General Hawthorneite Information
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Chemical Formula: |
Ba[Ti3Cr4Fe4Mg]O19 |
Composition: |
Molecular Weight = 1,040.63 gm |
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Barium 13.20 % Ba 14.73 % BaO |
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Magnesium 2.34 % Mg 3.87 % MgO |
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Titanium 13.80 % Ti 23.03 % TiO2 |
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Chromium 19.99 % Cr 26.14 % CrO |
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Iron 21.47 % Fe 27.62 % FeO |
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Oxygen 29.21 % O |
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______ ______ |
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100.00 % 95.39 % = TOTAL OXIDE |
Empirical Formula: |
BaTi3Cr4Fe2+4MgO19 |
Environment: |
Formed during upper-mantle (75-100 km, 900-1,000 Deg C., 20-30 kbar) metasomatism of chromian spinel in peridotite xenolith in a kimberlite pipe. Included in spinel surrounded by li ndsleyite. |
IMA Status: |
Approved IMA 1989 |
Locality: |
Bultfontein diamond mine, Kimberley, Cape Province, South Africa. Link to MinDat.org Location Data. |
Name Origin: |
Named for John Barry Hawthorne, formerly chief geologist (Diamonds), DeBeers Consolidated Mines, South Africa. |
Synonym: |
ICSD 202256 |
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PDF 46-1469 |
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Search for Hawthorneite Images |
Images:
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Hawthorneite Crystallography
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Axial Ratios: |
a:c = 1:3.92778 |
Cell Dimensions: |
a = 5.871, c = 23.06, Z = 2; V = 688.36 Den(Calc)= 5.02 |
Crystal System: |
Hexagonal - Dihexagonal DipyramidalH-M Symbol (6/m 2/m 2/m) Space Group: P 63/mmc |
X Ray Diffraction: |
By Intensity(I/Io): 2.616(1), 2.765(0.85), 2.414(0.49), |
Crystal Structure:
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Help on Above
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Grey I E , Madsen I C , Haggerty S E , American Mineralogist , 72 (1987) p.633-636, Structure of a new upper-mantle, magnetoplumbite-type phase, Ba(Ti3Cr4Fe4Mg)O19
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Physical Properties of Hawthorneite
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Cleavage: |
None |
Color: |
Black, Brown. |
Diaphaniety: |
Opaque |
Habit: |
Granular - Generally occurs as anhedral to subhedral crystals in matrix. |
Habit: |
Inclusions - Generally found as inclusions in other minerals. |
Hardness: |
6-6.5 - Orthoclase-Pyrite |
Luster: |
Metallic |
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Optical Properties of Hawthorneite
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Optical Data: |
Uniaxial (-). |
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NCalc= 2.11 - from Gladstone-Dale relationship (KC = 0.2218) where Ncalc=Dcalc*KC+1 |
RL Anisotrophism: |
Weak to moderate, in browns and grays. |
RL Bireflectance: |
Weak to moderate. |
RL Color: |
Light gray. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Hawthorneite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
19.50 |
18.10 |

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| 420 nm |
19.10 |
17.80 |

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| 440 nm |
18.80 |
17.50 |

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| 460 nm |
18.40 |
17.20 |

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| 480 nm |
18.10 |
17.00 |

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| 500 nm |
17.90 |
16.80 |

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| 520 nm |
17.70 |
16.60 |

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| 540 nm |
17.60 |
16.50 |

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| 560 nm |
17.40 |
16.40 |

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| 580 nm |
17.30 |
16.30 |

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| 600 nm |
17.20 |
16.20 |

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| 620 nm |
17.20 |
16.20 |

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| 640 nm |
17.10 |
16.10 |

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| 660 nm |
17.00 |
16.00 |

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| 680 nm |
17.00 |
16.00 |

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| 700 nm |
16.90 |
15.90 |

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Calculated Relative Intensity Colors of Hawthorneite in Air
Relative Intensity |
0% |
60% |
100% |
120% |
180% |
240% |
300% |
360% |
420% |
480% |
540% |
| R1 |
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| R2 |
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Calculated Properties of Hawthorneite
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Electron Density: |
relectron=4.69 gm/cc note: rHawthorneite =5.02 gm/cc. |
Fermion Index |
Fermion Index = 0.06737 Boson Index = 0.93263 |
Photoelectric: |
PEHawthorneite = 70.35 barns/electron U=PEHawthorneite x relectron= 329.88 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Hawthorneite is Not Radioactive |
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Hawthorneite Classification
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Dana Class: |
7.4.1.3 (7)Multiple Oxides |
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(7.4)with O19 groups |
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(7.4.1)(Hexagonal, P63/mmc) |
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7.4.1.1 Hibonite (Ca,Ce)(Al,Ti,Mg)12O19 P 63/mmc 6/m 2/m 2/m |
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7.4.1.2 Yimengite K(Cr,Ti,Fe,Mg)12O19 P 63/mmc 6/m 2/m 2/m |
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7.4.1.3 Hawthorneite Ba[Ti3Cr4Fe4Mg]O19 P 63/mmc 6/m 2/m 2/m |
Strunz Class: |
IV/C.08-20 IV - Oxides |
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IV/C - Oxides with metal : oxygen = 2:3 (M2O3 and related compounds) |
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IV/C.08 - Yimngite - Otjisumeite series |
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IV/C.08-10 Yimengite K(Cr,Ti,Fe,Mg)12O19 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-20 Hawthorneite Ba[Ti3Cr4Fe4Mg]O19 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-22 Haggertyite! Ba[Fe6Ti5Mg]O19 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-25 Batiferrite! Ba(Ti2Fe8Fe2)O19 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-30 Hibonite (Ca,Ce)(Al,Ti,Mg)12O19 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-35 Nezilovite! PbZn2(Mn,Ti)2Fe8O19 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-40 Magnetoplumbite Pb(Fe,Mn)12O19 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-45 Zenzenite Pb3(Fe,Mn)4Mn3O15 P 63/mcm 6/m 2/m 2/m |
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IV/C.08-47 Lindqvistite Pb2(Mn,Mg)Fe16027 P 63/mmc 6/m 2/m 2/m |
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IV/C.08-50 Plumboferrite Pb2Fe(11-x)MnxO19-2x(x=1/3) P 63/mmc 6/m 2/m 2/m |
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IV/C.08-60 Bartelkeite PbFeGe3O8 P 21,P 21/m Mono |
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IV/C.08-70 Otjisumeite PbGe4O9 P1,P 1 Tri |
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Other Hawthorneite Information
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References: |
NAME( AntBidBlaNic3) PHYS. PROP.(Am.Min.,Vol.74,p668-675,1989) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Hawthorneite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 -École des Mines de Paris
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Print or Cut-and-Paste your Hawthorneite Specimen Label here :
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Hawthorneite
Ba[Ti3Cr4Fe4Mg]O19
Dana No: 7.4.1.3 Strunz No: IV/C.08-20
Locality:
Notes:
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