Hydroxyapophyllite Mineral Data


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General Hydroxyapophyllite Information

Help on Chemical  Formula: Chemical Formula: KCa4Si8O20(OH,F)·8(H2O)
Help on Composition: Composition: Molecular Weight = 759.07 gm
   Potassium   4.38 %  K     5.27 % K2O
   Sodium      0.45 %  Na    0.61 % Na2O
   Calcium    21.12 %  Ca   29.55 % CaO
   Silicon    29.60 %  Si   63.32 % SiO2
   Hydrogen    0.11 %  H     0.95 % H2O
   Oxygen     43.84 %  O
   Fluorine    0.50 %  F     0.50 % F
                -   %  F    -0.21 % -O=F2
             ______        ______ 
             100.00 %      100.00 % = TOTAL OXIDE
Help on Empirical Formula: Empirical Formula: K0.85Na0.15Ca4Si8O20(OH)0.8F0.2
Help on IMA Status: IMA Status: Approved IMA 1978
Help on Locality: Locality: Ore Knob mine, Jefferson, Ashe County, North Carolina, USA Link to MinDat.org Location Data.
Help on Name Origin: Name Origin: From the Greek apophylliso - "it flakes off" and the predominant hydroxyl anion.
Help on Synonym: Synonym: Apophyllite
  ICSD 200329
  PDF 29-994
 

Hydroxyapophyllite Image

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Hydroxyapophyllite   Apophyllite   Stilbite

Comments: 3 cm. pink-colored rosette of stilbite and clear "apophyllite" (probably hydroxyapophyllite) in an amygdaloidal cavity.
Location: Aurangabad District, Jalgaon, India. Scale: Specimen size 6 cm.
© Dave Barthelmy

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Hydroxyapophyllite   Apophyllite

Comments: Crystal cluster of tabular hydroxyapophyllite.
Location: Wessels Mine, Kalahari Manganese Field, Northern Cape Province, South Africa. Scale: 2.5 x 2.3 cm.
© John Veevaert

Hydroxyapophyllite Crystallography

Help on Axial Ratios: Axial Ratios: a:c = 1:1.76319
Help on Cell Dimensions: Cell Dimensions: a = 8.978, c = 15.83, Z = 2; V = 1,275.97 Den(Calc)= 1.98
Help on Crystal System: Crystal System: Tetragonal - Ditetragonal DipyramidalH-M Symbol (4/m 2/m 2/m) Space Group: P 4/mnc
Help on X Ray Diffraction: X Ray Diffraction: By Intensity(I/Io): 3.965(1), 2.99(0.67), 1.588(0.26),
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Rouse R C , Peacor D R , Dunn P J , American Mineralogist , 63 (1978) p.196-202, Hydroxyapophyllite, a new mineral, and a redefinition of the apophyllite group, II. Crystal structure, Note: sample is from Kimberley, South Africa

 

Physical Properties of Hydroxyapophyllite

Help on Cleavage: Cleavage: [001] Perfect
Help on Color: Color: White, Pink, Green, Yellow, Violet.
Help on Density: Density: 2.3 - 2.4, Average = 2.34
Help on Diaphaniety: Diaphaniety: Transparent
Help on Habit: Habit: Crystalline - Coarse - Occurs as well-formed coarse sized crystals.
Help on Habit: Habit: Massive - Uniformly indistinguishable crystals forming large masses.
Help on Habit: Habit: Pseudo Cubic - Crystals show a cubic outline.
Help on Hardness: Hardness: 4-5 - Fluorite-Apatite
Help on Luminescence: Luminescence: None.
Help on Luster: Luster: Vitreous - Pearly
Help on Streak: Streak: white
 

Optical Properties of Hydroxyapophyllite

Help on Gladstone-Dale: Gladstone-Dale: CI meas= -0.106 (Poor) - where the CI = (1-KPDmeas/KC)
CI calc= -0.313 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.274,KPDmeas= 0.2309,KC= 0.2087
Help on Optical Data: Optical Data: Uniaxial (+), w=1.542, e=1.543, bire=0.0010.
 

Calculated Properties of Hydroxyapophyllite

Help on Electron Density: Electron Density:

relectron=2.35 gm/cc
note: rHydroxyapophyllite =2.35 gm/cc.

Help on Fermion Index Fermion Index Fermion Index = 0.01432
Boson Index = 0.98568
Help on Photoelectric: Photoelectric:

PEHydroxyapophyllite = 4.17 barns/electron
U=PEHydroxyapophyllite x relectron= 9.78 barns/cc.

Help on Radioactivity: Radioactivity:

GRapi = 63.07 (Gamma Ray American Petroleum Institute Units)

Estimated Radioactivity from Hydroxyapophyllite - barely detectable

 

Hydroxyapophyllite Classification

Help on  Dana Class: Dana Class: 72.3.1.2 (72)Phyllosilicate Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings
  (72.3)with 3-, 4-, or 5-membered rings and 8-membered rings
  (72.3.1)Apophyllite group (4- & 8-membered rings)
 
72.3.1.0 Apophyllite* KCa4(Si4O10)2F·8(H2O) P 4/mnc 4/m 2/m 2/m
 
72.3.1.1 Fluorapophyllite (K,Na)Ca4Si8O20(F,OH)·8(H2O) P 4/mnc 4/m 2/m 2/m
 
72.3.1.2 Hydroxyapophyllite KCa4Si8O20(OH,F)·8(H2O) P 4/mnc 4/m 2/m 2/m
 
72.3.1.3 Natroapophyllite NaCa4Si8O20F·8(H2O) Pnnm 2/m 2/m 2/m
 
72.3.1.4 Carletonite KNa4Ca4Si8O18(CO3)4(OH,F)·(H2O) P 4/mbm 4/m 2/m 2/m
Help on  Strunz Class: Strunz Class: VIII/H.01-30 VIII - Silicates
  VIII/H - Phyllosilicates (layered), Tetragonal or pseudotetragonal layered structures [Si4O10]4- and others
  VIII/H.01 - Apophyllite series
 
VIII/H.01-10 Natroapophyllite NaCa4Si8O20F·8(H2O) Pnnm 2/m 2/m 2/m
 
VIII/H.01-20 Fluorapophyllite (K,Na)Ca4Si8O20(F,OH)·8(H2O) P 4/mnc 4/m 2/m 2/m
 
VIII/H.01-30 Hydroxyapophyllite KCa4Si8O20(OH,F)·8(H2O) P 4/mnc 4/m 2/m 2/m
 

Other Hydroxyapophyllite Information

Help on References: References: PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990)
Help on See Also: See Also: Links to other databases for Hydroxyapophyllite :
1 - Alkali-Nuts(English) 2 - Alkali-Nuts(Francais) 3 -Am. Min. Crystal Structure Database 4 -Athena 5 - EUROmin Project 6 - Franklin Minerals(Dunn) 7 -Google Images 8 -Google Scholar 9 -Handbook of Mineralogy (MinSocAm) 10 -Handbook of Mineralogy (UofA) 11 -MinDAT 12 -MinMax(Deutsch) 13 -MinMax(English) 14 -Mineralienatlas (Deutsch) 15 -QUT Mineral Atlas 16 - WWW-MINCRYST 17 -École des Mines de Paris

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Hydroxyapophyllite

KCa4Si8O20(OH,F)·8(H2O)
Dana No: 72.3.1.2 Strunz No: VIII/H.01-30
Locality:

 

Notes:

 

 
   
 
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