General Graulichite-(Ce) Information
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Chemical Formula: |
CeFe+++3(AsO4)2(OH)6 |
Composition: |
Molecular Weight = 680.93 gm |
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Barium 3.63 % Ba 4.05 % BaO |
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Strontium 0.26 % Sr 0.30 % SrO |
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Lanthanum 2.04 % La 2.39 % La2O3 |
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Cerium 13.79 % Ce 16.15 % Ce2O3 |
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Aluminum 1.66 % Al 3.14 % Al2O3 |
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Iron 21.98 % Fe 31.43 % Fe2O3 |
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Arsenic 20.80 % As 31.90 % As2O5 |
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Hydrogen 0.95 % H 8.49 % H2O |
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Sulfur 0.05 % S 0.11 % S2O5 |
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Neodymium 1.91 % Nd 2.22 % Nd2O3 |
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Oxygen 32.94 % O |
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______ ______ |
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100.00 % 100.19 % = TOTAL OXIDE |
Empirical Formula: |
Ce0.67Ba0.18La0.1Nd0.09Sr0.02Fe3+2.68Al0.42As1.89S0.01O8(OH)5.62(H2O)0.4 |
Environment: |
Formed from weathering arsenopyrite-bearing quartzite. Fe-dominant analogue of arsenoflorencite-(Ce). |
IMA Status: |
Approved IMA 2003 (Dana # Added) |
Locality: |
Hourt quarry, Stavelot Massif, Belgian Ardennes. Link to MinDat.org Location Data. |
Name Origin: |
Named for Jean-Marie Graulich (1920-2001), Belgian mining engineer and Honorary Driector of the Geological survey of Belgium. |
Synonym: |
IMA2002-001 |
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Graulichite-(Ce) Image |
Images:
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Graulichite-(Ce)
Comments: Scanning electron microscope image of rhombohedral graulichite-(Ce) crystals on goethite.
Location: Hourt quarry, Stavelot Massif, Belgian Ardennes.
Scale: See Image.
© University de Liege |
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Graulichite-(Ce) Crystallography
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Axial Ratios: |
a:c = 1:2.30991 |
Cell Dimensions: |
a = 7.26, c = 16.77, Z = 3; V = 765.49 Den(Calc)= 4.43 |
Crystal System: |
Trigonal - Hexagonal ScalenohedralH-M Symbol (3 2/m) Space Group: R 3m |
X Ray Diffraction: |
By Intensity(I/Io): 3.052(1)(113), 3.636(0.4)(110), 1.817(0.35)(220),2.239(0.35)(107), 2.792(0.3)(006), 5.906(0.25), |
Crystal Structure:
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Hatert F , Lefevre P , Pasero M , Fransolet A-M , European Journal of Mineralogy , 15 (2003) p.733-739, Gaulichite-(Ce), a new arsenate mineral from the Stavelot Massif, Belgium, Locality: Stavelot Massif, Belgium
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Physical Properties of Graulichite-(Ce)
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Cleavage: |
None |
Color: |
Light green, Brownish green. |
Density: |
3.9 |
Diaphaniety: |
Transparent |
Fracture: |
Irregular - Flat surfaces (not cleavage) fractured in an irregular pattern. |
Habit: |
Aggregates - Made of numerous individual crystals or clusters. |
Habit: |
Rhombohedral Crystals - Occurs as well-formed crystals showing rhobohedral crystals. |
Habit: |
Spherical - Spherical, rounded aggregates. |
Luster: |
Resinous |
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Optical Properties of Graulichite-(Ce)
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Gladstone-Dale: |
CI meas= -0.123 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= 0.012 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.219,KPDmeas= 0.2487,KC= 0.2215 |
Optical Data: |
Uniaxial (-), w=1.97. |
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Calculated Properties of Graulichite-(Ce)
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Electron Density: |
relectron=4.13 gm/cc note: rGraulichite-(Ce) =4.43 gm/cc. |
Fermion Index |
Fermion Index = 0.01539 Boson Index = 0.98461 |
Photoelectric: |
PEGraulichite-(Ce) = 125.82 barns/electron U=PEGraulichite-(Ce) x relectron= 519.06 barns/cc. |
Radioactivity: |
GRapi = 17,614.42 (Gamma Ray American Petroleum Institute Units)
Graulichite-(Ce) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Radioactivity from Graulichite-(Ce) - weak
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.55 cm |
397,220 |
1.07E-05 |
17,614.42 |
5.79 |
| 100 gm / 3.51 cm |
39,722 |
1.07E-06 |
1,761.44 |
0.58 |
| 10 gm / 1.63 cm |
3,972 |
1.07E-07 |
176.14 |
0.06 |
| 1 gm / 7.55 mm |
397 |
1.07E-08 |
17.61 |
0.01 |
| 0.1 gm / 3.51 mm |
40 |
1.07E-09 |
1.76 |
0.00 |
| 0.01 gm / 1.63 mm |
4 |
1.07E-10 |
0.18 |
0.00 |
| 0.001 gm / 0.76 mm |
0 |
1.07E-11 |
