General Breithauptite Information
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Chemical Formula: |
NiSb |
Composition: |
Molecular Weight = 180.44 gm |
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Nickel 32.53 % Ni |
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Antimony 67.47 % Sb |
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______ |
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100.00 % |
Empirical Formula: |
NiSb |
Environment: |
In hydrothermal calcite veins associated with Co-Ni-Ag ores. |
IMA Status: |
Valid Species (Pre-IMA) 1845 |
Locality: |
From the Cobalt district, near Red Lake; in the Silver Islet mine and the Hemlo gold deposit, Thunder Bay district, Ontario, Canada. Link to MinDat.org Location Data. |
Name Origin: |
After the Saxon mineralogist Johann Friedrich August Breithaupt (1791-1873). |
Synonym: |
ICSD 293304 |
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PDF 41-1439 |
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Breithauptite Image |
Images:
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Breithauptite Crystallography
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Axial Ratios: |
a:c = 1:1.30534 |
Cell Dimensions: |
a = 3.93, c = 5.13, Z = 2; V = 68.62 Den(Calc)= 8.73 |
Crystal System: |
Hexagonal - Dihexagonal DipyramidalH-M Symbol (6/m 2/m 2/m) Space Group: P 63/mmc |
X Ray Diffraction: |
By Intensity(I/Io): 2.86(1), 1.97(0.4), 2.05(0.4), |
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Crystal Structure:
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Wyckoff R W G , Crystal Structures , 1 (1963) p.85-237, Second edition. Interscience Publishers, New York, New York, Note: ideal nickel arsenide structure
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Physical Properties of Breithauptite
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Cleavage: |
None |
Color: |
Copper red, Light brown red. |
Density: |
8.23 |
Diaphaniety: |
Opaque |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Massive - Uniformly indistinguishable crystals forming large masses. |
Habit: |
Reniform - "Kidney like" in shape (e.g.. hematite). |
Habit: |
Tabular - Form dimensions are thin in one direction. |
Hardness: |
3.5-4 - Copper Penny-Fluorite |
Luminescence: |
None. |
Luster: |
Metallic |
Magnetism: |
Nonmagnetic |
Streak: |
reddish brown |
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Optical Properties of Breithauptite
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RL Anisotrophism: |
Very noticeable in air and oil. |
RL Color: |
Light copper red with violet tint. |
RL Pleochroism: |
Very distinct. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Breithauptite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
47.80 |
51.40 |

