General Pyrrhotite Information
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Chemical Formula: |
Fe(1-x)S (x=0-0.17) |
Composition: |
Molecular Weight = 85.12 gm |
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Iron 62.33 % Fe |
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Sulfur 37.67 % S |
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______ |
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100.00 % |
Empirical Formula: |
Fe2+0.95S |
Environment: |
Wide spread occurrences in igneous and metamorphic rocks. |
IMA Status: |
Valid Species (Pre-IMA) 1835 |
Locality: |
Sudbury, Ontario, Canada and Santa Eulalia, Chihuahua, Mexico. Link to MinDat.org Location Data. |
Name Origin: |
From the Greek, phrrhotes, "redness," in allusion to color. |
Synonym: |
Magnetic pyrites |
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Pyrrhotite Image |
Images:
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Pyrrhotite
Comments: Lustrous sharp crystals of pyrrhotite to 3.5 cm in size with minor sphalerite and chalcopyrite.
Location: Nikolaevskiy mine, Dal'negors, Primorskiy Kray, Russia.
Scale: 4 x 5 x 5.5 cm.
© Dan Weinrich |
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Pyrrhotite Crystallography
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Axial Ratios: |
a:b:c =1.8647:1:1.7299 |
Cell Dimensions: |
a = 12.811, b = 6.87, c = 11.885, Z = 26; beta = 117.3° V = 929.51 Den(Calc)= 3.95 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: A2/a |
X Ray Diffraction: |
By Intensity(I/Io): 2.057(1), 2.635(0.9), 2.966(0.9), |
Forms:
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Forms:
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Crystal Structure:
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Tokonami M , Nishiguchi K , Morimoto N , American Mineralogist , 57 (1972) p.1066-1080, Crystal structure of a monoclinic pyrrhotite (Fe7S8)
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Physical Properties of Pyrrhotite
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Cleavage: |
[0001] Imperfect, [1120] Imperfect |
Color: |
Bronze, Bronze red, Dark brown. |
Density: |
4.58 - 4.65, Average = 4.61 |
Diaphaniety: |
Opaque |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Massive - Granular - Common texture observed in granite and other igneous rock. |
Habit: |
Platy - Sheet forms (e.g. micas). |
Habit: |
Tabular - Form dimensions are thin in one direction. |
Hardness: |
3.5-4 - Copper Penny-Fluorite |
Luminescence: |
None. |
Luster: |
Metallic |
Magnetism: |
Naturally strong |
Streak: |
gray black |
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Optical Properties of Pyrrhotite
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RL Anisotrophism: |
Strong. |
RL Pleochroism: |
Weak. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Pyrrhotite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
27.90 |
31.00 |

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| 420 nm |
28.60 |
32.20 |

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| 440 nm |
29.40 |
33.60 |

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| 460 nm |
30.30 |
34.80 |

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| 480 nm |
31.40 |
36.20 |

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| 500 nm |
32.40 |
37.60 |

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| 520 nm |
33.40 |
38.60 |

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| 540 nm |
34.50 |
39.60 |

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| 560 nm |
35.50 |
40.40 |

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| 580 nm |
36.50 |
41.20 |

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| 600 nm |
37.40 |
42.00 |

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| 620 nm |
38.30 |
42.60 |

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| 640 nm |
39.10 |
43.00 |

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| 660 nm |
39.90 |
43.50 |

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| 680 nm |
40.70 |
43.90 |

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| 700 nm |
41.40 |
44.10 |

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Calculated Relative Intensity Colors of Pyrrhotite in Air
Relative Intensity |
0% |
40% |
80% |
100% |
120% |
160% |
200% |
240% |
280% |
300% |
| R1 |
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| R2 |
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Calculated Properties of Pyrrhotite
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Electron Density: |
relectron=3.78 gm/cc note: rPyrrhotite =3.95 gm/cc. |
Fermion Index |
Fermion Index = 0.01603 Boson Index = 0.98397 |
Photoelectric: |
PEPyrrhotite = 20.96 barns/electron U=PEPyrrhotite x relectron= 79.17 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Pyrrhotite is Not Radioactive |
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Pyrrhotite Classification
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Dana Class: |
2.8.10.1 (2)Sulfides - Including Selenides and Tellurides |
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(2.8)where Am Bn Xp, with (m+n):p=1:1 |
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(2.8.10)Dana Group |
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2.8.10.1 Pyrrhotite Fe(1-x)S(x=0-0.17) A2/a 2/m |
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2.8.10.2 Smythite (Fe,Ni)9S11or(Fe,Ni)13S16 R 3m 3 2/m |
Strunz Class: |
II/C.19-20 II - Sulfides and sulphosalts |
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II/C - Sulfides with metal: sulfur, selenium and tellurium = 1:1 |
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II/C.19 - Troilite - Pyrrhotite - Haideite series |
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II/C.19-10 Troilite FeS P 63/mmc 6/m 2/m 2/m |
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II/C.19-20 Pyrrhotite Fe(1-x)S(x=0-0.17) A2/a 2/m |
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II/C.19-25 Jaipurite* CoS P 63/mmc 6/m 2/m 2/m |
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II/C.19-30 Westerveldite (Fe,Ni,Co)As Pnam 2/m 2/m 2/m |
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II/C.19-40 Modderite (Co,Fe)As Pmcn 2/m 2/m 2/m |
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II/C.19-50 Smythite (Fe,Ni)9S11or(Fe,Ni)13S16 R 3m 3 2/m |
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II/C.19-60 Achavalite* FeSe P 63/mmc 6/m 2/m 2/m |
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II/C.19-70 Heideite (Fe,Cr)1x(Ti,Fe)2S4 I2/m 2/m |
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Other Pyrrhotite Information
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References: |
NAME( Sinkankas66) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Pyrrhotite :
1 - Alkali-Nuts(English)
2 - Alkali-Nuts(Francais)
3 -Am. Min. Crystal Structure Database
4 - Amethyst Galleries' Mineral Gallery
5 - Applied Mineralogy
6 -Athena
7 - Crocoite.com Mineral Locations
8 - EUROmin Project
9 - Franklin Minerals(Dunn)
10 - Franklin Minerals(Palache)
11 -Google Images
12 -Google Scholar
13 -Handbook of Mineralogy (UofA)
14 - HyperPhysics
15 -MinDAT
16 -MinMax(Deutsch)
17 -MinMax(English)
18 -Mineralienatlas (Deutsch)
19 - Minerals of Wisconsin
20 -NSDL Reciprocal Net (JAVA)
21 - Philatelic Mineralogy
22 -QUT Mineral Atlas
23 - Scandinavian mineral gallery
24 -University of Minnesota
25 - WWW-MINCRYST
26 -École des Mines de Paris
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Pyrrhotite
Fe(1-x)S (x=0-0.17)
Dana No: 2.8.10.1 Strunz No: II/C.19-20
Locality:
Notes:
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