General Pillaite Information
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Chemical Formula: |
Pb9Sb10S23ClO0.5 |
Composition: |
Molecular Weight = 3,909.56 gm |
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Copper 0.16 % Cu |
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Antimony 30.52 % Sb |
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Lead 49.29 % Pb |
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Sulfur 18.86 % S |
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Chlorine 0.96 % Cl |
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Oxygen 0.20 % O |
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______ |
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100.00 % |
Empirical Formula: |
Pb9.3Sb9.8Cu0.1S23Cl1.06O0.5 |
Environment: |
Calcite veins that cut the Ba-Fe orebody and host rocks. |
IMA Status: |
Approved IMA 2001 (Dana # Added) |
Locality: |
Buca della Vena mine in the Apuan Alps of norhtern Tuscany, Italy. Link to MinDat.org Location Data. |
Name Origin: |
Named for Leopoldo Pilla (1805-1848), Italian Earth scientist. |
Synonym: |
IMA1997-042 |
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Pillaite Image |
Images:
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Pillaite
Comments: Scanning electron microscope image of acicular pillaite fibers. (Eur. J. Mineral, 13:606).
Location: Buca della Vena mine in the Apuan Alps, northern Tuscany, Italy.
Scale: See Image.
© Eur. J. Mineral |
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Pillaite Crystallography
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Axial Ratios: |
a:b:c =11.9638:1:5.2795 |
Cell Dimensions: |
a = 49.65, b = 4.15, c = 21.91, Z = 4; beta = 99.76° V = 4,449.16 Den(Calc)= 5.84 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 2/m |
X Ray Diffraction: |
By Intensity(I/Io): 3.48(1)(206), 2.956(0.47)(515,914), 3.458(0.4)(12.0.4),4.14(0.27)(205), 3.261(0.26)(406,12.0.2), |
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Physical Properties of Pillaite
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Cleavage: |
None |
Color: |
Black. |
Diaphaniety: |
Opaque |
Fracture: |
Brittle - Irregular - Very brittle fracture producing irregular fragments |
Habit: |
Acicular - Occurs as needle-like crystals. |
Hardness: |
3-4 - Calcite-Fluorite |
Luster: |
Metallic |
Streak: |
brownish black |
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Optical Properties of Pillaite
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Optical Data: |
NCalc= 1.02 - from Gladstone-Dale relationship (KC = 0.0035) where Ncalc=Dcalc*KC+1 |
RL Anisotrophism: |
Weak. |
RL Bireflectance: |
Weak. |
RL Color: |
Rare red internal reflections. |
RL Pleochroism: |
None. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Pillaite in Air
| λ |
R |
 |
∑ R(λ) |
| 400 nm |
37.00 |
 |
|
| 410 nm |
35.30 |
 |
| 420 nm |
37.70 |
 |
| 430 nm |
36.30 |
 |
| 440 nm |
36.00 |
 |
| 450 nm |
36.70 |
 |
| 460 nm |
35.90 |
 |
| 470 nm |
35.70 |
 |
| 480 nm |
35.40 |
 |
| 490 nm |
35.30 |
 |
| 500 nm |
35.40 |
 |
| 510 nm |
35.10 |
 |
| 520 nm |
34.70 |
 |
| 530 nm |
34.40 |
 |
| 540 nm |
34.90 |
 |
| 550 nm |
34.20 |
 |
| 560 nm |
34.20 |
 |
| 570 nm |
34.50 |
 |
| 580 nm |
34.20 |
 |
| 590 nm |
34.00 |
 |
| 600 nm |
32.70 |
 |
| 610 nm |
32.90 |
 |
| 620 nm |
32.80 |
 |
| 630 nm |
32.80 |
 |
| 640 nm |
32.40 |
 |
| 650 nm |
32.70 |
 |
| 660 nm |
31.90 |
 |
| 670 nm |
31.90 |
 |
| 680 nm |
31.50 |
 |
| 690 nm |
31.00 |
 |
| 700 nm |
30.50 |
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Standardized Intensity (100%) Reflection Spectra of Pillaite in Oil
| λ |
R |
 |
∑ R(λ) |
| 400 nm |
21.25 |
 |
|
| 410 nm |
20.30 |
 |
| 420 nm |
19.80 |
 |
| 430 nm |
20.00 |
 |
| 440 nm |
20.50 |
