General Huanghoite-(Ce) Information
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Chemical Formula: |
BaCe(CO3)2F |
Composition: |
Molecular Weight = 416.46 gm |
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Barium 32.97 % Ba 36.82 % BaO |
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Cerium 33.64 % Ce 39.41 % Ce2O3 |
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Carbon 5.77 % C 21.14 % CO2 |
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Oxygen 23.05 % O |
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Fluorine 4.56 % F 4.56 % F |
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- % F -1.92 % -O=F2 |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
BaCe(CO3)2F |
IMA Status: |
Approved IMA 1961 |
Locality: |
Link to MinDat.org Location Data. |
Synonym: |
ICSD 74178 |
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PDF 15-286 |
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Huanghoite-(Ce) Crystallography
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Axial Ratios: |
a:c = 1:7.5828 |
Cell Dimensions: |
a = 5.072, c = 38.46, Z = 6; V = 856.84 Den(Calc)= 4.84 |
Crystal System: |
Trigonal - Hexagonal ScalenohedralH-M Symbol (3 2/m) Space Group: R 3m |
X Ray Diffraction: |
By Intensity(I/Io): 1.937(1), 3.21(1), 2.01(0.9), |
Crystal Structure:
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Yang Z M , Pertlik F , Neues Jahrbuch fur Mineralogie, Monatshefte , 1993 (1993) p.163-171, Huanghoite-(Ce), BaCe(CO3)2F, from Khibina, Kola peninsula, Russia:, Redetermination of the crystal structure with a discussion on space group symmetry, Locality: Khibina, Kola Peninsula, Russia
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Physical Properties of Huanghoite-(Ce)
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Cleavage: |
[???] Indistinct, [0001] Distinct |
Color: |
Yellow green, Honey yellow. |
Density: |
4.51 - 4.67, Average = 4.59 |
Diaphaniety: |
Translucent |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Hardness: |
4.7 |
Luster: |
Greasy (Oily) |
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Optical Properties of Huanghoite-(Ce)
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Gladstone-Dale: |
CI meas= 0.011 (Superior) - where the CI = (1-KPDmeas/KC) CI calc= 0.062 (Fair) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1413,KPDmeas= 0.149,KC= 0.1506 |
Optical Data: |
Uniaxial (-), e=1.603, w=1.765, bire=0.1620. |
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Calculated Properties of Huanghoite-(Ce)
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Electron Density: |
relectron=4.03 gm/cc note: rHuanghoite-(Ce) =4.59 gm/cc. |
Fermion Index |
Fermion Index = 0.05951 Boson Index = 0.94049 |
Photoelectric: |
PEHuanghoite-(Ce) = 327.24 barns/electron U=PEHuanghoite-(Ce) x relectron=1,320.03 barns/cc. |
Radioactivity: |
GRapi = 31,539.16 (Gamma Ray American Petroleum Institute Units)
Huanghoite-(Ce) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
964.41 ±241.10 grams of pure Huanghoite-(Ce) .
