General Ulrichite Information
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Chemical Formula: |
CaCu(UO2)(PO4)2·4(H2O) |
Composition: |
Molecular Weight = 635.66 gm |
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Calcium 6.30 % Ca 8.82 % CaO |
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Uranium 37.45 % U 42.48 % UO2 |
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Copper 10.00 % Cu 12.51 % CuO |
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Phosphorus 9.75 % P 22.33 % P2O5 |
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Hydrogen 1.27 % H 11.34 % H2O |
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Oxygen 35.24 % O |
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______ ______ |
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100.00 % 97.48 % = TOTAL OXIDE |
Empirical Formula: |
CaCu(UO2)(PO4)2·4(H2O) |
IMA Status: |
Approved IMA 1988 |
Locality: |
Lake Boga, Victoria, Australia. Link to MinDat.org Location Data. |
Name Origin: |
Named for G.H.F. Ulrich. |
Synonym: |
ICSD 54139 |
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PDF 46-1302 |
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Ulrichite Image |
Images:
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Images:
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Ulrichite
Comments: Green, acicular crystals of ulrichite on matrix. Co-type specimen (?) collected by the discoverer, Anthony Fraser.
Location: Lake Boga granite quarry, Lake Boga, Victoria, Australia.
Scale: Picture size 2 mm.
© Paul M. Schumacher |
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Ulrichite Crystallography
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Axial Ratios: |
a:b:c =1.8273:1:1.8592 |
Cell Dimensions: |
a = 12.784, b = 6.996, c = 13.007, Z = 4; beta = 91.92° V = 1,162.65 Den(Calc)= 3.63 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 2/m |
X Ray Diffraction: |
By Intensity(I/Io): 6.389(1), 3.193(0.45), 2.879(0.2), |
Crystal Structure:
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Kolitsch U , Giester G , Mineralogical Magazine , 65 (2001) p.717-724, Revision of the crystal structure of ulrichite, CaCu2+(UO2)(PO4)2*4(H2O), Locality: Lake Boga, near Swan Hill, Victoria, Australia
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Physical Properties of Ulrichite
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Cleavage: |
[???] Perfect |
Color: |
Green, Lime green. |
Diaphaniety: |
Transparent to Translucent |
Habit: |
Acicular - Occurs as needle-like crystals. |
Habit: |
Radial - Crystals radiate from a center without producing stellar forms (e.g. stibnite) |
Hardness: |
3.5 - Copper Penny |
Luster: |
Vitreous (Glassy) |
Streak: |
white |
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Optical Properties of Ulrichite
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Gladstone-Dale: |
CI calc= -0.07 (Fair) - where the CI = (1-KPDcalc/KC) KPDcalc= 0.173,KC= 0.1617 |
Optical Data: |
Biaxial (-), a=1.622, g=1.634, bire=0.0120 |
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Calculated Properties of Ulrichite
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Electron Density: |
relectron=3.32 gm/cc note: rUlrichite =3.63 gm/cc. |
Fermion Index |
Fermion Index = 0.00295 Boson Index = 0.99705 |
Photoelectric: |
PEUlrichite = 933.86 barns/electron U=PEUlrichite x relectron=3,103.77 barns/cc. |
Radioactivity: |
GRapi = 2,922,418.65 (Gamma Ray American Petroleum Institute Units)
Ulrichite is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
10.41 ± 2.60 grams of pure Ulrichite .
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 100 cm box)
1040.8 ±260.20 grams of pure Ulrichite .
Estimated Radioactivity from Ulrichite - very strong
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 8.07 cm |
67,028,698 |
1.81E-03 |
2,922,418.65 |
960.80 |
| 100 gm / 3.75 cm |
6,702,870 |
1.81E-04 |
292,241.86 |
96.08 |
| 10 gm / 1.74 cm |
670,287 |
1.81E-05 |
29,224.19 |
9.61 |
| 1 gm / 8.07 mm |
67,029 |
1.81E-06 |
2,922.42 |
0.96 |
| 0.1 gm / 3.75 mm |
6,703 |
1.81E-07 |
292.24 |
0.10 |
| 0.01 gm / 1.74 mm |
670 |
1.81E-08 |
29.22 |
0.01 |
| 0.001 gm / 0.81 mm |
67 |
1.81E-09 |
2.92 |
0.00 |
Weight of pure Ulrichite in grams (gm) and Calculated Diameter of a Sphere with a Density of 3.63 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
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Ulrichite Classification
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Dana Class: |
40.2a.33.1 (40)Hydrated Phosphates, etc |
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(40.2a)where A++ (B++)2 (XO4) · x(H2O), containing (UO2)++ |
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(40.2a.33)Dana Group |
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40.2a.33.1 Ulrichite CaCu(UO2)(PO4)2·4(H2O) C 2/m 2/m |
Strunz Class: |
VII/E.02-190 VII - Phosphates, Arsenates and Vanadates |
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VII/E - Uranylphosphates and uranylvanadates with [UO2]2+ - [PO4 | AsO4]3- and [UO2]2+ - [V2O8]6- |
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VII/E.02 - Meta-autunite group |
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VII/E.02-10 Metanovacekite Mg(UO2)2(AsO4)2·4-8(H2O) P 4/n 4/m |
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VII/E.02-20 Bassetite Fe(UO2)2(PO4)2·8(H2O) P 21/m 2/m |
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VII/E.02-30 Metakahlerite Fe(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-40 Lehnerite Mn[UO2/PO4]2·8(H2O) P 21/n 2/m |
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VII/E.02-50 Metakirchheimerite Co(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-60 Metatorbernite Cu(UO2)2(PO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-70 Metazeunerite Cu(UO2)2(AsO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-80 Metalodevite Zn(UO2)2(AsO4)2·10(H2O) P 41/m 4/m |
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VII/E.02-90 Meta-autunite Ca(UO2)2(PO4)2·2-6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-95 Sodium meta-autunite! Na2(UO2)2(PO4)2·6-8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-100 Meta-uranospinite Ca(UO2)2(AsO4)2·8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-110 Meta-uranocircite Ba(UO2)2(PO4)2·6-8(H2O) P 21 2 |
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VII/E.02-120 Metaheinrichite Ba(UO2)2(AsO4)2·8(H2O) P 41/? 4/m |
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VII/E.02-130 Sodium-uranospinite (Na2,Ca)(UO2)2(AsO4)2·5(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-140 Meta-ankoleite K2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-150 Abernathyite K(UO2)(AsO4)·4(H2O) P 4/ncc 4/m 2/m 2/m |
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VII/E.02-160 Uramphite (NH4)(UO2)(PO4)·3(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-170 Chernikovite (H3O)2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-180 Pseudo-autunite* (H3O)4Ca2(UO2)2(PO4)4·5(H2O)(?) Unk Ortho |
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VII/E.02-190 Ulrichite CaCu(UO2)(PO4)2·4(H2O) C 2/m 2/m |
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Other Ulrichite Information
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References: |
PHYS. PROP.(Am.Min.,Vol.75,p243,1990) OPTIC PROP.(Am.Min.,Vol.75,p243,1990) |
See Also: |
Links to other databases for Ulrichite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (UofA)
8 -MinDAT
9 -MinMax(Deutsch)
10 -MinMax(English)
11 -Mineralienatlas (Deutsch)
12 -QUT Mineral Atlas
13 - Uranium Minerals
14 -École des Mines de Paris
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Print or Cut-and-Paste your Ulrichite Specimen Label here :
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Ulrichite
CaCu(UO2)(PO4)2·4(H2O)
Dana No: 40.2a.33.1 Strunz No: VII/E.02-190
Locality:
Notes:
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