0.02 |
0.00 |
Weight of pure Graulichite-(Ce) in grams (gm) and Calculated Diameter of a Sphere with a Density of 4.43 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
**
Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 0.89 % Th) From Sum REE Elements (17.73 % REE)
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Graulichite-(Ce) Classification
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Dana Class: |
41.5.11.4 (41)Anhydrous Phosphates, etc. Containing Hydroxyl or Halogen |
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(41.5)where (A B)2 (XO4) Zq |
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(41.5.11)Dana Group |
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41.5.11.1 Arsenoflorencite-(Ce) (Ce,La)Al3(AsO4)2(OH)6 R 3m 3 2/m |
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41.5.11.2 Arsenoflorencite-(Nd)* (Nd,La,Ce,Ba)(Al,Fe)3(AsO4,PO4)2(OH)6 R 3m 3m |
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41.5.11.3 Arsenoflorencite-(La)* (La,Sr)Al3(AsO4,SO4,PO4)2(OH)6 R 3m 3m |
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41.5.11.4 Graulichite-(Ce) ! CeFe3(AsO4)2(OH)6 R 3m 3 2/m |
Strunz Class: |
VII/B.36-152 VII - Phosphates, Arsenates and Vanadates |
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VII/B - Waterfree phosphates with unfamiliar anions F, Cl, O, OH. cations of medium and big size: Mg, Cu, Zn, and Ca, Na, K, Ba, Pb |
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VII/B.36 - Crandallite group |
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VII/B.36-10 Crandallite CaAl3(PO4)2(OH)5·(H2O) R 3m 3 2/m |
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VII/B.36-20 Arsenocrandallite (Ca,Sr)Al3[(As,P)O4]2(OH)5·(H2O) R 3m 3m |
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VII/B.36-30 Goyazite SrAl3(PO4)2(OH)5·(H2O) R 3m 3 2/m |
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VII/B.36-40 Arsenogoyazite (Sr,Ca,Ba)Al3(AsO4,PO4)2(OH,F)5·(H2O) R 3m 3 2/m |
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VII/B.36-50 Gorceixite BaAl3(PO4)(PO3OH)(OH)6 Cm m |
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VII/B.36-60 Arsenogorceixite! BaAl3AsO3(OH)(AsO4,PO4)(OH,F)6 R 3m 3 2/m |
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VII/B.36-70 Plumbogummite PbAl3(PO4)2(OH)5·(H2O) R 3m 3 2/m |
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VII/B.36-80 Philipsbornite PbAl3(AsO4)2(OH)5·(H2O) R 3m-,R 3m Trig |
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VII/B.36-90 Waylandite BiAl3(PO4)2(OH)6 R 3m 3 2/m |
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VII/B.36-100 Eylettersite (Th,Pb)1-xAl3(PO4,SiO4)2(OH)6(?) R 3m 3 2/m |
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VII/B.36-110 Florencite-(Ce) CeAl3(PO4)2(OH)6 R 3m 3 2/m |
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VII/B.36-120 Arsenoflorencite-(Ce) (Ce,La)Al3(AsO4)2(OH)6 R 3m 3 2/m |
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VII/B.36-125 Arsenoflorencite-(La)* (La,Sr)Al3(AsO4,SO4,PO4)2(OH)6 R 3m 3m |
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VII/B.36-130 Florencite-(La) (La,Ce)Al3(PO4)2(OH)6 R 3m 3 2/m |
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VII/B.36-135 Arsenoflorencite-(Nd)* (Nd,La,Ce,Ba)(Al,Fe)3(AsO4,PO4)2(OH)6 R 3m 3m |
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VII/B.36-140 Florencite-(Nd) (Nd,Ce)Al3(PO4)2(OH)6 R 3m 3 2/m |
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VII/B.36-150 Benauite! HSrFe3(PO4)2(OH)6 R 3m 3 2/m |
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VII/B.36-150* Lusungite? (Sr,Pb)Fe3(PO4)2(OH)5·(H2O) R 3m 3m |
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VII/B.36-152 Graulichite-(Ce) CeFe3(AsO4)2(OH)6 R 3m 3 2/m |
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VII/B.36-155 Springcreekite! BaV3(PO4)2(OH,H2O)6 R 3m 3 2/m |
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VII/B.36-160 Dussertite BaFe3(AsO4)2(OH)5 R 3m 3m |
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VII/B.36-170 Zairite Bi(Fe,Al)3(PO4)2(OH)6 R 3m 3 2/m |
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Other Graulichite-(Ce) Information
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References: |
NAME( AmMin, 89:468) PHYS. PROP.(AmMin, 89:468) OPTIC PROP.(AmMin, 89:468) |
See Also: |
Links to other databases for Graulichite-(Ce) :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -Handbook of Mineralogy (UofA)
6 -MinDAT
7 -MinMax(Deutsch)
8 -MinMax(English)
9 -Mineralienatlas (Deutsch)
10 -QUT Mineral Atlas
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Print or Cut-and-Paste your Graulichite-(Ce) Specimen Label here :
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Graulichite-(Ce)
CeFe+++3(AsO4)2(OH)6
Dana No: 41.5.11.4 Strunz No: VII/B.36-152
Locality:
Notes:
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