General Metakirchheimerite Information
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Chemical Formula: |
Co(UO2)2(AsO4)2·8(H2O) |
Composition: |
Molecular Weight = 1,020.95 gm |
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Uranium 46.63 % U 52.90 % UO2 |
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Cobalt 5.77 % Co 8.12 % Co2O3 |
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Arsenic 14.68 % As 22.51 % As2O5 |
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Hydrogen 1.58 % H 14.12 % H2O |
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Oxygen 31.34 % O |
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______ ______ |
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100.00 % 97.65 % = TOTAL OXIDE |
Empirical Formula: |
Co(UO2)2(AsO4)2·8(H2O) |
IMA Status: |
Valid Species (Pre-IMA) 1958 |
Locality: |
Link to MinDat.org Location Data. |
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Images:
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Metakirchheimerite Crystallography
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Axial Ratios: |
a:c = 1:1.19498 |
Cell Dimensions: |
a = 7.18, c = 8.58, Z = 1; V = 442.32 Den(Calc)= 3.83 |
Crystal System: |
Tetragonal - Ditetragonal DipyramidalH-M Symbol (4/m 2/m 2/m) Space Group: P 4/mmm |
X Ray Diffraction: |
By Intensity(I/Io): 3.56(1), 8.55(1), 5.07(0.6), |
Crystal Structure:
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Locock A J , Burns P C , Flynn M , The Canadian Mineralogist , 42 (2004) p.1699-1718, Divalent transition metals and magnesium in structures, that contain the autunite-type sheet, Sample: CoUAs8
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Physical Properties of Metakirchheimerite
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Cleavage: |
[001] Perfect |
Color: |
Light pink. |
Density: |
3.2 - 3.25, Average = 3.22 |
Diaphaniety: |
Transparent to Translucent |
Hardness: |
2-2.5 - Gypsum-Finger Nail |
Luster: |
Pearly |
Streak: |
white |
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Optical Properties of Metakirchheimerite
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Gladstone-Dale: |
CI meas= -0.191 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= -0.003 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1646,KPDmeas= 0.1955,KC= 0.1641 |
Optical Data: |
Uniaxial (-), e=1.617, w=1.644, bire=0.0270. |
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Calculated Properties of Metakirchheimerite
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Electron Density: |
relectron=3.40 gm/cc note: rMetakirchheimerite =3.83 gm/cc. |
Fermion Index |
Fermion Index = 0.00351 Boson Index = 0.99649 |
Photoelectric: |
PEMetakirchheimerite =1,205.00 barns/electron U=PEMetakirchheimerite x relectron=4,095.52 barns/cc. |
Radioactivity: |
GRapi = 3,527,062.36 (Gamma Ray American Petroleum Institute Units)
Metakirchheimerite is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
8.62 ± 2.16 grams of pure Metakirchheimerite .
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 100 cm box)
862.38 ±215.59 grams of pure Metakirchheimerite .
Estimated Radioactivity from Metakirchheimerite - very strong
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.93 cm |
83,465,785 |
2.26E-03 |
3,527,062.36 |
1,159.58 |
| 100 gm / 3.68 cm |
8,346,579 |
2.26E-04 |
352,706.24 |
115.96 |
| 10 gm / 1.71 cm |
834,658 |
2.26E-05 |
35,270.62 |
11.60 |
| 1 gm / 7.93 mm |
83,466 |
2.26E-06 |
3,527.06 |
1.16 |
| 0.1 gm / 3.68 mm |
8,347 |
2.26E-07 |
352.71 |
0.12 |
| 0.01 gm / 1.71 mm |
835 |
2.26E-08 |
35.27 |
0.01 |
| 0.001 gm / 0.79 mm |
83 |
2.26E-09 |
3.53 |
0.00 |
Weight of pure Metakirchheimerite in grams (gm) and Calculated Diameter of a Sphere with a Density of 3.83 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
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Metakirchheimerite Classification
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Dana Class: |
40.2a.17.1 (40)Hydrated Phosphates, etc |
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(40.2a)where A++ (B++)2 (XO4) · x(H2O), containing (UO2)++ |
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(40.2a.17)Dana Group |
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40.2a.17.1 Metakirchheimerite Co(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
Strunz Class: |
VII/E.02-50 VII - Phosphates, Arsenates and Vanadates |
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VII/E - Uranylphosphates and uranylvanadates with [UO2]2+ - [PO4 | AsO4]3- and [UO2]2+ - [V2O8]6- |
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VII/E.02 - Meta-autunite group |
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VII/E.02-10 Metanovacekite Mg(UO2)2(AsO4)2·4-8(H2O) P 4/n 4/m |
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VII/E.02-20 Bassetite Fe(UO2)2(PO4)2·8(H2O) P 21/m 2/m |
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VII/E.02-30 Metakahlerite Fe(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-40 Lehnerite Mn[UO2/PO4]2·8(H2O) P 21/n 2/m |
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VII/E.02-50 Metakirchheimerite Co(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-60 Metatorbernite Cu(UO2)2(PO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-70 Metazeunerite Cu(UO2)2(AsO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-80 Metalodevite Zn(UO2)2(AsO4)2·10(H2O) P 41/m 4/m |
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VII/E.02-90 Meta-autunite Ca(UO2)2(PO4)2·2-6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-95 Sodium meta-autunite! Na2(UO2)2(PO4)2·6-8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-100 Meta-uranospinite Ca(UO2)2(AsO4)2·8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-110 Meta-uranocircite Ba(UO2)2(PO4)2·6-8(H2O) P 21 2 |
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VII/E.02-120 Metaheinrichite Ba(UO2)2(AsO4)2·8(H2O) P 41/? 4/m |
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VII/E.02-130 Sodium-uranospinite (Na2,Ca)(UO2)2(AsO4)2·5(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-140 Meta-ankoleite K2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-150 Abernathyite K(UO2)(AsO4)·4(H2O) P 4/ncc 4/m 2/m 2/m |
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VII/E.02-160 Uramphite (NH4)(UO2)(PO4)·3(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-170 Chernikovite (H3O)2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-180 Pseudo-autunite* (H3O)4Ca2(UO2)2(PO4)4·5(H2O)(?) Unk Ortho |
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VII/E.02-190 Ulrichite CaCu(UO2)(PO4)2·4(H2O) C 2/m 2/m |
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Other Metakirchheimerite Information
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References: |
PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Metakirchheimerite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 -École des Mines de Paris
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Metakirchheimerite
Co(UO2)2(AsO4)2·8(H2O)
Dana No: 40.2a.17.1 Strunz No: VII/E.02-50
Locality:
Notes:
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