General Parapierrotite Information
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Chemical Formula: |
Tl(Sb,As)5S8 |
Composition: |
Molecular Weight = 1,041.56 gm |
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Thallium 19.62 % Tl |
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Antimony 51.43 % Sb |
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Arsenic 4.32 % As |
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Sulfur 24.63 % S |
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______ |
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100.00 % |
Empirical Formula: |
TlSb4.4As0.6S8 |
Environment: |
Hydrothermal origin, in cavities in realgar. |
IMA Status: |
Approved IMA 1975 |
Locality: |
Allchar, Macedonia, Yugoslavia. Link to MinDat.org Location Data. |
Name Origin: |
Named for its relationship to pierrotite. |
Synonym: |
ICSD 100291 |
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PDF 29-1330 |
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Parapierrotite Image |
Images:
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Parapierrotite Crystallography
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Axial Ratios: |
a:b:c =0.4144:1:0.4666 |
Cell Dimensions: |
a = 8.02, b = 19.35, c = 9.03, Z = 4; beta = 91.967° V = 1,400.51 Den(Calc)= 4.94 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 21/n |
X Ray Diffraction: |
By Intensity(I/Io): 2.832(1), 3.493(1), 4.15(0.9), |
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Crystal Structure:
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Engel P , Zeitschrift fur Kristallographie , 151 (1980) p.203-216, Die kristallstruktur von synthetischem parapierrotit, TlSb5S8, Locality: synthetic
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Physical Properties of Parapierrotite
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Cleavage: |
None |
Color: |
Black. |
Density: |
5.04 |
Diaphaniety: |
Opaque |
Habit: |
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline). |
Hardness: |
2.5-3 - Finger Nail-Calcite |
Luster: |
Sub Metallic |
Streak: |
gray |
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Optical Properties of Parapierrotite
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RL Anisotrophism: |
Distinct, brownish gray to bluish gray. |
RL Color: |
White with a creamy tint with rare purple-red internal reflections. |
RL Pleochroism: |
Weak in air , grayish white to brownish gray in oil. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Parapierrotite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
31.70 |
42.80 |

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| 420 nm |
31.30 |
42.20 |

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| 440 nm |
30.90 |
41.60 |

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| 460 nm |
30.30 |
41.10 |

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| 480 nm |
29.90 |
40.60 |

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| 500 nm |
29.50 |
40.30 |

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| 520 nm |
29.30 |
40.00 |

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| 540 nm |
29.10 |
39.70 |

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| 560 nm |
28.80 |
39.20 |

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| 580 nm |
28.60 |
38.50 |

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| 600 nm |
28.20 |
37.90 |

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| 620 nm |
27.90 |
37.10 |

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| 640 nm |
27.30 |
36.10 |

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| 660 nm |
26.70 |
35.10 |

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| 680 nm |
26.00 |
34.10 |

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| 700 nm |
26.60 |
34.20 |

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Calculated Relative Intensity Colors of Parapierrotite in Air
Relative Intensity |
0% |
40% |
80% |
100% |
120% |
160% |
200% |
240% |
280% |
320% |
| R1 |
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| R2 |
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Calculated Properties of Parapierrotite
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Electron Density: |
relectron=4.30 gm/cc note: rParapierrotite =4.94 gm/cc. |
Fermion Index |
Fermion Index = 0.00184 Boson Index = 0.99816 |
Photoelectric: |
PEParapierrotite = 510.13 barns/electron U=PEParapierrotite x relectron=2,193.00 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Parapierrotite is Not Radioactive |
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Parapierrotite Classification
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Dana Class: |
3.8.14.1 (3)Sulfides - Sulfosalts |
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(3.8)where 1 < z/y <2 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.8.14)Dana Group |
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3.8.14.1 Parapierrotite Tl(Sb,As)5S8 P 21/n 2/m |
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3.8.14.2 Bernardite Tl(As,Sb)5S8 P 21/c 2/m |
Strunz Class: |
II/E.14-40 II - Sulfides and sulphosalts |
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II/E - Sulfosalts (S : As,Sb,Bi = x) Sulfosalts with predominant Thallium and Mercury, x = 4.0 - 1.6 |
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II/E.14 - Rebulite - Chabourneite series |
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II/E.14-10 Rebulite Tl5Sb5As8S22 P 21/c 2/m |
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II/E.14-12 Jankovicite Tl5Sb9(As,Sb)4S22 P1 1 |
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II/E.14-15 Imhofite Tl6CuAs16S40 P 21/n 2/m |
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II/E.14-20 Bernardite Tl(As,Sb)5S8 P 21/c 2/m |
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II/E.14-25 Gillulyite Tl2(As,Sb)8S13 P 2/n 2/m |
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II/E.14-30 Pierrotite Tl2Sb6As4S16 P na21 mm2 |
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II/E.14-40 Parapierrotite Tl(Sb,As)5S8 P 21/n 2/m |
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II/E.14-50 Chabourneite (Tl,Pb)21(Sb,As)91S147 P1 1 |
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Other Parapierrotite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Parapierrotite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - WWW-MINCRYST
13 -École des Mines de Paris
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Print or Cut-and-Paste your Parapierrotite Specimen Label here :
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Parapierrotite
Tl(Sb,As)5S8
Dana No: 3.8.14.1 Strunz No: II/E.14-40
Locality:
Notes:
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