General Kotulskite Information
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Chemical Formula: |
Pd(Te,Bi) |
Composition: |
Molecular Weight = 254.37 gm |
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Bismuth 20.54 % Bi |
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Tellurium 37.62 % Te |
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Palladium 41.84 % Pd |
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______ |
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100.00 % |
Empirical Formula: |
PdTe0.75Bi0.25 |
Environment: |
As grains in chalcopyrite veins cutting magnetite. |
IMA Status: |
Approved IMA 1963 |
Locality: |
Monchegorsk, Lake Imandra, Murmansk, Kola peninsula, Russia Link to MinDat.org Location Data. |
Name Origin: |
Named for Vladimir Klement'evich Kotul'skii, economic geologist and an authority on Cu-Ni sulfide deposits. |
Synonym: |
ICSD 42552 |
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PDF 29-971 |
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Kotulskite Image |
Images:
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Kotulskite Telluropalladinite Keithconnite
Comments: Polyphase grain of (1) ferroan platinum corroded by (2) Pt(Fe,Cu) and overgrown by (5) telluropalladinite, an unknown (6) Pd-Te-Fe-Si-O phase, (7) Fe-hydroxide and (8) a Ca-Mn-Fe silicate with inclusions of (3) kotulskite and (4) keithconnite. (BGR).
Location: Stream sediments of rivers in the vicinity of the original discovery of the Merensky Reef on the farm Maandagshoek close to Burgersfort in the Eastern Bushveld, South Africa..
Scale: See Image.
© Federal Institute for Geosciences and Natural Resources |
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Kotulskite Crystallography
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Axial Ratios: |
a:c = 1:1.35322 |
Cell Dimensions: |
a = 4.19, c = 5.67, Z = 2; V = 86.21 Den(Calc)= 9.80 |
Crystal System: |
Hexagonal - Dihexagonal DipyramidalH-M Symbol (6/m 2/m 2/m) Space Group: P 63/mmc |
X Ray Diffraction: |
By Intensity(I/Io): 3.05(1), 2.09(0.9), 2.24(0.9), |
Crystal Structure:
Mouse
drag1 - LMB Manipulate Structure
drag2 - RMB Resize/Rotate
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H - Help Screen
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Help on Above
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Wyckoff R W G , Crystal Structures , 1 (1963) p.85-237, Second edition. Interscience Publishers, New York, New York, Note: ideal nickel arsenide structure
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Physical Properties of Kotulskite
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Cleavage: |
None |
Color: |
Gray, Steel gray. |
Density: |
8.26 |
Diaphaniety: |
Opaque |
Habit: |
Inclusions - Generally found as inclusions in other minerals. |
Hardness: |
4-4.5 - Between Fluorite and Apatite |
Luster: |
Metallic |
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Optical Properties of Kotulskite
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RL Anisotrophism: |
Strong, from gray to dark bluish gray. |
RL Color: |
Cream or pale yellow. |
RL Pleochroism: |
Distinct, from light cream to darker grayish cream. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Kotulskite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
36.40 |
33.60 |

