General Meta-uranocircite Information
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Chemical Formula: |
Ba(UO2)2(PO4)2·6-8(H2O) |
Composition: |
Molecular Weight = 993.43 gm |
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Barium 13.82 % Ba 15.43 % BaO |
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Uranium 47.92 % U 54.36 % UO2 |
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Phosphorus 6.24 % P 14.29 % P2O5 |
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Hydrogen 1.42 % H 12.69 % H2O |
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Oxygen 30.60 % O |
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______ ______ |
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100.00 % 96.78 % = TOTAL OXIDE |
Empirical Formula: |
Ba(UO2)2(PO4)2·7(H2O) |
Environment: |
Secndary mineral derived from phosphatic uraninite deposits. |
IMA Status: |
Approved IMA 1982 |
Locality: |
Bergen, Falkenstein, Vogtland, Sachsen (Saxony), Germany. Link to MinDat.org Location Data. |
Name Origin: |
Named for its lower hydrate relationship to uranocercite. |
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Meta-uranocircite Image |
Images:
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Images:
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Meta-uranocircite Uranocircite
Comments: Brilliant, fluorescent yellow green crystals of uranocircite altered to meta-uranocircite.
Location: Bergen, Vogtland, Saxony, Germany.
Scale: 2.3 x 2.2 cm.
© John Veevaert |
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Images:
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Meta-uranocircite Uranocircite
Comments: Crystal fragment of uranocircite fracturing due to dehydration to meta-uranocircite. The most common are 100 and 010 fractures, with 110 close behind. But notice the 210 and 410 fractures (breaks) as well.
Location: .
Scale: Crystal size 2x3.5 cm.
© Paul M. Schumacher |
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Images:
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Meta-uranocircite Crystallography
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Axial Ratios: |
a:b:c =1.0001:1:2.5344 |
Cell Dimensions: |
a = 6.965, b = 6.964, c = 17.65, Z = 2; beta = 90.6° V = 856.05 Den(Calc)= 3.85 |
Crystal System: |
Monoclinic - SphenoidalH-M Symbol (2) Space Group: P 21 |
X Ray Diffraction: |
By Intensity(I/Io): 3.6(1), 8.34(0.9), 4.23(0.4), |
Crystal Structure:
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Khosrawan-Sazedj F , Tschermaks Mineralogische und Petrographische Mitteilungen , 29 (1982) p.193-204, The crystal structure of meta-uranocircite II, Ba(UO2)2(PO4)2*6H2O, Locality: synthetic
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Physical Properties of Meta-uranocircite
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Color: |
Green. |
Density: |
3.95 |
Diaphaniety: |
Transparent to Translucent |
Hardness: |
2-2.5 - Gypsum-Finger Nail |
Luminescence: |
Fluorescent. |
Luster: |
Pearly |
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Optical Properties of Meta-uranocircite
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Gladstone-Dale: |
CI meas= -0.092 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= -0.12 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1607,KPDmeas= 0.1566,KC= 0.1434 |
Optical Data: |
Biaxial (-), a=1.61, b=1.623, g=1.623, bire=0.0130 |
Pleochroism (x): |
colorless. |
Pleochroism (y): |
colorless. |
Pleochroism (z): |
colorless. |
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Calculated Properties of Meta-uranocircite
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Electron Density: |
relectron=3.47 gm/cc note: rMeta-uranocircite =3.95 gm/cc. |
Fermion Index |
Fermion Index = 0.02823 Boson Index = 0.97177 |
Photoelectric: |
PEMeta-uranocircite =1,302.10 barns/electron U=PEMeta-uranocircite x relectron=4,514.59 barns/cc. |
Radioactivity: |
GRapi = 3,585,364.47 (Gamma Ray American Petroleum Institute Units)
Meta-uranocircite is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
8.48 ± 2.12 grams of pure Meta-uranocircite .
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 100 cm box)
848.36 ±212.09 grams of pure Meta-uranocircite .
