General Ferriallanite-(Ce) Information
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Chemical Formula: |
CaCe(Fe+++,Fe++,Al)3[SiO4][Si2O7]O(OH) |
Composition: |
Molecular Weight = 613.85 gm |
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Calcium 7.05 % Ca 9.87 % CaO |
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Cerium 21.00 % Ce 24.60 % Ce2O3 |
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Titanium 1.09 % Ti 1.82 % TiO2 |
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Manganese 0.63 % Mn 0.81 % MnO |
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Aluminum 2.99 % Al 5.65 % Al2O3 |
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Iron 19.74 % Fe 10.89 % FeO / 16.13 % Fe2O3 |
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Silicon 13.45 % Si 28.78 % SiO2 |
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Hydrogen 0.16 % H 1.47 % H2O |
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Oxygen 33.88 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Ca0.97Ce0.03Ce0.89Ca0.11Fe3+0.8Ti0.14Al0.06Al0.56Fe3+0.44Fe2+0.93Mn2+0.07Si0.94
Al0.06O4(Si2O7)O(OH) |
Environment: |
In an alkaline granitic pegmatite. |
IMA Status: |
Approved IMA 2002 (Dana # Added) |
Locality: |
Mount Ylyn Khuren, Altia Range, Mongolian People's Republic. Link to MinDat.org Location Data. |
Name Origin: |
Named as the Fe3+ analogue of allanite-(Ce) |
Synonym: |
Cerine |
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IMA2000-041 |
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Ferriallanite-(Ce) Crystallography
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Axial Ratios: |
a:b:c =1.5356:1:1.7446 |
Cell Dimensions: |
a = 8.962, b = 5.836, c = 10.182, Z = 2; beta = 115.02° V = 482.57 Den(Calc)= 4.22 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 21/m |
X Ray Diffraction: |
By Intensity(I/Io): 2.18(1)(112,123,401), 2.14(0.8)(221,403,223,02.72(0.8)(120,013),
2.93(0.65)(113), 2.63(0.6)(311), 3.55(0.55)(211), 2.34(0.55)( |
Crystal Structure:
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Kartashov P M , Ferraris G , Ivaldi G , Sokolova E V , McCammon C A , The Canadian Mineralogist , 41 (2003) p.829-830, Ferriallanite-(Ce), CaCeFeAlFe(SiO4)(Si2O7)O(OH), a new member of the, epidote group: Description, X-ray and Mossbauer study: Errata, Note: supercedes data from The Canadian Mineralogist 40 (2002) 1641-1648
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Physical Properties of Ferriallanite-(Ce)
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Cleavage: |
None |
Color: |
Black. |
Density: |
4.22 |
Diaphaniety: |
Opaque to translucent |
Fracture: |
Brittle - Conchoidal - Very brittle fracture producing small, conchoidal fragments. |
Habit: |
Aggregates - Made of numerous individual crystals or clusters. |
Habit: |
Subhedral Crystals - Occurs as crystals which tend to exhibit a recognizable crystal shape. |
Hardness: |
6 - Orthoclase |
Luster: |
Vitreous - Resinous |
Streak: |
brown |
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Optical Properties of Ferriallanite-(Ce)
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Optical Data: |
Biaxial (-), a=1.825, b=1.855, g=1.88, bire=0.0550 |
RL Color: |
Black with red or orange internal reflections. |
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Calculated Properties of Ferriallanite-(Ce)
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Electron Density: |
relectron=4.00 gm/cc note: rFerriallanite-(Ce) =4.22 gm/cc. |
Fermion Index |
Fermion Index = 0.01213 Boson Index = 0.98787 |
