General Bechererite Information
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Chemical Formula: |
(Zn,Cu)6Zn2(OH)13[(S,Si)(O,OH)4]2 |
Composition: |
Molecular Weight = 933.60 gm |
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Zinc 45.53 % Zn 56.67 % ZnO |
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Copper 10.21 % Cu 12.78 % CuO |
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Silicon 1.50 % Si 3.22 % SiO2 |
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Hydrogen 1.62 % H 14.47 % H2O |
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Sulfur 5.15 % S 10.29 % SO2 |
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Oxygen 35.99 % O |
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______ ______ |
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100.00 % 97.43 % = TOTAL OXIDE |
Empirical Formula: |
Zn4.5Cu1.5Zn2(OH)132(S0.75)2(Si0.25)2(O3)2(OH) |
Environment: |
Alteration product of copper and zinc orebodies. |
IMA Status: |
Approved IMA 1994 (Dana # Added) |
Locality: |
The dump of the Tonopah-Belmont mine, Osborne silver-gold district, Maricopa County, Arizona USA. Link to MinDat.org Location Data. |
Name Origin: |
Named after Dr. Karl Becherer (1926-) of the University of Vienna, in recognition of his contributions to the mineralogy of Spangolite from Lavrion. |
Synonym: |
ICSD 81354 |
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IMA1994-005 |
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PDF 46-1438 |
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Bechererite Crystallography
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Axial Ratios: |
a:c = 1:0.88632 |
Cell Dimensions: |
a = 8.322, c = 7.376, Z = 1; V = 442.39 Den(Calc)= 3.50 |
Crystal System: |
Trigonal - PyramidalH-M Symbol (3) Space Group: P 3 |
X Ray Diffraction: |
By Intensity(I/Io): 7.37(1), 2.556(0.5), 3.282(0.3), |
Forms:
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Crystal Structure:
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Giester G , Rieck B , American Mineralogist , 81 (1996) p.244-248, Bechererite, (Zn,Cu)6Zn2(OH)13[(S,Si)(O,OH)4]2, a novel mineral species from the, Tonopah-Belmont mine, Arizonia, Note: U(1,2) changed for Si, S, O1, OH1 to match symmetry constraints.
View Additional jPOWD Structure files for Bechererite
[1]
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Physical Properties of Bechererite
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Cleavage: |
[001] Perfect |
Color: |
Light green. |
Density: |
3.45 - 3.49, Average = 3.47 |
Diaphaniety: |
Transparent |
Fracture: |
Brittle - Generally displayed by glasses and most non-metallic minerals. |
Habit: |
Acicular - Occurs as needle-like crystals. |
Habit: |
Druse - Crystal growth in a cavity which results in numerous crystal tipped surfaces. |
Habit: |
Spherical - Spherical, rounded aggregates. |
Hardness: |
2.5-3 - Finger Nail-Calcite |
Luminescence: |
Non-fluorescent. |
Luster: |
Vitreous (Glassy) |
Streak: |
white |
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Optical Properties of Bechererite
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Dichroism (e): |
colorless. |
Dichroism (w): |
colorless. |
Gladstone-Dale: |
CI meas= 0.023 (Excellent) - where the CI = (1-KPDmeas/KC) CI calc= 0.032 (Excellent) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.188,KPDmeas= 0.1896,KC= 0.1941 |
Optical Data: |
Uniaxial (-), e=1.611, w=1.705, bire=0.0940. |
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Calculated Properties of Bechererite
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Electron Density: |
relectron=3.36 gm/cc note: rBechererite =3.47 gm/cc. |
Fermion Index |
Fermion Index = 0.01992 Boson Index = 0.98008 |
Photoelectric: |