Estimated Radioactivity from Meta-uranocircite - very strong
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.85 cm |
85,777,713 |
2.32E-03 |
3,585,364.47 |
1,178.75 |
| 100 gm / 3.64 cm |
8,577,771 |
2.32E-04 |
358,536.45 |
117.87 |
| 10 gm / 1.69 cm |
857,777 |
2.32E-05 |
35,853.64 |
11.79 |
| 1 gm / 7.85 mm |
85,778 |
2.32E-06 |
3,585.36 |
1.18 |
| 0.1 gm / 3.64 mm |
8,578 |
2.32E-07 |
358.54 |
0.12 |
| 0.01 gm / 1.69 mm |
858 |
2.32E-08 |
35.85 |
0.01 |
| 0.001 gm / 0.78 mm |
86 |
2.32E-09 |
3.59 |
0.00 |
Weight of pure Meta-uranocircite in grams (gm) and Calculated Diameter of a Sphere with a Density of 3.95 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
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Meta-uranocircite Classification
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Dana Class: |
40.2a.3.2 (40)Hydrated Phosphates, etc |
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(40.2a)where A++ (B++)2 (XO4) · x(H2O), containing (UO2)++ |
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(40.2a.3)Dana Group |
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40.2a.3.1 Uranocircite Ba(UO2)2(PO4)2·12(H2O) P 4/nnc 4/m 2/m 2/m |
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40.2a.3.2 Meta-uranocircite Ba(UO2)2(PO4)2·6-8(H2O) P 21 2 |
Strunz Class: |
VII/E.02-110 VII - Phosphates, Arsenates and Vanadates |
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VII/E - Uranylphosphates and uranylvanadates with [UO2]2+ - [PO4 | AsO4]3- and [UO2]2+ - [V2O8]6- |
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VII/E.02 - Meta-autunite group |
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VII/E.02-10 Metanovacekite Mg(UO2)2(AsO4)2·4-8(H2O) P 4/n 4/m |
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VII/E.02-20 Bassetite Fe(UO2)2(PO4)2·8(H2O) P 21/m 2/m |
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VII/E.02-30 Metakahlerite Fe(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-40 Lehnerite Mn[UO2/PO4]2·8(H2O) P 21/n 2/m |
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VII/E.02-50 Metakirchheimerite Co(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-60 Metatorbernite Cu(UO2)2(PO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-70 Metazeunerite Cu(UO2)2(AsO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-80 Metalodevite Zn(UO2)2(AsO4)2·10(H2O) P 41/m 4/m |
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VII/E.02-90 Meta-autunite Ca(UO2)2(PO4)2·2-6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-95 Sodium meta-autunite! Na2(UO2)2(PO4)2·6-8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-100 Meta-uranospinite Ca(UO2)2(AsO4)2·8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-110 Meta-uranocircite Ba(UO2)2(PO4)2·6-8(H2O) P 21 2 |
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VII/E.02-120 Metaheinrichite Ba(UO2)2(AsO4)2·8(H2O) P 41/? 4/m |
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VII/E.02-130 Sodium-uranospinite (Na2,Ca)(UO2)2(AsO4)2·5(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-140 Meta-ankoleite K2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-150 Abernathyite K(UO2)(AsO4)·4(H2O) P 4/ncc 4/m 2/m 2/m |
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VII/E.02-160 Uramphite (NH4)(UO2)(PO4)·3(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-170 Chernikovite (H3O)2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-180 Pseudo-autunite* (H3O)4Ca2(UO2)2(PO4)4·5(H2O)(?) Unk Ortho |
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VII/E.02-190 Ulrichite CaCu(UO2)(PO4)2·4(H2O) C 2/m 2/m |
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Other Meta-uranocircite Information
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References: |
NAME( Dana8) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990, AmMin 89:1833) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Meta-uranocircite :
1 -Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 -Athena
4 - Crocoite.com Mineral Locations
5 -Google Images
6 -Google Scholar
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - Uranium Minerals
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Meta-uranocircite
Ba(UO2)2(PO4)2·6-8(H2O)
Dana No: 40.2a.3.2 Strunz No: VII/E.02-110
Locality:
Notes:
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