Photoelectric: |
PEFerriallanite-(Ce) = 110.12 barns/electron U=PEFerriallanite-(Ce) x relectron= 440.92 barns/cc. |
Radioactivity: |
GRapi = 21,252.91 (Gamma Ray American Petroleum Institute Units)
Ferriallanite-(Ce) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Radioactivity from Ferriallanite-(Ce) - weak
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.68 cm |
470,393 |
1.27E-05 |
21,252.91 |
6.99 |
| 100 gm / 3.56 cm |
47,039 |
1.27E-06 |
2,125.29 |
0.70 |
| 10 gm / 1.65 cm |
4,704 |
1.27E-07 |
212.53 |
0.07 |
| 1 gm / 7.68 mm |
470 |
1.27E-08 |
21.25 |
0.01 |
| 0.1 gm / 3.56 mm |
47 |
1.27E-09 |
2.13 |
0.00 |
| 0.01 gm / 1.65 mm |
5 |
1.27E-10 |
0.21 |
0.00 |
| 0.001 gm / 0.77 mm |
0 |
1.27E-11 |
0.02 |
0.00 |
Weight of pure Ferriallanite-(Ce) in grams (gm) and Calculated Diameter of a Sphere with a Density of 4.22 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 1.05 % Th) From Sum REE Elements (21.00 % REE)
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Ferriallanite-(Ce) Classification
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Dana Class: |
58.2.1a.14 (58)Sorosilicate Insular, Mixed, Single, and Larger Tetrahedral Groups |
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(58.2)with cations in [6] and higher coordination; single and double groups (n=1,2) |
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(58.2.1a)Epidote group (Epidote subgroup) |
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58.2.1a.1 Allanite-(Ce) (Ce,Ca,Y)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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58.2.1a.2 Allanite-(La)! Ca(REE,Ca)Al2(Fe,Fe)(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.3 Allanite-(Y) (Y,Ce,Ca)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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58.2.1a.4 Clinozoisite Ca2Al3(SiO4)3(OH)=Ca2AlAl2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.5 Dissakisite-(Ce) Ca(Ce,REE)(Mg,Fe)(Al,Fe)2Si3O12(OH) P 21/m 2/m |
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58.2.1a.6 Dollaseite-(Ce) CaCeMg2AlSi3O11(OH,F)2 P 21/m 2/m |
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58.2.1a.7 Epidote Ca2(Fe,Al)3(SiO4)3(OH)=Ca2(Fe,Al)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.8 Hancockite (Ca,Pb,Sr)2(Al,Fe)3(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.9 Khristovite-(Ce) (Ca,REE)(Ce,REE)(Mg,Fe,Cr,Ti,V,Al)MnAl(SiO4)(Si2O7)(OH)(F,O) P 21/m 2/m |
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58.2.1a.10 Mukhinite Ca2Al2V(SiO4)3(OH) P 21/m 2/m |
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58.2.1a.11 Piemontite Ca2(Al,Mn,Fe)3(SiO4)3(OH)=Ca2(Mn,Fe)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.12 Strontiopiemontite (Ca,Mn)(Sr,Ca)Mn(Al,Mn,Fe)2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.13 Androsite-(La)! (Mn,Ca)(La,Ce,Ca,Nd)AlMnMn(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.14 Ferriallanite-(Ce) ! CaCe(Fe,Fe,Al)3[SiO4][Si2O7]O(OH) P 21/m 2/m |
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58.2.1a.15 Tweddillite! CaSr(Mn,Fe)2Al[Si3O12](OH) P 21/m 2/m |
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58.2.1a.16 Gatelite-(Ce)! (Ca,Ce,La,Nd)4(Al,Mg,Fe)4[Si2O7][SiO4]3(O,F,OH)3 P 21/a 2/m |
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58.2.1a.17 Niigataite! CaSrAl3(Si2O7)(SiO4)O(OH) P 21/m 2/m |
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58.2.1a.18 Vastmanlandite-(Ce)! Ce3CaMg2Al2Si5O19(OH)2F P 21/m 2/m |
