General Apuanite Information
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Chemical Formula: |
Fe++Fe+++4Sb+++4O12S |
Composition: |
Molecular Weight = 990.29 gm |
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Iron 28.20 % Fe 7.26 % FeO / 32.25 % Fe2O3 |
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Antimony 49.18 % Sb 58.87 % Sb2O3 |
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Sulfur 3.24 % S 3.24 % S2- |
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- % S -1.62 % -O=S |
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Oxygen 19.39 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Fe2+Fe3+4Sb4O12S |
Environment: |
In an iron deposit in barite formed by low-grade metasomatic processes at the contact between phyllites and dolostones. |
IMA Status: |
Approved IMA 1978 |
Locality: |
Buca della Vena mine, northeast of Stazzema, Apuan Alps, Tuscany, Italy. Link to MinDat.org Location Data. |
Name Origin: |
Named for the locality. |
Synonym: |
ICSD 100541 |
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PDF 33-642 |
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Apuanite Image |
Images:
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Apuanite
Comments: Black tabular crystal of apuanite on matrix.
Location: Buca della Vena Mine, Stazzema, Versilia Valley, Apuan Alps, Tuscany, Italy.
Scale: Picture size 1.2 mm.
© Thomas Witzke / Abraxas-Verlag |
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Apuanite Crystallography
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Axial Ratios: |
a:c = 1:2.1464 |
Cell Dimensions: |
a = 8.367, c = 17.959, Z = 4; V = 1,257.25 Den(Calc)= 5.23 |
Crystal System: |
Tetragonal - Ditetragonal DipyramidalH-M Symbol (4/m 2/m 2/m) Space Group: P 41/mbc |
X Ray Diffraction: |
By Intensity(I/Io): 3.168(1), 1.922(0.47), 2.957(0.43), |
Crystal Structure:
Mouse
drag1 - LMB Manipulate Structure
drag2 - RMB Resize/Rotate
Keyboard
S - Stereo Pair on/off
H - Help Screen
I - Data Info
A - Atoms On/Off
P - Polyhedra On/Off
B - Bonds On/Off
Help on Above
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Mellini M , Merlino S , American Mineralogist , 64 (1979) p.1235-1242, Versliaite and apuanite: Derivative structures related to schafarzikite
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Physical Properties of Apuanite
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Cleavage: |
[110] Perfect |
Color: |
Black. |
Density: |
5.33 |
Diaphaniety: |
Opaque |
Habit: |
Massive - Uniformly indistinguishable crystals forming large masses. |
Hardness: |
4-5 - Fluorite-Apatite |
Luster: |
Metallic |
Streak: |
black |
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Optical Properties of Apuanite
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Optical Data: |
Uniaxial (?). |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Apuanite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 470 nm |
19.10 |
20.80 |

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| 546 nm |
21.90 |
19.60 |

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| 589 nm |
21.60 |
18.40 |

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| 650 nm |
19.60 |
16.90 |

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Calculated Relative Intensity Colors of Apuanite in Air
Relative Intensity |
0% |
50% |
100% |
150% |
200% |
250% |
300% |
350% |
400% |
450% |
490% |
| R1 |
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| R2 |
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Calculated Properties of Apuanite
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Electron Density: |
relectron=4.71 gm/cc note: rApuanite =5.23 gm/cc. |
Fermion Index |
Fermion Index = 0.00631 Boson Index = 0.99369 |
Photoelectric: |
PEApuanite = 169.84 barns/electron U=PEApuanite x relectron= 800.10 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Apuanite is Not Radioactive |
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Apuanite Classification
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Dana Class: |
45.1.9.1 (45)Acid and normal Antimonites, Arsenites and Phosphites |
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(45.1)with miscellaneous formulae |
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(45.1.9)Dana Group |
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45.1.9.1 Apuanite FeFe4Sb4O12S P 41/mbc 4/m 2/m 2/m |
Strunz Class: |
IV/B.06-40 IV - Oxides |
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IV/B - Oxides with metal : oxygen = 3:4 (spinel type M3O4 and related) |
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IV/B.06 - Trippkeite - Minium series |
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IV/B.06-10 Trippkeite CuAs2O4 P 41/mbc 4/m 2/m 2/m |
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IV/B.06-15 Kusachiite CuBi2O4 P 4/ncc 4/m 2/m 2/m |
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IV/B.06-20 Schafarzikite FeSb2O4 P 41/mbc 4/m 2/m 2/m |
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IV/B.06-30 Versiliaite Fe4Fe8Sb12O23S2 Pbam ? 2/m 2/m 2/m |
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IV/B.06-40 Apuanite FeFe4Sb4O12S P 41/mbc 4/m 2/m 2/m |
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IV/B.06-50 Minium Pb2PbO4 P 41/mbc 4/m 2/m 2/m |
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Other Apuanite Information
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References: |
NAME( AntBidBlaNic3) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Apuanite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - WWW-MINCRYST
13 -École des Mines de Paris
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Print or Cut-and-Paste your Apuanite Specimen Label here :
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Apuanite
Fe++Fe+++4Sb+++4O12S
Dana No: 45.1.9.1 Strunz No: IV/B.06-40
Locality:
Notes:
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