General Kupletskite Information
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Chemical Formula: |
K2Na(Mn,Fe++)7(Ti,Nb)2Si8O26(OH)4F |
Composition: |
Molecular Weight = 1,337.34 gm |
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Potassium 6.58 % K 7.92 % K2O |
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Sodium 1.29 % Na 1.74 % Na2O |
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Titanium 5.37 % Ti 8.96 % TiO2 |
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Manganese 21.57 % Mn 27.85 % MnO |
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Niobium 3.47 % Nb 4.97 % Nb2O5 |
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Iron 7.31 % Fe 9.40 % FeO |
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Silicon 16.80 % Si 35.94 % SiO2 |
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Hydrogen 0.30 % H 2.69 % H2O |
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Oxygen 35.89 % O |
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Fluorine 1.42 % F 1.42 % F |
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- % F -0.60 % -O=F2 |
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______ ______ |
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100.00 % 100.30 % = TOTAL OXIDE |
Empirical Formula: |
K2.25Na0.75Mn2+5.25Fe2+1.75Ti1.5Nb0.5Si8O26(OH)4(F) |
Environment: |
The monoclinic version is kukpletskite-Ma2b2c and the triclinic version is kupletskite-1A |
IMA Status: |
Valid Species (Pre-IMA) 1956 |
Locality: |
Lovozero massif, Kola Peninsula, Russia. Link to MinDat.org Location Data. |
Name Origin: |
Named for Boris Mikhailovich Kupletski (1984-1964) and Elsa Maximilianove Bohnshtedt Kupletskaya (1897-1974), Russian geologists. |
Synonym: |
ICSD 86867 |
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PDF 26-6 |
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Kupletskite Image |
Images:
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Images:
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Kupletskite Niobokupletskite
Comments: Back-scattered electron image of Niobokupletskite (Nkpt) rimming kupletskite (Kpt). The zoning in the kupletskite is from Nb-poor to Nb-rich in the direction of the arrow (dark to medium gray). (CanMin v 38, p 628).
Location: Mont Saint-Hilaire, Quebec, Canada.
Scale: Scale bar 100 µ-m.
© Canadian Mineralogist |
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Kupletskite Crystallography
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Axial Ratios: |
a:b:c =0.2325:1:0.9118 |
Cell Dimensions: |
a = 5.4022, b = 23.226, c = 21.1782, Z = 4; beta = 95.246° V = 2,646.13 Den(Calc)= 3.36 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 2/c |
X Ray Diffraction: |
By Intensity(I/Io): 2.64(1), 3.51(1), 2.57(0.5),1.732(0.4), 2.1(0.4), 2.76(0.1), 3(0.1), 3.25(0.1), |
Crystal Structure:
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Piilonen P C , McDonald A M , Lalonde A E , The Canadian Mineralogist , 41 (2003) p.27-54, Insights into astrophyllite-group minerals II: Crystal chemistry, Note: sample NOR17, alkali granite, Locality: Gjerdingen intrusion, Norway
View Additional jPOWD Structure files for Kupletskite
[1]
[10]
[11]
[12]
[13]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
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Physical Properties of Kupletskite
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Cleavage: |
[001] Perfect |
Color: |
Yellow brown, Black, Black brown. |
Density: |
3.2 - 3.23, Average = 3.21 |
Diaphaniety: |
Translucent to Opaque |
Habit: |
Acicular - Occurs as needle-like crystals. |
Habit: |
Tabular - Form dimensions are thin in one direction. |
Hardness: |
4 - Fluorite |
Luster: |
Vitreous - Adamantine |
Streak: |
brown |
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Optical Properties of Kupletskite
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Gladstone-Dale: |
CI meas= 0.037 (Excellent) - where the CI = (1-KPDmeas/KC) CI calc= 0.078 (Fair) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2069,KPDmeas= 0.2163,KC= 0.2245 |
Optical Data: |
