General Poyarkovite Information
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Chemical Formula: |
Hg3ClO |
Composition: |
Molecular Weight = 653.22 gm |
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Mercury 92.12 % Hg 95.80 % Hg2O |
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Chlorine 5.43 % Cl 5.43 % Cl |
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- % Cl -1.22 % -O=Cl2 |
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Oxygen 2.45 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Hg3ClO |
Environment: |
Oxidized cinnabar ores. |
IMA Status: |
Approved IMA 1981 |
Locality: |
Khaydarkan (Kyrgyzstan) antimony-mercury deposit. Arzak mercury deposit, situated about 12 km northeast of the well-known Terlig-Khaya mercury mine, Pii-Khem district, Tuva Republic, R
Link to MinDat.org Location Data. |
Name Origin: |
Named for Vlakimir Erastovich Poyarkov, Russian geologist, well-known investigator of mercury and antimony deposits. |
Synonym: |
ICSD 87734 |
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PDF 33-920 |
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Poyarkovite Image |
Images:
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Poyarkovite Crystallography
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Axial Ratios: |
a:b:c =2.1078:1:1.8682 |
Cell Dimensions: |
a = 19.009, b = 9.018, c = 16.848, Z = 24; beta = 110.82° V = 2,699.55 Den(Calc)= 9.64 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 2/c |
X Ray Diffraction: |
By Intensity(I/Io): 2.38(1), 2.74(0.8), 2.6(0.6), |
Crystal Structure:
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Vasil ev V I , Pervukhina N V , Romanenko G V , Magarill S A , Borisov S V , The Canadian Mineralogist , 37 (1999) p.119-126, New data on the mercury oxide-chloride mineral poyarkovite: The second, find, and crystal-structure determination
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Physical Properties of Poyarkovite
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Cleavage: |
None |
Color: |
Dark red, Red, Black. |
Density: |
9.56 |
Diaphaniety: |
Opaque to translucent |
Fracture: |
Conchoidal - Fractures developed in brittle materials characterized by smoothly curving surfaces, (e.g. quartz). |
Habit: |
Anhedral Grains - Granular minerals without the expression of crystal shapes |
Hardness: |
2-2.5 - Gypsum-Finger Nail |
Luster: |
Vitreous - Adamantine |
Streak: |
red |
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Optical Properties of Poyarkovite
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Gladstone-Dale: |
CI meas= 0.326 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= 0.331 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1037,KPDmeas= 0.1046,KC= 0.1551 |
Optical Data: |
Biaxial (?), b=2 |
Pleochroism (x): |
deep red. |
Pleochroism (z): |
brownish red. |
RL Anisotrophism: |
Strong, azure to blue. |
RL Color: |
White. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Poyarkovite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 440 nm |
25.00 |
31.00 |

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| 460 nm |
24.50 |
31.00 |

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| 480 nm |
22.50 |
31.00 |

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| 500 nm |
22.50 |
30.00 |

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| 520 nm |
22.20 |
29.20 |

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| 540 nm |
22.00 |
28.40 |

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| 560 nm |
21.60 |
27.20 |

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| 580 nm |
20.90 |
25.50 |

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| 600 nm |
20.00 |
23.50 |

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| 620 nm |
18.50 |
22.10 |

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| 640 nm |
17.00 |
20.70 |

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Calculated Relative Intensity Colors of Poyarkovite in Air
Relative Intensity |
0% |
50% |
100% |
150% |
200% |
250% |
300% |
350% |
400% |
450% |
| R1 |
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| R2 |
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Calculated Properties of Poyarkovite
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Electron Density: |
relectron=7.76 gm/cc note: rPoyarkovite =9.56 gm/cc. |
Fermion Index |
Fermion Index = 0.27822 Boson Index = 0.72178 |
Photoelectric: |
PEPoyarkovite =1,607.49 barns/electron U=PEPoyarkovite x relectron=12468.73 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Poyarkovite is Not Radioactive |
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Poyarkovite Classification
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Dana Class: |
10.5.2.1 (10)Oxyhalides and Hydroxyhalides |
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(10.5)where Am (O,OH)p Xq |
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(10.5.2)Dana Group |
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10.5.2.1 Poyarkovite Hg3ClO C 2/c 2/m |
Strunz Class: |
III/D.06-20 III - Halogenides |
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III/D - Oxi-halogenides with mercury |
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III/D.06 - Terlinguaite - Comancheite |
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III/D.06-10 Terlinguaite HgHgClO C 2/c 2/m |
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III/D.06-11 Aurivilliusite! HgHgOI C 2/m 2/m |
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III/D.06-12 Hanawaltite Hg6Hg[Cl,(OH)]2O3 Pbma 2/m 2/m 2/m |
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III/D.06-13 Tedhadleyite! HgHg10O4I2(Cl1.16Br0.84)2 A1 1 |
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III/D.06-20 Poyarkovite Hg3ClO C 2/c 2/m |
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III/D.06-30 Kadyrelite Hg4(Br,Cl)2O I a3d 4/m 3 2/m |
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III/D.06-40 Eglestonite Hg6Cl3O(OH)(?) I a3d 4/m 3 2/m |
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III/D.06-45 Vasilyevite! (Hg2)10O6I3Cl(CO3) P1 1 |
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III/D.06-50 Mosesite Hg2N(Cl,SO4,MoO4,CO3)·(H2O) F43m 4 3m |
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III/D.06-60 Gianellaite Hg4(SO4)N2 F43m 4 3m |
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III/D.06-70 Kleinite Hg2N(Cl,SO4)·n(H2O) C63/mmc 6/m 2/m 2/m |
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III/D.06-80 Pinchite Hg5O4Cl2 I bam 2/m 2/m 2/m |
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III/D.06-90 Comancheite Hg13(Cl,Br)8O9 Pnnm,Pnn2 Ortho |
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Other Poyarkovite Information
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References: |
NAME( CanMin, 2/99) PHYS. PROP.(CanMin, 2/99) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Poyarkovite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 -École des Mines de Paris
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Poyarkovite
Hg3ClO
Dana No: 10.5.2.1 Strunz No: III/D.06-20
Locality:
Notes:
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