General Copiapite Information
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Chemical Formula: |
Fe++Fe+++4(SO4)6(OH)2·20(H2O) |
Composition: |
Molecular Weight = 1,249.94 gm |
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Iron 22.34 % Fe 5.75 % FeO / 25.55 % Fe2O3 |
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Hydrogen 3.39 % H 30.27 % H2O |
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Sulfur 15.39 % S 38.43 % SO3 |
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Oxygen 58.88 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Fe2+Fe3+4(SO4)6(OH)2·20(H2O) |
Environment: |
Oxidized iron sulfide deposits. |
IMA Status: |
Valid Species (Pre-IMA) 1833 |
Locality: |
Copiapo, Chile. Link to MinDat.org Location Data. |
Name Origin: |
Named after its locality. |
Synonym: |
ICSD 10276 |
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Janosite |
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Misy |
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PDF 35-583 |
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Copiapite Image |
Images:
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Images:
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Copiapite Crystallography
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Axial Ratios: |
a:b:c =0.3852:1:0.3933 |
Cell Dimensions: |
a = 7.227, b = 18.76, c = 7.379, Z = 1; alpha = 91.46°, beta = 102.18°, gamma = 98.95° V = 965.69 Den(Calc)= 2.15 |
Crystal System: |
Triclinic - PinacoidalH-M Symbol ( 1) Space Group: P1 |
X Ray Diffraction: |
By Intensity(I/Io): 9.23(1), 18.4(1), 5.57(0.7), |
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Crystal Structure:
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Fanfani L , Nunzi A , Zanazzi P F , Zanzari A R , American Mineralogist , 58 (1973) p.314-322, The copiapite problem: The crystal structure of a ferrian copiapite
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Physical Properties of Copiapite
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Cleavage: |
[010] Perfect |
Color: |
Green, Green yellow, Yellow, Yellow green, Golden yellow. |
Density: |
2.1 |
Diaphaniety: |
Translucent |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Encrustations - Forms crust-like aggregates on matrix. |
Habit: |
Massive - Granular - Common texture observed in granite and other igneous rock. |
Habit: |
Scaly - Morphology like fish scales. |
Hardness: |
2.5 - Finger Nail |
Luminescence: |
None. |
Luster: |
Pearly |
Magnetism: |
Magnetic |
Streak: |
pale yellow |
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Optical Properties of Copiapite
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Gladstone-Dale: |
CI meas= -0.041 (Good) - where the CI = (1-KPDmeas/KC) CI calc= -0.017 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2557,KPDmeas= 0.2617,KC= 0.2514 |
Optical Data: |
Biaxial (+), a=1.506-1.54, b=1.528-1.549, g=1.575-1.6, bire=0.0600-0.0690, 2V(Calc)=48-72, 2V(Meas)=45-74. Dispersion none. |
Pleochroism (x): |
none. |
Pleochroism (y): |
none. |
Pleochroism (z): |
none. |
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Calculated Properties of Copiapite
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Electron Density: |
relectron=2.19 gm/cc note: rCopiapite =2.15 gm/cc. |
Fermion Index |
Fermion Index = 0.00617 Boson Index = 0.99383 |
Photoelectric: |
PECopiapite = 7.42 barns/electron U=PECopiapite x relectron= 16.23 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Copiapite is Not Radioactive |
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Copiapite Classification
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Dana Class: |
31.10.5.1 (31)Hydrated Sulfates Containing Hydroxyl or Halogen |
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(31.10)miscellaneous |
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(31.10.5)Copiapite Group |
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31.10.5.1 Copiapite FeFe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.2 Magnesiocopiapite MgFe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.3 Cuprocopiapite CuFe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.4 Ferricopiapite Fe2/3Fe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.5 Calciocopiapite CaFe4(SO4)6(OH)2·19(H2O) P1 1 |
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31.10.5.6 Zincocopiapite ZnFe4(SO4)6(OH)2·18(H2O) P1 1 |
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31.10.5.7 Aluminocopiapite Al2/3Fe4(SO4)6O(OH)2·20(H2O) P1 1 |
Strunz Class: |
VI/D.10-50 VI - Sulfates,Chromates,Molybdates and Tungstates |
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VI/D - Water-bearing sulfates with unfamiliar anions. cations of medium size |
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VI/D.10 - Copiapite group, Botryogen - Chaidamuite |
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VI/D.10-10 Botryogen MgFe(SO4)2(OH)·7(H2O) P 21/n 2/m |
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VI/D.10-20 Zincobotryogen (Zn,Mg,Mn)Fe(SO4)2(OH)·7(H2O) P 21/n 2/m |
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VI/D.10-30 Calciocopiapite CaFe4(SO4)6(OH)2·19(H2O) P1 1 |
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VI/D.10-40 Magnesiocopiapite MgFe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-50 Copiapite FeFe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-60 Cuprocopiapite CuFe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-70 Zincocopiapite ZnFe4(SO4)6(OH)2·18(H2O) P1 1 |
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VI/D.10-80 Aluminocopiapite Al2/3Fe4(SO4)6O(OH)2·20(H2O) P1 1 |
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VI/D.10-90 Ferricopiapite Fe2/3Fe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-100 Guildite CuFe(SO4)2(OH)·4(H2O) P 21/m 2/m |
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VI/D.10-110 Chaidamuite (Zn,Fe)Fe(SO4)2(OH)·4(H2O) P1 1 |
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Other Copiapite Information
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References: |
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Ford32) |
See Also: |
Links to other databases for Copiapite :
1 -Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 - Applied Mineralogy
4 -Athena
5 - CalTech Mineral Spectroscopy
6 - Crocoite.com Mineral Locations
7 - EUROmin Project
8 -Google Images
9 -Google Scholar
10 -Handbook of Mineralogy (UofA)
11 -MinDAT
12 -MinMax(Deutsch)
13 -MinMax(English)
14 -Mineralienatlas (Deutsch)
15 -NSDL Reciprocal Net (JAVA)
16 -QUT Mineral Atlas
17 - WWW-MINCRYST
18 -École des Mines de Paris
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Copiapite
Fe++Fe+++4(SO4)6(OH)2·20(H2O)
Dana No: 31.10.5.1 Strunz No: VI/D.10-50
Locality:
Notes:
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