General Tweddillite Information
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Chemical Formula: |
CaSr(Mn+++,Fe+++)2Al[Si3O12](OH) |
Composition: |
Molecular Weight = 559.08 gm |
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Strontium 15.67 % Sr 18.53 % SrO |
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Calcium 7.17 % Ca 10.03 % CaO |
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Manganese 14.74 % Mn 21.18 % Mn2O3 |
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Aluminum 6.27 % Al 11.85 % Al2O3 |
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Iron 4.00 % Fe 5.71 % Fe2O3 |
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Silicon 15.07 % Si 32.24 % SiO2 |
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Hydrogen 0.16 % H 1.45 % H2O |
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Oxygen 36.92 % O |
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______ ______ |
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100.00 % 101.00 % = TOTAL OXIDE |
Empirical Formula: |
CaSrMn3+1.5Al0.3Fe3+0.4Al(Si3O12)(OH)0.9 |
Environment: |
Calc-silicate rocks formed by hydrothermal alteration of Mn ores. Epidote Group. |
IMA Status: |
Approved IMA 2002 (Dana # Added) |
Locality: |
Wessels mine, Kalahari manganese fields, South Africa. Link to MinDat.org Location Data. |
Name Origin: |
Named for Samuel M. Tweddill, first curator (1897 to 1915) of the Museum of the Geological Survey, Pretoria, Republic of South Africa. |
Synonym: |
IMA2001-014 |
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Tweddillite Image |
Images:
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Tweddillite
Comments: Thin-section of (100) twinned tweddillite blades (red-orange-magenta ) in a matrix of serandite-pectolite (white-grey-yellow). Crossed polarizers. (MinMag 66:144).
Location: Kalahari manganese fields (Republic of South Africa).
Scale: Picture Size 1 mm.
© Mineralogical Magazine |
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Tweddillite Crystallography
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Axial Ratios: |
a:b:c =1.5675:1:1.8094 |
Cell Dimensions: |
a = 8.932, b = 5.698, c = 10.31, Z = 2; beta = 114.56° V = 477.25 Den(Calc)= 3.89 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 21/m |
X Ray Diffraction: |
By Intensity(I/Io): 2.936(1)(113), 2.182(0.8)(401), 2.586(0.8)(202),2.703(0.8)(300), 3.513(0.5)(211), 2.149(0.4)(221), 2.854(0.4)(020), 2.415(0.3), |
Crystal Structure:
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Armbruster T , Gnos E , Dixon R , Gutzmer J , Hejny C , Dobelin N , Medenbach O , Mineralogical Magazine , 66 (2002) p.137-150, Manganvesuvianite and tweddillite, two new Mn3+-silicate minerals, from the Kalahari manganese fields, South Africa, Locality: Kalahari manganese fields, South Africa
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Physical Properties of Tweddillite
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Cleavage: |
[001] Perfect |
Color: |
Deep red. |
Diaphaniety: |
Transparent |
Fracture: |
Brittle - Subconchoidal - Brittle frature with subconchoidal fragments |
Habit: |
Bladed - Aggregates of thin lath-like crystals (e.g. kyanite). |
Habit: |
Radial - Crystals radiate from a center without producing stellar forms (e.g. stibnite) |
Hardness: |
6-7 - Orthoclase-Quartz |
Luster: |
Vitreous (Glassy) |
Streak: |
brownish red |
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Optical Properties of Tweddillite
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Gladstone-Dale: |
CI calc= 0.062 (Fair) - where the CI = (1-KPDcalc/KC) KPDcalc= 0.2121,KC= 0.2262 |
Optical Data: |
Biaxial (+), b=1.825 |
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Calculated Properties of Tweddillite
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Electron Density: |
relectron=3.74 gm/cc note: rTweddillite =3.89 gm/cc. |
Fermion Index |
Fermion Index = 0.01912 Boson Index = 0.98088 |
Photoelectric: |
PETweddillite = 23.90 barns/electron U=PETweddillite x relectron= 89.44 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Tweddillite is Not Radioactive |
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Tweddillite Classification
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Dana Class: |
58.2.1a.15 (58)Sorosilicate Insular, Mixed, Single, and Larger Tetrahedral Groups |
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(58.2)with cations in [6] and higher coordination; single and double groups (n=1,2) |
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(58.2.1a)Epidote group (Epidote subgroup) |
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58.2.1a.1 Allanite-(Ce) (Ce,Ca,Y)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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58.2.1a.2 Allanite-(La)! Ca(REE,Ca)Al2(Fe,Fe)(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.3 Allanite-(Y) (Y,Ce,Ca)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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58.2.1a.4 Clinozoisite Ca2Al3(SiO4)3(OH)=Ca2AlAl2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.5 Dissakisite-(Ce) Ca(Ce,REE)(Mg,Fe)(Al,Fe)2Si3O12(OH) P 21/m 2/m |