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| 420 nm |
41.50 |
41.50 |

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| 440 nm |
46.60 |
49.40 |

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| 460 nm |
50.20 |
54.80 |

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| 480 nm |
53.40 |
59.50 |

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| 500 nm |
56.00 |
63.10 |

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| 520 nm |
58.20 |
65.60 |

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| 540 nm |
59.60 |
67.40 |

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| 560 nm |
60.70 |
68.50 |

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| 580 nm |
61.20 |
69.00 |

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| 600 nm |
61.50 |
69.30 |

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| 620 nm |
61.90 |
69.70 |

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| 640 nm |
62.30 |
70.20 |

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| 660 nm |
62.80 |
70.80 |

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| 680 nm |
63.30 |
71.40 |

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| 700 nm |
63.90 |
72.00 |

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Calculated Relative Intensity Colors of Kotulskite in Air
Relative Intensity |
0% |
20% |
40% |
60% |
80% |
100% |
120% |
140% |
160% |
180% |
190% |
| R1 |
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| R2 |
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Calculated Properties of Kotulskite
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Electron Density: |
relectron=8.15 gm/cc note: rKotulskite =9.80 gm/cc. |
Fermion Index |
Fermion Index = 0.12348 Boson Index = 0.87652 |
Photoelectric: |
PEKotulskite = 641.58 barns/electron U=PEKotulskite x relectron=5,227.95 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Kotulskite is Not Radioactive |
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Kotulskite Classification
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Dana Class: |
2.8.11.6 (2)Sulfides - Including Selenides and Tellurides |
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(2.8)where Am Bn Xp, with (m+n):p=1:1 |
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(2.8.11)Nickeline Group (Hexagonal: P63/mmc) |
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2.8.11.1 Nickeline NiAs P 63/mmc 6/m 2/m 2/m |
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2.8.11.2 Breithauptite NiSb P 63/mmc 6/m 2/m 2/m |
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2.8.11.3 Sederholmite NiSe P 63/mmc 6/m 2/m 2/m |
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2.8.11.4 Hexatestibiopanickelite (Ni,Pd)(Te,Sb) P 63/mmc 6/m 2/m 2/m |
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2.8.11.5 Sudburyite (Pd,Ni)Sb P 63/mmc 6/m 2/m 2/m |
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2.8.11.6 Kotulskite Pd(Te,Bi) P 63/mmc 6/m 2/m 2/m |
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2.8.11.7 Sobolevskite PdBi P 63/mmc 6/m 2/m 2/m |
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2.8.11.8 Stumpflite Pt(Sb,Bi) P 63/mmc 6/m 2/m 2/m |
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2.8.11.9 Langisite (Co,Ni)As P 63/mmc 6/m 2/m 2/m |
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2.8.11.10 Freboldite CoSe P 63/mmc 6/m 2/m 2/m |
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2.8.11.11 Sorosite! Cu(Sn,Sb) P 63/mmc 6/m 2/m 2/m |
Strunz Class: |
II/C.20-80 II - Sulfides and sulphosalts |
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II/C - Sulfides with metal: sulfur, selenium and tellurium = 1:1 |
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II/C.20 - Nickeline group and related compounds, Polarite - Cherepanovite series |
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II/C.20-05 Sorosite! Cu(Sn,Sb) P 63/mmc 6/m 2/m 2/m |
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II/C.20-10 Langisite (Co,Ni)As P 63/mmc 6/m 2/m 2/m |
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II/C.20-20 Nickeline NiAs P 63/mmc 6/m 2/m 2/m |
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II/C.20-30 Breithauptite NiSb P 63/mmc 6/m 2/m 2/m |
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II/C.20-40 Freboldite CoSe P 63/mmc 6/m 2/m 2/m |
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II/C.20-50 Sederholmite NiSe P 63/mmc 6/m 2/m 2/m |
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II/C.20-70 Hexatestibiopanickelite (Ni,Pd)(Te,Sb) P 63/mmc 6/m 2/m 2/m |
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II/C.20-75 Yuanjiangite AuSn P 63/mmc 6/m 2/m 2/m |
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II/C.20-80 Kotulskite Pd(Te,Bi) P 63/mmc 6/m 2/m 2/m |
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II/C.20-90 Sudburyite (Pd,Ni)Sb P 63/mmc 6/m 2/m 2/m |
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II/C.20-95 Stumpflite Pt(Sb,Bi) P 63/mmc 6/m 2/m 2/m |
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II/C.20-100 Polarite Pd(Bi,Pb) Ccm21 mm2 |
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II/C.20-110 Sobolevskite PdBi P 63/mmc 6/m 2/m 2/m |
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II/C.20-120 Ruthenarsenite (Ru,Ni)As P nma 2/m 2/m 2/m |
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II/C.20-130 Cherepanovite RhAs P nma 2/m 2/m 2/m |
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Other Kotulskite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Kotulskite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - WWW-MINCRYST
13 -École des Mines de Paris
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Kotulskite
Pd(Te,Bi)
Dana No: 2.8.11.6 Strunz No: II/C.20-80
Locality:
Notes:
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