PEBechererite = 27.31 barns/electron U=PEBechererite x relectron= 91.87 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Bechererite is Not Radioactive |
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Bechererite Classification
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Dana Class: |
31.1.6.2 (31)Hydrated Sulfates Containing Hydroxyl or Halogen |
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(31.1)where (A+ B++)m (XO4)p Zq·x(H2O), where m:p>6:1 |
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(31.1.6)Dana Group |
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31.1.6.1 Schulenbergite (Cu,Zn)7(SO4,CO3)2(OH)10·3(H2O) P 3 or P 3- Trig |
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31.1.6.2 Bechererite ! (Zn,Cu)6Zn2(OH)13[(S,Si)(O,OH)4]2 P 3 3 |
Strunz Class: |
VI/D.08-05 VI - Sulfates,Chromates,Molybdates and Tungstates |
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VI/D - Water-bearing sulfates with unfamiliar anions. cations of medium size |
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VI/D.08 - Spangolite - Glaucocerinite series |
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VI/D.08-05 Bechererite (Zn,Cu)6Zn2(OH)13[(S,Si)(O,OH)4]2 P 3 3 |
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VI/D.08-10 Spangolite Cu6Al(SO4)(OH)12Cl·3(H2O) P 31c 3m |
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VI/D.08-20 Cyanotrichite Cu4Al2(SO4)(OH)12·2(H2O) Unk Ortho |
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VI/D.08-30 Carbonate-cyanotrichite Cu4Al2(CO3,SO4)(OH)12·2(H2O) Unk Ortho |
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VI/D.08-35 Camerolaite Cu4Al2[HSbO4,SO4](OH)10(CO3)·2(H2O) P 21 ? 2 |
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VI/D.08-40 Woodwardite Cu4Al2(SO4)(OH)12·2-4(H2O) Unk Hex |
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VI/D.08-42 Hydrowoodwardite! Cu1-xAlx(OH)2(SO4)x/2·n(H2O)with0<x<0.67andn>3x/2 R 3m 3 2/m |
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VI/D.08-45 Zincowoodwardite! [Zn1-xAlx(OH)2][(SO4)x/2(H2O)n] P 3- or R 3m 3 |
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VI/D.08-45* Zincowoodwardite-1T! [Zn1BxAlx(OH)2][(SO4)x/2·n(H2O)],x=0.33,n.0.96 P 3 3 |
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VI/D.08-45** Zincowoodwardite-3R! [Zn1BxAlx(OH)2][(SO4)x/2·n(H2O)],0.32<x<0.50,n=0.59 R 3m 3 2/m |
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VI/D.08-50 Chalcoalumite CuAl4(SO4)(OH)12·3(H2O) P 21 2 |
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VI/D.08-60 Nickelalumite (Ni,Cu)Al4[(SO4),(NO3)2](OH)12·3(H2O) P 21 2 |
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VI/D.08-70 Mbobomkulite (Ni,Cu)Al4(NO3,SO4)2(OH)12·3(H2O) P 21 2 |
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VI/D.08-80 Hydrombobomkulite (Ni,Cu)Al4(NO3,SO4)2(OH)12·14(H2O) Unk Mono |
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VI/D.08-90 Carrboydite (Ni,Cu)14Al9(SO4,CO3)6(OH)43·7(H2O) Unk Hex |
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VI/D.08-100 Zincaluminite Zn6Al6(SO4)2(OH)26·5(H2O) Unk Hex |
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VI/D.08-110 Glaucocerinite (Zn,Cu)5Al3(SO4)1.5(OH)16·9(H2O) Unk (HEX-R) Trig |
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Other Bechererite Information
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References: |
NAME( MinRec) PHYS. PROP.(Am.Min.,Vol.81,1996) OPTIC PROP.(MinRec) |
See Also: |
Links to other databases for Bechererite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - WWW-MINCRYST
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Print or Cut-and-Paste your Bechererite Specimen Label here :
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Bechererite
(Zn,Cu)6Zn2(OH)13[(S,Si)(O,OH)4]2
Dana No: 31.1.6.2 Strunz No: VI/D.08-05
Locality:
Notes:
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