General Luzonite Information
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Chemical Formula: |
Cu3AsS4 |
Composition: |
Molecular Weight = 393.82 gm |
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Copper 48.41 % Cu |
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Arsenic 19.02 % As |
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Sulfur 32.57 % S |
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______ |
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100.00 % |
Empirical Formula: |
Cu3AsS4 |
Environment: |
Low to moderate temperature hydrothermal deposits. Dimorphous with enargite. |
IMA Status: |
Valid Species (Pre-IMA) 1874 |
Locality: |
Mancayan, Luzon Island, Phillippines. Link to MinDat.org Location Data. |
Name Origin: |
Named after the locality |
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Luzonite Image |
Images:
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Luzonite Crystallography
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Axial Ratios: |
a:c = 1:1.97826 |
Cell Dimensions: |
a = 5.29, c = 10.465, Z = 2; V = 292.85 Den(Calc)= 4.47 |
Crystal System: |
Tetragonal - ScalenohedralH-M Symbol (4 2m) Space Group: I 42m |
X Ray Diffraction: |
By Intensity(I/Io): 3.046(1), 1.855(0.9), 1.592(0.7), |
Crystal Structure:
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drag2 - RMB Resize/Rotate
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Marumo F , Nowacki W , Zeitschrift fur Kristallographie , 124 (1967) p.1-8, A refinement of the crystal structure of luzonite, Cu3AsS4, Locality: Cerro de Pasco, Peru
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Physical Properties of Luzonite
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Cleavage: |
None |
Color: |
Gray, Dark pink brown, Red. |
Density: |
4.4 - 4.6, Average = 4.5 |
Diaphaniety: |
Opaque |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Euhedral Crystals - Occurs as well-formed crystals showing good external form. |
Habit: |
Granular - Generally occurs as anhedral to subhedral crystals in matrix. |
Hardness: |
3.5 - Copper Penny |
Luster: |
Metallic |
Streak: |
black |
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Optical Properties of Luzonite
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RL Anisotrophism: |
Strong, in greenish yellow and purplish. |
RL Color: |
Pale brownish pink. |
RL Pleochroism: |
Weak. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Luzonite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
26.50 |
29.20 |

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| 420 nm |
25.50 |
27.70 |

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| 440 nm |
24.50 |
26.20 |

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| 460 nm |
23.80 |
25.00 |

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| 480 nm |
23.60 |
24.60 |

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| 500 nm |
23.60 |
25.00 |

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| 520 nm |
23.90 |
26.00 |

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| 540 nm |
24.40 |
27.00 |

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| 560 nm |
25.00 |
27.90 |

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| 580 nm |
25.60 |
28.70 |

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| 600 nm |
26.20 |
29.30 |

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| 620 nm |
27.00 |
29.90 |

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| 640 nm |
27.70 |
30.30 |

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| 660 nm |
28.40 |
30.50 |

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| 680 nm |
28.90 |
30.50 |

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| 700 nm |
29.00 |
30.30 |

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Calculated Relative Intensity Colors of Luzonite in Air
Relative Intensity |
0% |
40% |
80% |
100% |
120% |
160% |
200% |
240% |
280% |
320% |
360% |
| R1 |
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| R2 |
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Calculated Properties of Luzonite
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Electron Density: |
relectron=4.18 gm/cc note: rLuzonite =4.47 gm/cc. |
Fermion Index |
Fermion Index = 0.00244 Boson Index = 0.99756 |
Photoelectric: |
PELuzonite = 36.75 barns/electron U=PELuzonite x relectron= 153.51 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Luzonite is Not Radioactive |
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Luzonite Classification
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Dana Class: |
3.2.2.1 (3)Sulfides - Sulfosalts |
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(3.2)where z/y = 4 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.2.2)Dana Group |
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3.2.2.1 Luzonite Cu3AsS4 I 42m 4 2m |
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3.2.2.2 Famatinite Cu3SbS4 I 42m 4 2m |
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3.2.2.3 Permingeatite Cu3SbSe4 I 42m 4 2m |
Strunz Class: |
II/C.06-10 II - Sulfides and sulphosalts |
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II/C - Sulfides with metal: sulfur, selenium and tellurium = 1:1 |
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II/C.06 - Stannite group |
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II/C.06-10 Luzonite Cu3AsS4 I 42m 4 2m |
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II/C.06-20 Famatinite Cu3SbS4 I 42m 4 2m |
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II/C.06-30 Permingeatite Cu3SbSe4 I 42m 4 2m |
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II/C.06-40 Briartite Cu2(Zn,Fe)GeS4 I 42m 4 2m |
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II/C.06-45 Barquillite! Cu2CdGeS4 I 42m 4 2m |
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II/C.06-50 Kuramite Cu3SnS4 I 42m 4 2m |
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II/C.06-60 Stannite Cu2FeSnS4 I 42m 4 2m |
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II/C.06-70 Ferrokesterite Cu2(Fe,Zn)SnS4 I 42m 4 2m |
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II/C.06-80 Kesterite Cu2(Zn,Fe)SnS4 I 4 4 |
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II/C.06-90 Cernyite Cu2CdSnS4 I 42m 4 2m |
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II/C.06-100 Velikite Cu2HgSnS4 I 42m 4 2m |
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II/C.06-110 Hocartite Ag2FeSnS4 I 42m 4 2m |
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II/C.06-120 Pirquitasite Ag2ZnSnS4 I 42m 4 2m |
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II/C.06-130 Sakuraiite (Cu,Zn,Fe,In,Sn)4S4 P 432, P 43m, or P m3m Cubic |
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II/C.06-140 Petrukite (Cu,Fe,Zn)2(Sn,In)S4 P mn21 mm2 |
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II/C.06-150 Rhodostannite Cu2FeSn3S8 I 41/a 4/m |
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II/C.06-160 Toyohaite Ag2FeSn3S8 I 41/a 4/m |
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Other Luzonite Information
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References: |
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Luzonite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - WWW-MINCRYST
13 -École des Mines de Paris
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Print or Cut-and-Paste your Luzonite Specimen Label here :
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Luzonite
Cu3AsS4
Dana No: 3.2.2.1 Strunz No: II/C.06-10
Locality:
Notes:
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