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58.2.1a.19 IMA2002-049! (Mn,Ca)(Ce,REE)AlMnMn(Si2O7)(SiO4)O(OH) P 21/m 2/m |
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58.2.1a.20 Dissakisite-(La)! (Ca,Fe,Th)(REE,Ca)(Al,Cr,Ti)2(Mg,Fe,Al)Si3O12(OH,F)withLa>Ce P 21/m 2/m |
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58.2.1a.22 IMA2004-015! (Mn,Ca)(REE)VAlMn(Si2O7)(SiO4)O(OH) P 21/m 2/m |
Strunz Class: |
VIII/C.23-85a VIII - Silicates |
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VIII/C - Sorosilicates, mixed structure with [SiO4]2- "inseln" and [Si2O7]6- groups |
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VIII/C.23 - Epidote group |
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VIII/C.23-10 Clinozoisite Ca2Al3(SiO4)3(OH)=Ca2AlAl2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-20 Epidote Ca2(Fe,Al)3(SiO4)3(OH)=Ca2(Fe,Al)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-30 Piemontite Ca2(Al,Mn,Fe)3(SiO4)3(OH)=Ca2(Mn,Fe)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-40 Strontiopiemontite (Ca,Mn)(Sr,Ca)Mn(Al,Mn,Fe)2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-43 Niigataite! CaSrAl3(Si2O7)(SiO4)O(OH) P 21/m 2/m |
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VIII/C.23-45 Tweddillite! CaSr(Mn,Fe)2Al[Si3O12](OH) P 21/m 2/m |
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VIII/C.23-50 Mukhinite Ca2Al2V(SiO4)3(OH) P 21/m 2/m |
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VIII/C.23-52 Androsite-(La)! (Mn,Ca)(La,Ce,Ca,Nd)AlMnMn(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-55 Dollaseite-(Ce) CaCeMg2AlSi3O11(OH,F)2 P 21/m 2/m |
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VIII/C.23-58 Dissakisite-(Ce) Ca(Ce,REE)(Mg,Fe)(Al,Fe)2Si3O12(OH) P 21/m 2/m |
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VIII/C.23-60 Allanite-(Y) (Y,Ce,Ca)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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VIII/C.23-65 Allanite-(La)! Ca(REE,Ca)Al2(Fe,Fe)(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-80 Allanite-(Ce) (Ce,Ca,Y)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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VIII/C.23-85a Ferriallanite-(Ce) CaCe(Fe,Fe,Al)3[SiO4][Si2O7]O(OH) P 21/m 2/m |
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VIII/C.23-85 Khristovite-(Ce) (Ca,REE)(Ce,REE)(Mg,Fe,Cr,Ti,V,Al)MnAl(SiO4)(Si2O7)(OH)(F,O) P 21/m 2/m |
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VIII/C.23-87 Gatelite-(Ce)! (Ca,Ce,La,Nd)4(Al,Mg,Fe)4[Si2O7][SiO4]3(O,F,OH)3 P 21/a 2/m |
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VIII/C.23-90 Hancockite (Ca,Pb,Sr)2(Al,Fe)3(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-100 Zoisite Ca2Al3(SiO4)3(OH)=Ca2AlAl2(SiO4)(Si2O7)O(OH) Pnmc 2/m 2/m 2/m |
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Other Ferriallanite-(Ce) Information
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References: |
NAME( CanMin, 41:809) PHYS. PROP.(CanMin, 41:809) OPTIC PROP.(CanMin, 41:809) |
See Also: |
Links to other databases for Ferriallanite-(Ce) :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -MinDAT
6 -MinMax(Deutsch)
7 -MinMax(English)
8 -Mineralienatlas (Deutsch)
9 -QUT Mineral Atlas
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Print or Cut-and-Paste your Ferriallanite-(Ce) Specimen Label here :
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Ferriallanite-(Ce)
CaCe(Fe+++,Fe++,Al)3[SiO4][Si2O7]O(OH)
Dana No: 58.2.1a.14 Strunz No: VIII/C.23-85a
Locality:
Notes:
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