General Na-komarovite Information
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Chemical Formula: |
Na6CaNb6[Si4O12F2·4(H2O) |
Composition: |
Molecular Weight = 1,359.81 gm |
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Sodium 9.13 % Na 12.31 % Na2O |
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Calcium 2.36 % Ca 3.30 % CaO |
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Cerium 1.03 % Ce 1.21 % Ce2O3 |
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Titanium 2.11 % Ti 3.52 % TiO2 |
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Niobium 38.26 % Nb 54.73 % Nb2O5 |
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Silicon 8.26 % Si 17.67 % SiO2 |
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Hydrogen 0.59 % H 5.30 % H2O |
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Oxygen 35.18 % O |
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Fluorine 3.07 % F 3.07 % F |
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- % F -1.29 % -O=F2 |
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______ ______ |
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100.00 % 99.82 % = TOTAL OXIDE |
Empirical Formula: |
Na5.4Ca0.8Ce0.1Ti0.6Nb5.6(Si4O12)O13.9F2.2·4(H2O) |
Environment: |
In alkalic syenites. |
IMA Status: |
Discredited IMA 1979 |
Locality: |
Ilimaussaq massif, Greenland. Link to MinDat.org Location Data. |
Name Origin: |
Named in 1979 for Vladimir M. Komarov (1927-1967), Russian cosmonaut who was killed during his return flight on April 23, 1967 and the sodium content. |
Synonym: |
Komarovite-Na |
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Silicified pyrochlore |
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Sodium-Komarovite |
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Na-komarovite Crystallography
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Axial Ratios: |
a:b:c =0.2972:1:0.301 |
Cell Dimensions: |
a = 7.31, b = 24.588, c = 7.402, Z = 2; V = 1,330.42 Den(Calc)= 3.39 |
Crystal System: |
Orthorhombic - DipyramidalH-M Symbol (2/m 2/m 2/m) Space Group: C mmm |
Crystal Structure:
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Balic-Zunic T , Petersen O V , Bernhardt H J , Micheelsen H I , Neues Jahrbuch fur Mineralogie, Monatshefte , 2002 (2002) p.497-514, The crystal structure and mineralogical description of a Na-dominant, komarovite from the Ilimaussaq alkaline complex, South Greenland, Locality: Ilimaussaq, South Greenland
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Physical Properties of Na-komarovite
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Cleavage: |
[100] Perfect, [001] Fair |
Color: |
White, Light yellowish white. |
Density: |
3.3 |
Diaphaniety: |
Transparent to Translucent |
Habit: |
Foliated - Two dimensional platy forms. |
Habit: |
Massive - Uniformly indistinguishable crystals forming large masses. |
Habit: |
Platy - Sheet forms (e.g. micas). |
Hardness: |
4 - Fluorite |
Luster: |
Adamantine |
Streak: |
white |
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Optical Properties of Na-komarovite
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Gladstone-Dale: |
CI meas= -0.054 (Good) - where the CI = (1-KPDmeas/KC) CI calc= -0.026 (Excellent) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2554,KPDmeas= 0.2623,KC= 0.2488 |
Optical Data: |
Biaxial (-), a=1.809, b=1.876, g=1.912, bire=0.1030, 2V(Calc)=70, 2V(Meas)=72. Dispersion r >> v. |
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Calculated Properties of Na-komarovite
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Electron Density: |
relectron=3.23 gm/cc note: rNa-komarovite =3.39 gm/cc. |
Fermion Index |
Fermion Index = 0.00679 Boson Index = 0.99321 |
Photoelectric: |
PENa-komarovite = 63.01 barns/electron U=PENa-komarovite x relectron= 203.25 barns/cc. |
Radioactivity: |
GRapi = 1,045.91 (Gamma Ray American Petroleum Institute Units)
Estimated Radioactivity from Na-komarovite - mild
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 8.26 cm |
23,081 |
6.24E-07 |
1,045.91 |
0.34 |
| 100 gm / 3.83 cm |
2,308 |
6.24E-08 |
104.59 |
0.03 |
| 10 gm / 1.78 cm |
