General Gratonite Information
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Chemical Formula: |
Pb9As4S15 |
Composition: |
Molecular Weight = 2,645.48 gm |
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Arsenic 11.33 % As |
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Lead 70.49 % Pb |
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Sulfur 18.18 % S |
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______ |
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100.00 % |
Empirical Formula: |
Pb9As4S15 |
Environment: |
In vugs in hydrothermal copper ores. |
IMA Status: |
Valid Species (Pre-IMA) 1939 |
Locality: |
In the Excelsior mine, Cerro de Pasco, Peru, in large crystals. Link to MinDat.org Location Data. |
Name Origin: |
For Louis Carly Graton (1880-1970), Professor of Economic Geology, Harvard University, Cambridge, Massachusetts, USA. |
Synonym: |
ICSD 18097 |
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PDF 44-1412 |
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Gratonite Image |
Images:
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Gratonite
Comments: Crystal cluster of gratonite. The largest crystal is 2.5 mm across.
Location: Excelsior mine, Cerro de Pasco, Pasco dept., Peru.
Scale: 1.5 x 1 cm.
© John Veevaert |
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Gratonite Crystallography
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Axial Ratios: |
a:c = 1:0.4402 |
Cell Dimensions: |
a = 17.701, c = 7.792, Z = 3; V = 2,114.34 Den(Calc)= 6.23 |
Crystal System: |
Trigonal - Ditrigonal PyramidalH-M Symbol (3m) Space Group: R 3m |
X Ray Diffraction: |
By Intensity(I/Io): 3.43(1), 3.75(0.6), 2.734(0.5), |
Forms:
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Forms:
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[ 0 2 1]
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Crystal Structure:
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drag1 - LMB Manipulate Structure
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Ribar B , Nowacki W , Zeitschrift fur Kristallographie , 128 (1969) p.321-338, Neubestimmung der kristallstruktur von gratonit, Pb9As4S15, Locality: Wiesloch, Germany
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Physical Properties of Gratonite
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Cleavage: |
None |
Color: |
Lead gray, Dark lead gray. |
Density: |
6.22 |
Diaphaniety: |
Opaque |
Fracture: |
Brittle - Generally displayed by glasses and most non-metallic minerals. |
Hardness: |
2.5 - Finger Nail |
Luster: |
Metallic |
Streak: |
black |
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Optical Properties of Gratonite
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RL Color: |
White, distinctly yellow against galena. |
RL Pleochroism: |
Very weak. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Gratonite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
36.90 |
37.80 |

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| 420 nm |
36.30 |
37.20 |

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| 440 nm |
35.70 |
36.60 |

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| 460 nm |
35.30 |
36.10 |

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| 480 nm |
35.10 |
35.70 |

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| 500 nm |
34.80 |
35.40 |

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| 520 nm |
34.50 |
35.00 |

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| 540 nm |
34.20 |
34.80 |

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| 560 nm |
34.10 |
34.60 |

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| 580 nm |
34.00 |
34.50 |

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| 600 nm |
33.90 |
34.50 |

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| 620 nm |
33.80 |
34.40 |

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| 640 nm |
33.70 |
34.20 |

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| 660 nm |
33.50 |
33.80 |

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| 680 nm |
33.00 |
33.40 |

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| 700 nm |
32.40 |
32.70 |

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Calculated Relative Intensity Colors of Gratonite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
240% |
260% |
| R1 |
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| R2 |
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Calculated Properties of Gratonite
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Electron Density: |
relectron=5.23 gm/cc note: rGratonite =6.23 gm/cc. |
Fermion Index |
Fermion Index = 0.15714 Boson Index = 0.84286 |
Photoelectric: |
PEGratonite =1,299.32 barns/electron U=PEGratonite x relectron=6,792.88 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Gratonite is Not Radioactive |
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Gratonite Classification
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Dana Class: |
3.3.2.1 (3)Sulfides - Sulfosalts |
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(3.3)where 3 < z/y < 4 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.3.2)Dana Group |
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3.3.2.1 Gratonite Pb9As4S15 R 3m 3m |
Strunz Class: |
II/E.15-30 II - Sulfides and sulphosalts |
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II/E - Sulfosalts (S : As,Sb,Bi = x) Lead-Sulfosalts with Arsen and Antimon x = 3.8 - 3.1 |
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II/E.15 - Jordanite - Lengenbachite series |
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II/E.15-10 Jordanite Pb14(As,Sb)6S23 P 21/m 2/m |
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II/E.15-20 Geocronite Pb14(Sb,As)6S23 P 21/m 2/m |
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II/E.15-30 Gratonite Pb9As4S15 R 3m 3m |
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II/E.15-40 Meneghinite Pb13CuSb7S24 Pbnm 2/m 2/m 2/m |
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II/E.15-45 Tsugaruite! Pb4As2S7 Pba2 or Pbam Ortho |
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II/E.15-50 Lengenbachite Pb6(Ag,Cu)2As4S13 P1 or P1 Tri |
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Other Gratonite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Gratonite :
1 -Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 -Athena
4 - EUROmin Project
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (UofA)
8 - HyperPhysics
9 -MinDAT
10 -MinMax(Deutsch)
11 -MinMax(English)
12 -Mineralienatlas (Deutsch)
13 -QUT Mineral Atlas
14 -École des Mines de Paris
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Print or Cut-and-Paste your Gratonite Specimen Label here :
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Gratonite
Pb9As4S15
Dana No: 3.3.2.1 Strunz No: II/E.15-30
Locality:
Notes:
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