Biaxial (-), a=1.656, b=1.699, g=1.731, bire=0.0750, 2V(Calc)=78, 2V(Meas)=79. |
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Calculated Properties of Kupletskite
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Electron Density: |
relectron=3.11 gm/cc note: rKupletskite =3.22 gm/cc. |
Fermion Index |
Fermion Index = 0.01651 Boson Index = 0.98349 |
Photoelectric: |
PEKupletskite = 15.04 barns/electron U=PEKupletskite x relectron= 46.72 barns/cc. |
Radioactivity: |
GRapi = 91.72 (Gamma Ray American Petroleum Institute Units)
Estimated Radioactivity from Kupletskite - barely detectable
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Kupletskite Classification
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Dana Class: |
69.1.1.2 (69)Inosilicate Chains with Side Branches or Loops |
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(69.1)with (P=2, and N=4, 2 branches) |
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(69.1.1)Astrophyllite group |
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69.1.1.1 Astrophyllite K2Na(Fe,Mn)7Ti2Si8O26(OH)4 P1 1 |
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69.1.1.2 Kupletskite K2Na(Mn,Fe)7(Ti,Nb)2Si8O26(OH)4F C 2/c 2/m |
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69.1.1.3 Kupletskite-(Cs) (Cs,K)2Na(Mn,Fe,Li)7(Ti,Nb)2Si8O26(OH)4F P1 1 |
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69.1.1.4 Niobophyllite K2Na(Fe,Mn)7(Nb,Ti)2Si8O26(OH)4(F,O) P1,P 1 Tri |
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69.1.1.5 Zircophyllite K2(Na,Ca)(Mn,Fe)7(Zr,Nb)2Si8O26(OH)4F P1 1 |
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69.1.1.6 Hydroastrophyllite (H3O,K)2Ca(Fe,Mn)5-6Ti2Si8O26(OH)4F P1 1 |
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69.1.1.7 Magnesiumastrophyllite K2Na[Na(Fe,Fe,Mn)Mg2]Ti2Si8O26(OH)4F A2/m 2/m |
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69.1.1.8 Niobokupletskite! K2Na(Mn,Zn,Fe)7(Nb,Zr,Ti)2Si8O26(OH)4(O,F) P1 1 |
Strunz Class: |
VIII/G.12-50 VIII - Silicates |
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VIII/G - Intermediate between chain- and layered silicates |
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VIII/G.12 - Astrophyllite- Kupletskite group |
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VIII/G.12-20 Magnesiumastrophyllite K2Na[Na(Fe,Fe,Mn)Mg2]Ti2Si8O26(OH)4F A2/m 2/m |
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VIII/G.12-30 Hydroastrophyllite (H3O,K)2Ca(Fe,Mn)5-6Ti2Si8O26(OH)4F P1 1 |
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VIII/G.12-40 Astrophyllite K2Na(Fe,Mn)7Ti2Si8O26(OH)4 P1 1 |
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VIII/G.12-50 Kupletskite K2Na(Mn,Fe)7(Ti,Nb)2Si8O26(OH)4F C 2/c 2/m |
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VIII/G.12-60 Kupletskite-(Cs) (Cs,K)2Na(Mn,Fe,Li)7(Ti,Nb)2Si8O26(OH)4F P1 1 |
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VIII/G.12-65 Niobokupletskite! K2Na(Mn,Zn,Fe)7(Nb,Zr,Ti)2Si8O26(OH)4(O,F) P1 1 |
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VIII/G.12-70 Zircophyllite K2(Na,Ca)(Mn,Fe)7(Zr,Nb)2Si8O26(OH)4F P1 1 |
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VIII/G.12-80 Niobophyllite K2Na(Fe,Mn)7(Nb,Ti)2Si8O26(OH)4(F,O) P1,P 1 Tri |
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Other Kupletskite Information
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References: |
NAME( Dana8) PHYS. PROP.(Dana8, AmMin, Vol 87, p 768) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Kupletskite :
1 - Alkali-Nuts(English)
2 - Alkali-Nuts(Francais)
3 -Am. Min. Crystal Structure Database
4 - Amethyst Galleries' Mineral Gallery
5 -Athena
6 - EUROmin Project
7 -Google Images
8 -Google Scholar
9 -Handbook of Mineralogy (MinSocAm)
10 -Handbook of Mineralogy (UofA)
11 -MinDAT
12 -MinMax(Deutsch)
13 -MinMax(English)
14 -Mineralienatlas (Deutsch)
15 -QUT Mineral Atlas
16 -École des Mines de Paris
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Kupletskite
K2Na(Mn,Fe++)7(Ti,Nb)2Si8O26(OH)4F
Dana No: 69.1.1.2 Strunz No: VIII/G.12-50
Locality:
Notes:
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