 |
| 450 nm |
20.40 |
 |
| 460 nm |
20.50 |
 |
| 470 nm |
20.10 |
 |
| 480 nm |
20.00 |
 |
| 490 nm |
19.75 |
 |
| 500 nm |
19.25 |
 |
| 510 nm |
19.45 |
 |
| 520 nm |
19.25 |
 |
| 530 nm |
18.95 |
 |
| 540 nm |
18.60 |
 |
| 550 nm |
18.75 |
 |
| 560 nm |
18.35 |
 |
| 570 nm |
18.15 |
 |
| 580 nm |
18.15 |
 |
| 590 nm |
17.60 |
 |
| 600 nm |
17.65 |
 |
| 610 nm |
17.50 |
 |
| 620 nm |
16.85 |
 |
| 630 nm |
16.90 |
 |
| 640 nm |
16.75 |
 |
| 650 nm |
16.45 |
 |
| 660 nm |
16.10 |
 |
| 670 nm |
16.15 |
 |
| 680 nm |
16.05 |
 |
| 690 nm |
15.55 |
 |
| 700 nm |
15.40 |
 |
Calculated Relative Intensity Colors of Pillaite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
240% |
270% |
| R |
|
|
|
|
|
|
|
|
|
|
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Calculated Relative Intensity Colors of Pillaite in Oil
Relative Intensity |
0% |
60% |
100% |
120% |
180% |
240% |
300% |
360% |
420% |
480% |
510% |
| R |
|
|
|
|
|
|
|
|
|
|
|
|
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Calculated Properties of Pillaite
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Electron Density: |
relectron=4.95 gm/cc note: rPillaite =5.84 gm/cc. |
Fermion Index |
Fermion Index = 0.11034 Boson Index = 0.88966 |
Photoelectric: |
PEPillaite =1,000.79 barns/electron U=PEPillaite x relectron=4,949.24 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Pillaite is Not Radioactive |
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Pillaite Classification
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Dana Class: |
3.8.1.2 (3)Sulfides - Sulfosalts |
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(3.8)where 1 < z/y <2 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.8.1)Dana Group |
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3.8.1.1 Zinkenite Pb9Sb22S42 P 63 6 |
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3.8.1.2 Pillaite ! Pb9Sb10S23ClO0.5 C 2/m 2/m |
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3.8.1.3 Pellouxite! (Cu,Ag)Pb10Sb12S27(Cl,S)0.6O C 2/m 2/m |
Strunz Class: |
II/E.19-45 II - Sulfides and sulphosalts |
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II/E - Sulfosalts (S : As,Sb,Bi = x) Lead-Sulfosalts with predominant Antimon x = 3.0 - 1.9 |
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II/E.19 - Falkmanite - Jaskolskiite series |
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II/E.19-10 Falkmanite Pb5Sb4S11 Mono |
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II/E.19-20 Ardaite Pb19Sb13S35Cl7 Unk Mono |
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II/E.19-30 Boulangerite Pb5Sb4S11 Unk Ortho |
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II/E.19-40 Plumosite* Pb2Sb2S5 Mono |
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II/E.19-42 Moeloite! Pb6Sb6S14(S3) P 21221 2 2 2 |
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II/E.19-45 Pillaite Pb9Sb10S23ClO0.5 C 2/m 2/m |
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II/E.19-50 Jaskolskiite Pb2xCux(Sb,Bi)2-xS5,x=0.2 Pbnm 2/m 2/m 2/m |
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Other Pillaite Information
|
References: |
NAME( AmMin, Vol 87, P 181) PHYS. PROP.(AmMin, Vol 87, P 181) OPTIC PROP.(EurJMin, v 13, p 605) |
See Also: |
Links to other databases for Pillaite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -Handbook of Mineralogy (UofA)
6 -MinDAT
7 -MinMax(Deutsch)
8 -MinMax(English)
9 -Mineralienatlas (Deutsch)
10 -QUT Mineral Atlas
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Print or Cut-and-Paste your Pillaite Specimen Label here :
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Pillaite
Pb9Sb10S23ClO0.5
Dana No: 3.8.1.2 Strunz No: II/E.19-45
Locality:
Notes:
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