General Diaphorite Information
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Chemical Formula: |
Pb2Ag3Sb3S8 |
Composition: |
Molecular Weight = 1,359.78 gm |
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Silver 23.80 % Ag |
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Antimony 26.86 % Sb |
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Lead 30.48 % Pb |
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Sulfur 18.87 % S |
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______ |
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100.00 % |
Empirical Formula: |
Pb2Ag3Sb3S8 |
Environment: |
In hydrothermal veins with other sulfides, formed at a moderate temperature. |
IMA Status: |
Valid Species (Pre-IMA) 1871 |
Locality: |
Himmelsfürst Mine, Brand-Erbisdorf, Freiberg District, Erzgebirge, Saxony, Germany. Link to MinDat.org Location Data. |
Name Origin: |
From the Greek diaphora, "difference" as being distinct from freieslebenite. |
Synonym: |
Brongniardite |
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ICSD 38568 |
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PDF 9-126 |
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Diaphorite Image |
Images:
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Diaphorite Crystallography
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Axial Ratios: |
a:b:c =0.4937:1:0.1839 |
Cell Dimensions: |
a = 15.84, b = 32.08, c = 5.9, Z = 8; beta = 90.165° V = 2,998.06 Den(Calc)= 6.02 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 21/a |
X Ray Diffraction: |
By Intensity(I/Io): 3.296(1), 2.809(0.8), 2.945(0.4), |
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Crystal Structure:
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Armbruster T , Makovicky E , Berlepsch P , Sejkora J , European Journal of Mineralogy , 15 (2003) p.137-146, Crystal structure, cation ordering, and polytypic character of diaphorite,, Pb2Ag3Sb3S8, a PbS-based structure
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Physical Properties of Diaphorite
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Cleavage: |
None |
Color: |
Gray, Steel gray. |
Density: |
6 - 6.2, Average = 6.1 |
Diaphaniety: |
Opaque |
Fracture: |
Brittle - Generally displayed by glasses and most non-metallic minerals. |
Habit: |
Euhedral Crystals - Occurs as well-formed crystals showing good external form. |
Habit: |
Granular - Generally occurs as anhedral to subhedral crystals in matrix. |
Habit: |
Striated - Parallel lines on crystal surface or cleavage face. |
Hardness: |
2.5 - Finger Nail |
Luminescence: |
Non-fluorescent. |
Luster: |
Metallic |
Magnetism: |
Nonmagnetic |
Streak: |
steel gray |
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Optical Properties of Diaphorite
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RL Anisotrophism: |
Strong. |
RL Color: |
White to grayish white. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Diaphorite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
41.20 |
44.40 |

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| 420 nm |
40.60 |
43.60 |

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| 440 nm |
40.00 |
43.00 |

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| 460 nm |
39.40 |
42.50 |

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| 480 nm |
38.80 |
42.00 |

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| 500 nm |
38.30 |
41.60 |

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| 520 nm |
37.80 |
41.10 |

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| 540 nm |
37.30 |
40.70 |

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| 560 nm |
36.90 |
40.30 |

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| 580 nm |
36.50 |
39.80 |

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| 600 nm |
36.20 |
39.50 |

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| 620 nm |
35.80 |
39.10 |

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| 640 nm |
35.50 |
38.60 |

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| 660 nm |
35.00 |
38.20 |

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| 680 nm |
34.50 |
37.60 |

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| 700 nm |
33.80 |
37.00 |

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Calculated Relative Intensity Colors of Diaphorite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
240% |
250% |
| R1 |
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| R2 |
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Calculated Properties of Diaphorite
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Electron Density: |
relectron=5.19 gm/cc note: rDiaphorite =6.02 gm/cc. |
Fermion Index |
Fermion Index = 0.06876 Boson Index = 0.93124 |
Photoelectric: |
PEDiaphorite = 698.49 barns/electron U=PEDiaphorite x relectron=3,624.24 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Diaphorite is Not Radioactive |
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Diaphorite Classification
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Dana Class: |
3.5.4.1 (3)Sulfides - Sulfosalts |
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(3.5)where 2.5 < z/y < 3 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.5.4)Dana Group |
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3.5.4.1 Diaphorite Pb2Ag3Sb3S8 C 21/a 2/m |
Strunz Class: |
II/E.17-30 II - Sulfides and sulphosalts |
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II/E - Sulfosalts (S : As,Sb,Bi = x) Lead-Sulfosalts with As/Sb, x=3,0-2,5 |
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II/E.17 - Marrite - Owyheeite series |
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II/E.17-10 Marrite PbAgAsS3 P 21/a 2/m |
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II/E.17-20 Freieslebenite AgPbSbS3 P 21/n 2/m |
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II/E.17-30 Diaphorite Pb2Ag3Sb3S8 C 21/a 2/m |
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II/E.17-40 Zoubekite AgPb4Sb4S10 Unk Ortho |
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II/E.17-50 Owyheeite Pb7Ag2(Sb,Bi)8S20 Pnam 2/m 2/m 2/m |
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Other Diaphorite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Diaphorite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (UofA)
8 -MinDAT
9 -MinMax(Deutsch)
10 -MinMax(English)
11 -Mineralienatlas (Deutsch)
12 -QUT Mineral Atlas
13 -École des Mines de Paris
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Print or Cut-and-Paste your Diaphorite Specimen Label here :
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Diaphorite
Pb2Ag3Sb3S8
Dana No: 3.5.4.1 Strunz No: II/E.17-30
Locality:
Notes:
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