231 |
6.24E-09 |
10.46 |
0.00 |
| 1 gm / 8.26 mm |
23 |
6.24E-10 |
1.05 |
0.00 |
| 0.1 gm / 3.83 mm |
2 |
6.24E-11 |
0.10 |
0.00 |
| 0.01 gm / 1.78 mm |
0 |
6.24E-12 |
0.01 |
0.00 |
| 0.001 gm / 0.83 mm |
0 |
6.24E-13 |
0.00 |
0.00 |
Weight of pure Na-komarovite in grams (gm) and Calculated Diameter of a Sphere with a Density of 3.39 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
**
Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 0.05 % Th) From Sum REE Elements ( 1.03 % REE)
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Na-komarovite Classification
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Dana Class: |
56.2.4.13 (56)Sorosilicate Si2O7 Groups and O, OH, F. and H2O |
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(56.2)with cations in [4] and/or >[4] coordination |
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(56.2.4)Cuspidine - Wohlerite group |
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56.2.4.1 Baghdadite Ca3(Zr,Ti)Si2O9 P 21/a 2/m |
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56.2.4.2 Burpalite Na2CaZrSi2O7F2 P 21/a 2/m |
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56.2.4.3 Cuspidine Ca4Si2O7(F,OH)2 P 21/c 2/m |
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56.2.4.4 Lavenite (Na,Ca)2(Mn,Fe)(Zr,Ti,Nb)Si2O7(O,OH,F) P 21/a 2/m |
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56.2.4.5 Wohlerite NaCa2(Zr,Nb)Si2O7(O,OH,F)2 P 21/m 2/m |
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56.2.4.6 Niocalite Ca14Nb2(Si2O7)4O6F2 Pa m |
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56.2.4.7 Hiortdahlite (Ca,Na,Y)3(Zr,Ti)Si2O7(F,O,OH)2 P1 1 |
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56.2.4.8 Rosenbuschite (Ca,Na)3(Zr,Ti)Si2O8F P1 1 |
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56.2.4.9 Hainite Na4Ca8(Ti,Zr,Mn,Fe)3Si8O28F8 P1 1 |
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56.2.4.10 Janhaugite (Na,Ca)3(Mn,Fe)3(Ti,Zr,Nb)2Si4O15(OH,F,O)3 P 21/n 2/m |
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56.2.4.11 Jennite Ca9Si6O18(OH)6·8H2O P1 1 |
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56.2.4.12 Komarovite (Ca,Mn)2(Nb,Ti)2Si2O7(O,F)2·3.5(H2O) Unk Ortho |
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56.2.4.13 Na-komarovite ? Na6CaNb6[Si4O12F2·4(H2O) C mmm 2/m 2/m 2/m |
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56.2.4.14 Suolunite Ca2Si2O5(OH)2·(H2O) F dd2 mm2 |
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56.2.4.15 Mongolite Ca4Nb6Si5O24(OH)10·5(H2O) Unk Tetra |
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56.2.4.16 Kristiansenite! Ca2ScSn(Si2O7)(Si2O6OH) C1 1 |
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56.2.4.17 Kochite! Na2(Na,Ca)4Ca4(Mn,Ca)2Zr2Ti2(Si2O7)4(O,F)4F4 P1 1 |
Strunz Class: |
VIII/C.16-10 VIII - Silicates |
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VIII/C - Sorosilicates with [Si2O7]6-, with anions unfamiliar to tetraheders [O,OH,F] |
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VIII/C.16 - Komarovite series |
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VIII/C.16-10 Na-komarovite Na6CaNb6[Si4O12F2·4(H2O) C mmm 2/m 2/m 2/m |
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VIII/C.16-20 Komarovite (Ca,Mn)2(Nb,Ti)2Si2O7(O,F)2·3.5(H2O) Unk Ortho |
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VIII/C.16-30 Fersmanite Ca4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3 C 2/c 2/m |
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Other Na-komarovite Information
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References: |
NAME( Dana8) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990, AmMin, v 88, p 935) OPTIC PROP.(AmMin, v 88, p 935) |
See Also: |
Links to other databases for Na-komarovite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -MinDAT
6 -MinMax(Deutsch)
7 -MinMax(English)
8 -Mineralienatlas (Deutsch)
9 -QUT Mineral Atlas
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Na-komarovite
Na6CaNb6[Si4O12F2·4(H2O)
Dana No: 56.2.4.13 Strunz No: VIII/C.16-10
Locality:
Notes:
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