Estimated Radioactivity from Huanghoite-(Ce) - weak
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.47 cm |
753,634 |
2.04E-05 |
31,539.16 |
10.37 |
| 100 gm / 3.47 cm |
75,363 |
2.04E-06 |
3,153.92 |
1.04 |
| 10 gm / 1.61 cm |
7,536 |
2.04E-07 |
315.39 |
0.10 |
| 1 gm / 7.47 mm |
754 |
2.04E-08 |
31.54 |
0.01 |
| 0.1 gm / 3.47 mm |
75 |
2.04E-09 |
3.15 |
0.00 |
| 0.01 gm / 1.61 mm |
8 |
2.04E-10 |
0.32 |
0.00 |
| 0.001 gm / 0.75 mm |
1 |
2.04E-11 |
0.03 |
0.00 |
Weight of pure Huanghoite-(Ce) in grams (gm) and Calculated Diameter of a Sphere with a Density of 4.59 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 1.68 % Th) From Sum REE Elements (33.64 % REE)
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Huanghoite-(Ce) Classification
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Dana Class: |
16a.1.4.1 (16a)Carbonates - Hydroxyl or Halogen |
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(16a.1)in the Bastnasite/Shynchysite/Parasite Groups |
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(16a.1.4)Dana Group |
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16a.1.4.1 Huanghoite-(Ce) BaCe(CO3)2F R 3m 3 2/m |
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16a.1.4.2 IMA2004-019! Ba(Ce,REE)(CO3)2F P 3 3 |
Strunz Class: |
V/C.07-130 V - Nitrates, Carbonates and Borates |
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V/C - Waterfree carbonates with unfamiliar anions |
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V/C.07 - Bastnäsite-(Y) - Mineevite-(Y) series |
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V/C.07-10 Bastnasite-(Y) Y(CO3)F P 62c 6 m2 |
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V/C.07-20 Bastnasite-(La) La(CO3)F P 62c 6 m2 |
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V/C.07-30 Bastnasite-(Ce) Ce(CO3)F P 62c 6 m2 |
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V/C.07-40 Hydroxylbastnasite-(La) La(CO3)(OH) C 2221 2 2 2 |
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V/C.07-50 Hydroxylbastnasite-(Ce) Ce(CO3)(OH) P 62c 6 m2 |
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V/C.07-60 Hydroxylbastnasite-(Nd) Nd(CO3)(OH) P 62c 6 m2 |
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V/C.07-61 Kozoite-(Nd)! (Nd,La,Sm,Pr)(CO3)(OH) Pmcn 2/m 2/m 2/m |
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V/C.07-62 Kozoite-(La)! La(CO3)(OH) Pmcn 2/m 2/m 2/m |
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V/C.07-64 Horvathite-(Y)! NaY(CO3)F2 Pmcn 2/m 2/m 2/m |
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V/C.07-70 Parisite-(Ce) Ca(Ce,La)2(CO3)3F2 R 3 3 |
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V/C.07-80 Parisite-(Nd) Ca(Nd,Ce,La)2(CO3)3F2 R 3 3 |
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V/C.07-90 Rontgenite-(Ce) Ca2(Ce,La)3(CO3)5F3 R 3 3 |
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V/C.07-100 Synchysite-(Y) CaY(CO3)2F C 2/c 2/m |
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V/C.07-110 Synchysite-(Ce) CaCe(CO3)2F C 2/c 2/m |
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V/C.07-120 Synchysite-(Nd) CaNd(CO3)2F Unk Ortho |
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V/C.07-130 Huanghoite-(Ce) BaCe(CO3)2F R 3m 3 2/m |
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V/C.07-140 Cebaite-(Ce) Ba3Ce2(CO3)5F2 C 2/m or C 2 Mono |
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V/C.07-150 Cebaite-(Nd)! Ba3(Nd,Ce)2(CO3)5F2 Unk Mono |
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V/C.07-154 Kukharenkoite-(La)! Ba2(La,Ce)(CO3)3F P 21/m 2/m |
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V/C.07-155 Kukharenkoite-(Ce)! Ba2Ce(CO3)3F P 21/m 2/m |
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V/C.07-160 Zhonghuacerite-(Ce) Ba2Ce(CO3)3F P 21/m 2/m |
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V/C.07-170 Cordylite-(Ce) Ba(Ce,La)2(CO3)3F2 P 63/mmc 6/m 2/m 2/m |
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V/C.07-175 Lukechangite-(Ce)! Na3Ce2(CO3)4F P 63/mmc 6/m 2/m 2/m |
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V/C.07-190 Mineevite-(Y) Na25Ba(Y,Gd,Dy)2(HCO3)4(CO3)11(SO4)2ClF2 P 63/m 6/m |
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V/C.07-200 Reederite-(Y)! Na15Y2(CO3)9(SO3F)Cl P 6 6 |
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V/C.07-210 Micheelsenite! (Ca,Y)3Al[PO3OH,CO3](CO3)(OH)6·12(H2O) P 63 6 |
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Other Huanghoite-(Ce) Information
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References: |
PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Huanghoite-(Ce) :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 -École des Mines de Paris
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Print or Cut-and-Paste your Huanghoite-(Ce) Specimen Label here :
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Huanghoite-(Ce)
BaCe(CO3)2F
Dana No: 16a.1.4.1 Strunz No: V/C.07-130
Locality:
Notes:
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