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| 420 nm |
45.50 |
49.30 |

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| 440 nm |
43.20 |
47.20 |

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| 460 nm |
41.10 |
45.80 |

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| 480 nm |
39.50 |
45.20 |

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| 500 nm |
38.50 |
45.60 |

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| 520 nm |
38.70 |
46.80 |

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| 540 nm |
41.00 |
48.60 |

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| 560 nm |
43.60 |
51.10 |

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| 580 nm |
46.60 |
53.40 |

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| 600 nm |
49.30 |
55.60 |

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| 620 nm |
51.60 |
57.60 |

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| 640 nm |
53.60 |
59.30 |

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| 660 nm |
55.30 |
60.90 |

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| 680 nm |
56.80 |
62.20 |

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| 700 nm |
58.00 |
63.30 |

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Calculated Relative Intensity Colors of Breithauptite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
| R1 |
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| R2 |
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Calculated Properties of Breithauptite
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Electron Density: |
relectron=7.64 gm/cc note: rBreithauptite =8.73 gm/cc. |
Fermion Index |
Fermion Index = 0.00367 Boson Index = 0.99633 |
Photoelectric: |
PEBreithauptite = 240.90 barns/electron U=PEBreithauptite x relectron=1,841.50 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Breithauptite is Not Radioactive |
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Breithauptite Classification
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Dana Class: |
2.8.11.2 (2)Sulfides - Including Selenides and Tellurides |
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(2.8)where Am Bn Xp, with (m+n):p=1:1 |
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(2.8.11)Nickeline Group (Hexagonal: P63/mmc) |
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2.8.11.1 Nickeline NiAs P 63/mmc 6/m 2/m 2/m |
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2.8.11.2 Breithauptite NiSb P 63/mmc 6/m 2/m 2/m |
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2.8.11.3 Sederholmite NiSe P 63/mmc 6/m 2/m 2/m |
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2.8.11.4 Hexatestibiopanickelite (Ni,Pd)(Te,Sb) P 63/mmc 6/m 2/m 2/m |
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2.8.11.5 Sudburyite (Pd,Ni)Sb P 63/mmc 6/m 2/m 2/m |
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2.8.11.6 Kotulskite Pd(Te,Bi) P 63/mmc 6/m 2/m 2/m |
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2.8.11.7 Sobolevskite PdBi P 63/mmc 6/m 2/m 2/m |
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2.8.11.8 Stumpflite Pt(Sb,Bi) P 63/mmc 6/m 2/m 2/m |
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2.8.11.9 Langisite (Co,Ni)As P 63/mmc 6/m 2/m 2/m |
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2.8.11.10 Freboldite CoSe P 63/mmc 6/m 2/m 2/m |
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2.8.11.11 Sorosite! Cu(Sn,Sb) P 63/mmc 6/m 2/m 2/m |
Strunz Class: |
II/C.20-30 II - Sulfides and sulphosalts |
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II/C - Sulfides with metal: sulfur, selenium and tellurium = 1:1 |
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II/C.20 - Nickeline group and related compounds, Polarite - Cherepanovite series |
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II/C.20-05 Sorosite! Cu(Sn,Sb) P 63/mmc 6/m 2/m 2/m |
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II/C.20-10 Langisite (Co,Ni)As P 63/mmc 6/m 2/m 2/m |
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II/C.20-20 Nickeline NiAs P 63/mmc 6/m 2/m 2/m |
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II/C.20-30 Breithauptite NiSb P 63/mmc 6/m 2/m 2/m |
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II/C.20-40 Freboldite CoSe P 63/mmc 6/m 2/m 2/m |
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II/C.20-50 Sederholmite NiSe P 63/mmc 6/m 2/m 2/m |
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II/C.20-70 Hexatestibiopanickelite (Ni,Pd)(Te,Sb) P 63/mmc 6/m 2/m 2/m |
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II/C.20-75 Yuanjiangite AuSn P 63/mmc 6/m 2/m 2/m |
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II/C.20-80 Kotulskite Pd(Te,Bi) P 63/mmc 6/m 2/m 2/m |
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II/C.20-90 Sudburyite (Pd,Ni)Sb P 63/mmc 6/m 2/m 2/m |
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II/C.20-95 Stumpflite Pt(Sb,Bi) P 63/mmc 6/m 2/m 2/m |
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II/C.20-100 Polarite Pd(Bi,Pb) Ccm21 mm2 |
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II/C.20-110 Sobolevskite PdBi P 63/mmc 6/m 2/m 2/m |
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II/C.20-120 Ruthenarsenite (Ru,Ni)As P nma 2/m 2/m 2/m |
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II/C.20-130 Cherepanovite RhAs P nma 2/m 2/m 2/m |
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Other Breithauptite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Breithauptite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 - Franklin Minerals(Dunn)
6 -Google Images
7 -Google Scholar
8 -Handbook of Mineralogy (UofA)
9 -MinDAT
10 -MinMax(Deutsch)
11 -MinMax(English)
12 -Mineralienatlas (Deutsch)
13 -QUT Mineral Atlas
14 - WWW-MINCRYST
15 -École des Mines de Paris
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Print or Cut-and-Paste your Breithauptite Specimen Label here :
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Breithauptite
NiSb
Dana No: 2.8.11.2 Strunz No: II/C.20-30
Locality:
Notes:
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