General Freibergite Information
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Chemical Formula: |
(Ag,Cu,Fe)12(Sb,As)4S13 |
Composition: |
Molecular Weight = 1,929.46 gm |
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Iron 3.47 % Fe |
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Copper 11.86 % Cu |
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Silver 40.25 % Ag |
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Antimony 18.93 % Sb |
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Arsenic 3.88 % As |
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Sulfur 21.60 % S |
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______ |
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100.00 % |
Empirical Formula: |
Ag7.2Cu3.6Fe2+1.2Sb3AsS13 |
Environment: |
In hydrothermal deposits. |
IMA Status: |
Valid Species (Pre-IMA) 1853 |
Locality: |
Freiberg district, Saxony. Link to MinDat.org Location Data. |
Name Origin: |
Named after its locality. |
Synonym: |
ICSD 62116 |
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PDF 27-190 |
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Freibergite Image |
Images:
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Freibergite Crystallography
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Cell Dimensions: |
a = 10.47, Z = 2; V = 1,147.73 Den(Calc)= 5.58 |
Crystal System: |
Isometric - HextetrahedralH-M Symbol (4 3m) Space Group: I 43m |
X Ray Diffraction: |
By Intensity(I/Io): 3.05(1), 1.862(0.7), 2.64(0.5), |
Crystal Structure:
Mouse
drag1 - LMB Manipulate Structure
drag2 - RMB Resize/Rotate
Keyboard
S - Stereo Pair on/off
H - Help Screen
I - Data Info
A - Atoms On/Off
P - Polyhedra On/Off
B - Bonds On/Off
Help on Above
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Peterson R C , Miller I , Mineralogical Magazine , 50 (1986) p.717-721, Crystal structure and cation distribution in freibergite and tetrahedrite, Locality: Keno Hill, Yukon, Canada
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Physical Properties of Freibergite
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Cleavage: |
None |
Color: |
Gray, Steel gray, Black. |
Density: |
4.85 - 5, Average = 4.92 |
Diaphaniety: |
Opaque |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Massive - Granular - Common texture observed in granite and other igneous rock. |
Hardness: |
3.5-4 - Copper Penny-Fluorite |
Luster: |
Metallic |
Streak: |
reddish black |
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Optical Properties of Freibergite
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Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Freibergite in Air
| λ |
R |
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∑ R(λ) |
| 400 nm |
35.20 |
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| 420 nm |
35.10 |
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| 440 nm |
35.00 |
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| 460 nm |
34.70 |
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| 480 nm |
34.30 |
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| 500 nm |
33.70 |
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| 520 nm |
33.10 |
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| 540 nm |
32.60 |
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| 560 nm |
32.20 |
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| 580 nm |
31.80 |
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| 600 nm |
31.40 |
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| 620 nm |
30.90 |
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| 640 nm |
30.50 |
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| 660 nm |
30.00 |
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| 680 nm |
29.50 |
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| 700 nm |
29.00 |
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Calculated Relative Intensity Colors of Freibergite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
240% |
270% |
290% |
| R |
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Calculated Properties of Freibergite
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Electron Density: |
relectron=5.02 gm/cc note: rFreibergite =5.58 gm/cc. |
Fermion Index |
Fermion Index = 0.00235 Boson Index = 0.99765 |
Photoelectric: |
PEFreibergite = 174.53 barns/electron U=PEFreibergite x relectron= 876.24 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Freibergite is Not Radioactive |
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Freibergite Classification
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Dana Class: |
3.3.6.3 (3)Sulfides - Sulfosalts |
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(3.3)where 3 < z/y < 4 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.3.6)Tetrahedrite Group (Isometric: I4¯3m) |
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3.3.6.1 Tetrahedrite (Cu,Fe)12Sb4S13 I 43m 4 3m |
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3.3.6.2 Tennantite (Cu,Fe)12As4S13 I 43m 4 3m |
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3.3.6.3 Freibergite (Ag,Cu,Fe)12(Sb,As)4S13 I 43m 4 3m |
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3.3.6.4 Hakite (Cu,Hg)3(Sb,As)(Se,S)3 I 43m 4 3m |
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3.3.6.5 Giraudite (Cu,Zn,Ag)12(As,Sb)4(Se,S)13 I 43m 4 3m |
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3.3.6.6 Goldfieldite Cu12(Te,Sb,As)4S13 I 43m 4 3m |
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3.3.6.7 Argentotennantite (Ag,Cu)10(Zn,Fe)2(As,Sb)4S13 I 43m 4 3m |
Strunz Class: |
II/C.11-50 II - Sulfides and sulphosalts |
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II/C - Sulfides with metal: sulfur, selenium and tellurium = 1:1 |
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II/C.11 - Tetrahedrite group |
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II/C.11-10 Tennantite (Cu,Fe)12As4S13 I 43m 4 3m |
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II/C.11-20 Argentotennantite (Ag,Cu)10(Zn,Fe)2(As,Sb)4S13 I 43m 4 3m |
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II/C.11-30 Giraudite (Cu,Zn,Ag)12(As,Sb)4(Se,S)13 I 43m 4 3m |
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II/C.11-40 Tetrahedrite (Cu,Fe)12Sb4S13 I 43m 4 3m |
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II/C.11-50 Freibergite (Ag,Cu,Fe)12(Sb,As)4S13 I 43m 4 3m |
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II/C.11-60 Goldfieldite Cu12(Te,Sb,As)4S13 I 43m 4 3m |
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II/C.11-70 Hakite (Cu,Hg)3(Sb,As)(Se,S)3 I 43m 4 3m |
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II/C.11-75 Mgriite Cu3AsSe3 F d3m 4/m 3 2/m |
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II/C.11-80 Chameanite (Cu,Fe)4As(Se,S)4 I 43m 4 3m |
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Other Freibergite Information
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References: |
NAME( Ford32) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Freibergite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (UofA)
8 -MinDAT
9 -MinMax(Deutsch)
10 -MinMax(English)
11 -Mineralienatlas (Deutsch)
12 -QUT Mineral Atlas
13 - WWW-MINCRYST
14 -École des Mines de Paris
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Print or Cut-and-Paste your Freibergite Specimen Label here :
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Freibergite
(Ag,Cu,Fe)12(Sb,As)4S13
Dana No: 3.3.6.3 Strunz No: II/C.11-50
Locality:
Notes:
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