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58.2.1a.6 Dollaseite-(Ce) CaCeMg2AlSi3O11(OH,F)2 P 21/m 2/m |
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58.2.1a.7 Epidote Ca2(Fe,Al)3(SiO4)3(OH)=Ca2(Fe,Al)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.8 Hancockite (Ca,Pb,Sr)2(Al,Fe)3(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.9 Khristovite-(Ce) (Ca,REE)(Ce,REE)(Mg,Fe,Cr,Ti,V,Al)MnAl(SiO4)(Si2O7)(OH)(F,O) P 21/m 2/m |
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58.2.1a.10 Mukhinite Ca2Al2V(SiO4)3(OH) P 21/m 2/m |
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58.2.1a.11 Piemontite Ca2(Al,Mn,Fe)3(SiO4)3(OH)=Ca2(Mn,Fe)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.12 Strontiopiemontite (Ca,Mn)(Sr,Ca)Mn(Al,Mn,Fe)2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.13 Androsite-(La)! (Mn,Ca)(La,Ce,Ca,Nd)AlMnMn(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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58.2.1a.14 Ferriallanite-(Ce)! CaCe(Fe,Fe,Al)3[SiO4][Si2O7]O(OH) P 21/m 2/m |
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58.2.1a.15 Tweddillite ! CaSr(Mn,Fe)2Al[Si3O12](OH) P 21/m 2/m |
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58.2.1a.16 Gatelite-(Ce)! (Ca,Ce,La,Nd)4(Al,Mg,Fe)4[Si2O7][SiO4]3(O,F,OH)3 P 21/a 2/m |
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58.2.1a.17 Niigataite! CaSrAl3(Si2O7)(SiO4)O(OH) P 21/m 2/m |
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58.2.1a.18 Vastmanlandite-(Ce)! Ce3CaMg2Al2Si5O19(OH)2F P 21/m 2/m |
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58.2.1a.19 IMA2002-049! (Mn,Ca)(Ce,REE)AlMnMn(Si2O7)(SiO4)O(OH) P 21/m 2/m |
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58.2.1a.20 Dissakisite-(La)! (Ca,Fe,Th)(REE,Ca)(Al,Cr,Ti)2(Mg,Fe,Al)Si3O12(OH,F)withLa>Ce P 21/m 2/m |
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58.2.1a.22 IMA2004-015! (Mn,Ca)(REE)VAlMn(Si2O7)(SiO4)O(OH) P 21/m 2/m |
Strunz Class: |
VIII/C.23-45 VIII - Silicates |
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VIII/C - Sorosilicates, mixed structure with [SiO4]2- "inseln" and [Si2O7]6- groups |
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VIII/C.23 - Epidote group |
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VIII/C.23-10 Clinozoisite Ca2Al3(SiO4)3(OH)=Ca2AlAl2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-20 Epidote Ca2(Fe,Al)3(SiO4)3(OH)=Ca2(Fe,Al)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-30 Piemontite Ca2(Al,Mn,Fe)3(SiO4)3(OH)=Ca2(Mn,Fe)Al2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-40 Strontiopiemontite (Ca,Mn)(Sr,Ca)Mn(Al,Mn,Fe)2(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-43 Niigataite! CaSrAl3(Si2O7)(SiO4)O(OH) P 21/m 2/m |
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VIII/C.23-45 Tweddillite CaSr(Mn,Fe)2Al[Si3O12](OH) P 21/m 2/m |
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VIII/C.23-50 Mukhinite Ca2Al2V(SiO4)3(OH) P 21/m 2/m |
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VIII/C.23-52 Androsite-(La)! (Mn,Ca)(La,Ce,Ca,Nd)AlMnMn(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-55 Dollaseite-(Ce) CaCeMg2AlSi3O11(OH,F)2 P 21/m 2/m |
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VIII/C.23-58 Dissakisite-(Ce) Ca(Ce,REE)(Mg,Fe)(Al,Fe)2Si3O12(OH) P 21/m 2/m |
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VIII/C.23-60 Allanite-(Y) (Y,Ce,Ca)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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VIII/C.23-65 Allanite-(La)! Ca(REE,Ca)Al2(Fe,Fe)(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-80 Allanite-(Ce) (Ce,Ca,Y)2(Al,Fe)3(SiO4)3(OH) P 21/m 2/m |
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VIII/C.23-85a Ferriallanite-(Ce)! CaCe(Fe,Fe,Al)3[SiO4][Si2O7]O(OH) P 21/m 2/m |
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VIII/C.23-85 Khristovite-(Ce) (Ca,REE)(Ce,REE)(Mg,Fe,Cr,Ti,V,Al)MnAl(SiO4)(Si2O7)(OH)(F,O) P 21/m 2/m |
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VIII/C.23-87 Gatelite-(Ce)! (Ca,Ce,La,Nd)4(Al,Mg,Fe)4[Si2O7][SiO4]3(O,F,OH)3 P 21/a 2/m |
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VIII/C.23-90 Hancockite (Ca,Pb,Sr)2(Al,Fe)3(SiO4)(Si2O7)O(OH) P 21/m 2/m |
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VIII/C.23-100 Zoisite Ca2Al3(SiO4)3(OH)=Ca2AlAl2(SiO4)(Si2O7)O(OH) Pnmc 2/m 2/m 2/m |
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Other Tweddillite Information
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References: |
NAME( AmMin, Vol 88, p 253) PHYS. PROP.(AmMin, Vol 88, p 253) OPTIC PROP.(AmMin, Vol 88, p 253) |
See Also: |
Links to other databases for Tweddillite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -MinDAT
6 -MinMax(Deutsch)
7 -MinMax(English)
8 -Mineralienatlas (Deutsch)
9 -QUT Mineral Atlas
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Tweddillite
CaSr(Mn+++,Fe+++)2Al[Si3O12](OH)
Dana No: 58.2.1a.15 Strunz No: VIII/C.23-45
Locality:
Notes:
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