General Polydymite Information
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Chemical Formula: |
NiNi2S4 |
Composition: |
Molecular Weight = 304.33 gm |
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Nickel 57.85 % Ni |
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Sulfur 42.15 % S |
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______ |
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100.00 % |
Empirical Formula: |
NiNi2S4 |
Environment: |
Found in hydrothermal veins. Forms a series with linnaeite. |
IMA Status: |
Valid Species (Pre-IMA) 1876 |
Locality: |
Grünau mine, Sayn-Altenkirchen, Nordrhein-Westfalen, Germany. Link to MinDat.org Location Data. |
Name Origin: |
From the Greek for "many" and "twin", as the mineral is observed in twinned forms. |
Synonym: |
ICSD 36271 |
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PDF 47-1739 |
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Polydymite Image |
Images:
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Polydymite
Comments: Octahedral crystals of polydymite on matrix.
Location: Gr?neau Mine (Gr?ne Au Mine; Gr?nau Mine), Schutzbach, Betzdorf, Siegen District (W), Rhineland-Palatinate, Germany.
Scale: Picture size 5 mm.
© Thomas Witzke / Abraxas-Verlag |
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Polydymite Crystallography
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Cell Dimensions: |
a = 9.405, Z = 8; V = 831.91 Den(Calc)= 4.86 |
Crystal System: |
Isometric - HexoctahedralH-M Symbol (4/m 3 2/m) Space Group: F d3m |
X Ray Diffraction: |
By Intensity(I/Io): 1.674(1), 2.36(0.9), 2.85(0.9), |
Forms:
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Forms:
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Crystal Structure:
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Lundqvist D , Arkiv for Mineralogi och Geologi , 24 (1947) p.1-12, X-ray studies on the binary system Ni-S, Note: spinel structure, Locality: synthetic
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Physical Properties of Polydymite
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Cleavage: |
[001] Indistinct |
Color: |
Violet gray, Copper red, Light gray, Steel gray. |
Density: |
4.5 - 4.8, Average = 4.65 |
Diaphaniety: |
Opaque |
Fracture: |
Conchoidal - Uneven - Uneven fracture producing small, conchoidal fragments. |
Habit: |
Massive - Granular - Common texture observed in granite and other igneous rock. |
Habit: |
Octahedral Crystals - Occurs as octahedral shaped crystals. |
Habit: |
Twinning Common - Crystals are usually twinned. |
Hardness: |
4.5-5.5 - Near Apatite |
Luster: |
Metallic |
Streak: |
black gray |
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Optical Properties of Polydymite
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Optical Data: |
NCalc= 1.9 - from Gladstone-Dale relationship (KC = 0.1842) where Ncalc=Dcalc*KC+1
NCalc= 1.86 - from Gladstone-Dale relationship (KC = 0.1842) where Ncalc=Dmeas*KC+1 |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Polydymite in Air
| λ |
R |
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∑ R(λ) |
| 400 nm |
41.40 |
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| 420 nm |
42.00 |
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| 440 nm |
42.60 |
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| 460 nm |
43.30 |
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| 480 nm |
43.80 |
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| 500 nm |
44.40 |
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| 520 nm |
44.90 |
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| 540 nm |
45.40 |
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| 560 nm |
46.20 |
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| 580 nm |
47.10 |
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| 600 nm |
48.10 |
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| 620 nm |
49.20 |
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| 640 nm |
50.50 |
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| 660 nm |
51.70 |
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| 680 nm |
53.10 |
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| 700 nm |
54.50 |
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Calculated Relative Intensity Colors of Polydymite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
| R |
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Calculated Properties of Polydymite
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Electron Density: |
relectron=4.73 gm/cc note: rPolydymite =4.86 gm/cc. |
Fermion Index |
Fermion Index = 0.00969 Boson Index = 0.99031 |
Photoelectric: |
PEPolydymite = 25.34 barns/electron U=PEPolydymite x relectron= 119.77 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Polydymite is Not Radioactive |
