Data: |
Biaxial (+), a=2.35-2.38, b=2.36-2.39, g=2.38-2.42, bire=0.0300-0.0400, 2V(Calc)=62-72, 2V(Meas)=50. |
Pleochroism (x): |
yellowish brown. |
Pleochroism (y): |
brown. |
Pleochroism (z): |
reddish brown. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Pseudobrookite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
22.80 |
24.00 |

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| 420 nm |
21.90 |
23.10 |

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| 440 nm |
21.30 |
22.30 |

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| 460 nm |
20.50 |
21.40 |

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| 480 nm |
19.80 |
20.70 |

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| 500 nm |
19.40 |
20.40 |

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| 520 nm |
19.00 |
19.90 |

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| 540 nm |
18.50 |
19.30 |

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| 560 nm |
18.10 |
18.80 |

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| 580 nm |
17.80 |
18.50 |

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| 600 nm |
17.50 |
18.10 |

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| 620 nm |
17.30 |
17.90 |

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| 640 nm |
17.10 |
17.70 |

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| 660 nm |
17.00 |
17.60 |

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| 680 nm |
16.80 |
17.40 |

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| 700 nm |
16.70 |
17.30 |

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Calculated Relative Intensity Colors of Pseudobrookite in Air
Relative Intensity |
0% |
50% |
100% |
150% |
200% |
250% |
300% |
350% |
400% |
450% |
490% |
| R1 |
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Calculated Properties of Pseudobrookite
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Electron Density: |
relectron=4.16 gm/cc note: rPseudobrookite =4.37 gm/cc. |
Fermion Index |
Fermion Index = 0.03133 Boson Index = 0.96867 |
Photoelectric: |
PEPseudobrookite = 17.92 barns/electron U=PEPseudobrookite x relectron= 74.62 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Pseudobrookite is Not Radioactive |
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Pseudobrookite Classification
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Dana Class: |
7.7.1.1 (7)Multiple Oxides |
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(7.7)with miscellaneous formulae |
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(7.7.1)Dana Group |
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7.7.1.1 Pseudobrookite (Fe,Fe)2(Ti,Fe)O5 Bbmm 2/m 2/m 2/m |
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7.7.1.2 Armalcolite (Mg,Fe)Ti2O5 Bbmm 2/m 2/m 2/m |
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7.7.1.3 IMA2000-016! (Ti,Fe,Mg,Mn)1-xTi2O5 Pban 2/m 2/m 2/m |
Strunz Class: |
IV/C.24-20 IV - Oxides |
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IV/C - Oxides with metal : oxygen = 2:3 (M2O3 and related compounds) |
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IV/C.24 - Aramcolite - Arizonite series |
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IV/C.24-10 Armalcolite (Mg,Fe)Ti2O5 Bbmm 2/m 2/m 2/m |
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IV/C.24-20 Pseudobrookite (Fe,Fe)2(Ti,Fe)O5 Bbmm 2/m 2/m 2/m |
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IV/C.24-30 Pseudorutile Fe2Ti3O9 P 322 3 2 |
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Other Pseudobrookite Information
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References: |
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Pseudobrookite :
1 -Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 -Athena
4 - Crocoite.com Mineral Locations
5 - EUROmin Project
6 -Google Images
7 -Google Scholar
8 -Handbook of Mineralogy (UofA)
9 - HyperPhysics
10 -MinDAT
11 -MinMax(Deutsch)
12 -MinMax(English)
13 -Mineralienatlas (Deutsch)
14 -QUT Mineral Atlas
15 -University of Colorado - Mineral Structure Data
16 - University of Manchester - Mineral Structure
17 - WWW-MINCRYST
18 -École des Mines de Paris
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Print or Cut-and-Paste your Pseudobrookite Specimen Label here :
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Pseudobrookite
(Fe+++,Fe++)2(Ti,Fe++)O5
Dana No: 7.7.1.1 Strunz No: IV/C.24-20
Locality:
Notes:
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