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Polydymite Classification
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Dana Class: |
2.10.1.7 (2)Sulfides - Including Selenides and Tellurides |
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(2.10)where Am Bn Xp, with (m+n):p=3:4 |
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(2.10.1)Linnaeite Group (Isometric: Fd3m) |
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2.10.1.1 Linnaeite CoCo2S4 F d3m 4/m 3 2/m |
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2.10.1.2 Carrollite Cu(Co,Ni)2S4 F d3m 4/m 3 2/m |
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2.10.1.3 Fletcherite Cu(Ni,Co)2S4 F d3m 4/m 3 2/m |
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2.10.1.4 Tyrrellite (Cu,Co,Ni)3Se4 F d3m 4/m 3 2/m |
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2.10.1.5 Bornhardtite CoCo2Se4 F d3m 4/m 3 2/m |
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2.10.1.6 Siegenite (Ni,Co)3S4 F d3m 4/m 3 2/m |
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2.10.1.7 Polydymite NiNi2S4 F d3m 4/m 3 2/m |
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2.10.1.8 Violarite FeNi2S4 F d3m 4/m 3 2/m |
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2.10.1.9 Trustedtite Ni3Se4 F d3m 4/m 3 2/m |
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2.10.1.10 Greigite FeFe2S4 F d3m 4/m 3 2/m |
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2.10.1.11 Daubreelite FeCr2S4 F d3m 4/m 3 2/m |
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2.10.1.12 Indite FeIn2S4 F d3m 4/m 3 2/m |
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2.10.1.13 Kalininite ZnCr2S4 F d3m 4/m 3 2/m |
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2.10.1.14 Florensovite Cu(Cr1.5Sb0.5)S4 F d3m 4/m 3 2/m |
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2.10.1.15 Cuproiridsite CuIr2S4 F d3m 4/m 3 2/m |
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2.10.1.16 Cuprorhodsite CuRh2S4 F d3m 4/m 3 2/m |
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2.10.1.17 Malanite Cu(Pt,Ir)2S4 F d3m 4/m 3 2/m |
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2.10.1.18 Ferrorhodsite (Fe,Cu)(Rh,Ir,Pt)2S4 F d3m 4/m 3 2/m |
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2.10.1.19 Cadmoindite! CdIn2S4 F d3m 4/m 3 2/m |
Strunz Class: |
II/D.01-30 II - Sulfides and sulphosalts |
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II/D - Sulfides with metal: sulfur, selenium and tellurium < 1:1, Tellurides with Copper, Silver, Gold |
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II/D.01 - Linneite group and related compounds |
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II/D.01-10 Greigite FeFe2S4 F d3m 4/m 3 2/m |
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II/D.01-20 Linnaeite CoCo2S4 F d3m 4/m 3 2/m |
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II/D.01-30 Polydymite NiNi2S4 F d3m 4/m 3 2/m |
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II/D.01-40 Carrollite Cu(Co,Ni)2S4 F d3m 4/m 3 2/m |
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II/D.01-50 Fletcherite Cu(Ni,Co)2S4 F d3m 4/m 3 2/m |
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II/D.01-60 Florensovite Cu(Cr1.5Sb0.5)S4 F d3m 4/m 3 2/m |
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II/D.01-70 Violarite FeNi2S4 F d3m 4/m 3 2/m |
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II/D.01-80 Siegenite (Ni,Co)3S4 F d3m 4/m 3 2/m |
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II/D.01-90 Indite FeIn2S4 F d3m 4/m 3 2/m |
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II/D.01-95 Cadmoindite! CdIn2S4 F d3m 4/m 3 2/m |
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II/D.01-100 Daubreelite FeCr2S4 F d3m 4/m 3 2/m |
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II/D.01-110 Kalininite ZnCr2S4 F d3m 4/m 3 2/m |
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II/D.01-120 Bornhardtite CoCo2Se4 F d3m 4/m 3 2/m |
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II/D.01-130 Trustedtite Ni3Se4 F d3m 4/m 3 2/m |
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II/D.01-140 Tyrrellite (Cu,Co,Ni)3Se4 F d3m 4/m 3 2/m |
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Other Polydymite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Polydymite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - Google Images
6 - Google Scholar
7 - Handbook of Mineralogy (MinSocAm)
8 - Handbook of Mineralogy (UofA)
9 - MinDAT
10 - MinMax(Deutsch)
11 - MinMax(English)
12 - Mineralienatlas (Deutsch)
13 - QUT Mineral Atlas
14 - Ruff.Info
15 - WWW-MINCRYST
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Polydymite
NiNi2S4
Dana No: 2.10.1.7 Strunz No: II/D.01-30
Locality:
Notes:
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